21-11-2019 дата публикации
Номер: US20190352562A1
Disclosed herein are composite fluorescent gold nanoclusters with high quantum yield, as well as methods for manufacturing the same. According to some embodiments, the composite fluorescent gold nanocluster includes a gold nanocluster and a capping layer that encapsulates at least a portion of the outer surface of the gold nanocluster. The capping layer includes a matrix made of a benzene-based compound, and multiple phosphine-based compounds distributed across the matrix. 1. A composite fluorescent gold nanocluster , comprising ,a gold nanocluster; anda capping layer composed of a matrix made of a benzene-based compound, and a plurality of phosphine-based compounds distributed across the matrix;wherein, the capping layer encapsulates at least a portion of an outer surface of the gold nanocluster.2. The composite fluorescent gold nanocluster of claim 1 , wherein the benzene-based compound is selected from the group consisting of benzene claim 1 , alkylbenzene claim 1 , halobenzene claim 1 , phenol claim 1 , benzoic acid claim 1 , acetophenone claim 1 , methyl benzoate claim 1 , anisole claim 1 , aniline claim 1 , nitrobenzene claim 1 , benzonitrile claim 1 , benzamide claim 1 , benzenesulfonic acid claim 1 , naphthalene claim 1 , and anthracene.3. The composite fluorescent gold nanocluster of claim 2 , wherein claim 2 ,the alkylbenzene is toluene, cumene, ethylbenzene, styrene, or xylene; andthe halobenzene is fluorobenzene, chlorobenzene, bromobenzene, or iodobenzene.4. The composite fluorescent gold nanocluster to claim 3 , wherein the benzene-based compound is toluene.5. The composite fluorescent gold nanocluster of claim 1 , wherein the phosphine-based compounds is selected from the group consisting of phosphine claim 1 , phosphine oxide claim 1 , phosphonium claim 1 , diphosphine claim 1 , triphosphine claim 1 , alkyl phosphine claim 1 , cycloalkyl phosphine claim 1 , aryl phosphine claim 1 , aryl phosphine oxide claim 1 , bidentate phosphine claim 1 , silicone ...
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