22-09-2022 дата публикации
Номер: US20220301785A1
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In this disclosure, antiferroelectric capacitors having one or more interfacial layer/antiferroelectric layer/interfacial layer stacked structures are proposed. The compressive chemical pressure of the proposed structure leads to a reduction of the hysteresis and thus a high ESD and a low energy loss. A provided antiferroelectric capacitor demonstrates a record-high ESD of 94 J/cmand a high efficiency of 80%, along with a high maximum power density of 5×10W/kg. The degradation of the energy storage performance as the film thickness increases is alleviated by the above multi-stacked structure, which presents a high ESD of 80 J/cmand efficiency of 82% with the thickness scaled up to 48 nm. This improvement is attributed to the enhancement of breakdown strength due to the barrier effect of interfaces on electrical treeing. Furthermore, the capacitors also exhibit an excellent endurance up to 10operation cycles. 1. An antiferroelectric capacitor , comprising:a first electrode;a main layer formed on the first electrode; anda second electrode formed on the main layer;wherein the main layer comprises one or more antiferroelectric layers and a plurality of interfacial layers, and wherein each of the one or more antiferroelectric layers is sandwiched between two of the plurality of interfacial layers.2. The antiferroelectric capacitor as recited in claim 1 , wherein each antiferroelectric layer is made of a material selected from the group consisting of ZrO claim 1 , HfO claim 1 , and HfZrO claim 1 , where x denotes a fraction.3. The antiferroelectric capacitor as recited in claim 2 , wherein each antiferroelectric layer is further doped with one or more elements selected from the group consisting of Si claim 2 , Y claim 2 , Al claim 2 , La claim 2 , Gd claim 2 , N claim 2 , Ti claim 2 , Mg claim 2 , Sr claim 2 , Ce claim 2 , Sn claim 2 , Ge claim 2 , Fe claim 2 , Ta claim 2 , Ba claim 2 , Ga claim 2 , In claim 2 , and Sc.4. The antiferroelectric capacitor as recited in ...
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