23-05-2019 дата публикации
Номер: US20190157574A1
Принадлежит:
The invention relates to organic electroluminescent devices, and discloses a phosphorescence device containing heterocyclic phosphoric acid metal complexes. The phosphorescence device provided by the invention contains metal complexes of heterocyclic phosphoric acid auxiliary ligands, and the glass transition temperature of the hole transport material of phosphorescence device is not lower than 85° C. Because a hole transport material with high vitrification temperature is used, the device provided by the invention can overcome the instability of the device and the adverse effect on the service life of the device when the glass transition temperature of the working device when the ambient temperature is above 30-40° C. and the working device temperature is close to that of the hole transport material. Compared with the devices based on FIrpic and TAPC, the phosphorescence device provided by the invention not only has higher device efficiency, but also has better high temperature stability. 3. The phosphorescence device as described in claim 2 , wherein the aromatic group is replaced by a substituted group claim 2 , the substituents are hydrogen atom claim 2 , deuterium atom claim 2 , halogen claim 2 , alkyl claim 2 , naphthyl claim 2 , hetero-alkyl claim 2 , aromatic alkyl claim 2 , alkoxy claim 2 , aryl claim 2 , silyl claim 2 , alkynyl claim 2 , alkenyl claim 2 , aryl claim 2 , heteraryl claim 2 , acyl claim 2 , carbonyl claim 2 , ester group claim 2 , cyanide or its combination.4. The phosphorescence device as described claim 2 , wherein Ar claim 2 , Ar claim 2 , Ar claim 2 , Ar claim 2 , Ar claim 2 , Ar claim 2 , Ar claim 2 , Ar claim 2 , Arare selected from phenyl claim 2 , biphenyl claim 2 , triphenyl claim 2 , tetraphenyl claim 2 , toluene claim 2 , tert-#china_person0# phenyl claim 2 , Methoxy claim 2 , naphthyl claim 2 , anthracene claim 2 , phenanthroline claim 2 , pyrene claim 2 , benzophenyl claim 2 , carbazole claim 2 , thiophene or fluorene ...
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