03-03-2016 дата публикации
Номер: US20160059313A1
Принадлежит:
The disclosure relates to thermoelectric materials prepared by self-propagating high temperature synthesis (SHS) process combining with Plasma activated sintering and methods for preparing thereof. More specifically, the present disclosure relates to the new criterion for combustion synthesis and the method for preparing the thermoelectric materials which meet the new criterion. 115.-. (canceled)16. A method of self-propagating high temperature synthesis (SHS) for a binary compound , comprising{'sub': 'ad', '1) calculating an adiabatic temperatures Texpressed as Equation (1),'}{'sub': f', '298K', '298K, 'sup': '0', 'claim-text': {'br': None, 'sub': f', '298K', 'T', '298K', '298K, 'i': H', '=H', '−H', 'CdT, 'sup': 0', '0', 'T', {'sub2': 'ad'}], '−Δ=∫\u2003\u2003(1)'}, 'wherein ΔHis enthalpy of formation for the binary compound, T is temperature, His the enthalpy of the binary compounds at 298 K, and C is the molar specific heat of the product and the integral includes latent heats of melting, vaporization, and phase transitions, the reactants for the combustion reaction are pure elemental for the binary compounds,'}{'sub': 'p', 'claim-text': {'br': None, 'sub': f', '298K', 'T', '298K', '298K', 'p, 'i': H', '=H', '−H', 'C', 'dT, 'sup': 0', '0', 'T', {'sub2': 'ad'}], '−Δ=∫\u2003\u2003(2)'}, 'when there is no phase transition and the adiabatic temperature is lower than a melting point of the binary compound, the Equation (1) is expressed as Equation (2) shown below, where Cis the the molar specific heat of the product in solid state,'}{'sub': p', 'p', 'm', 'm, 'claim-text': {'br': None, 'sub': f', '298K', 'T', '298K', '298K', 'p', 'm', 'Tm', 'p, 'i': H', '=H', '−H', 'C', 'dT+ΔH', 'C″', 'dT, 'sup': 0', '0', 'T', {'sub2': 'ad'}, 'Tad, '−Δ=∫+∫\u2003\u2003(3)'}, 'when there is no phase transition and the adiabatic temperature is higher than the melting point of the binary compound and lower than a ‘boiling point of of the binary compound, Equation (1) is expressed as ...
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