19-12-2013 дата публикации
Номер: US20130334688A1
The invention relates to the semiconductor material manufacturing technical field. A multi-elements-doped zinc oxide film as well as manufacturing method and application in photo-electric devices thereof are provided. The manufacturing method comprises the following steps: (1) mixing the powder of GaO, AlO, SiOand ZnO according to the following percentage by mass: 0.5%˜10% of GaO, 0.5%˜5% of AlO, 0.5%˜1.5% of SiO, and the residue of ZnO; (2) sintering the powder mixture as target material; (3) putting the target material into a magnetic sputtering chamber, evacuating, setting-up work pressure of 0.2 Pa-5 Pa, introducing mixed gas of inert gas and hydrogen with a flow rate of 15 sccm˜25 sccm, adopting a sputtering power of 40 W˜200 W, and sputtering on the substrate to obtain the multi-elements-doped zinc oxide film. 1. A method for manufacturing a multi-elements doped zinc oxide film , comprising following steps:{'sub': 2', '3', '2', '3', '2', '2', '3', '2', '3', '2, 'mixing GaOpowder, AlOpowder, SiOpowder, and ZnO powder, sintering the resulted mixture to give a target, wherein the said GaOpowder accounts for 0.5%-10% of the total weight, the said AlOpowder accounts for 0.5%-5% of the total weight, the said SiOpowder accounts for 0.5%-1.5% of the total weight, and the rest is ZnO powder;'}loading the said target into a magnetron sputtering chamber, then evacuating the said chamber, and setting the operating pressure within the range of 0.2 Pa to 5 Pa, then inletting a mixed gas of an inert gas and a hydrogen gas into the said chamber at a flow rate of 15 sccm to 25 sccm, and sputtering on a substrate to give a multi-elements doped zinc oxide film, wherein the power of the said sputtering is in the range of 40 W to 200 W.20815. The method for manufacturing a multi-elements doped zinc oxide film of claim 1 , wherein the said GaOpowder accounts for 2%-4% of the total weight claim 1 , the said AlOpowder accounts for .%-.% of the total weight claim 1 , the said ...
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