PROCESS FOR PREPARING PERFLUORINATED ETHERS

14-08-1979 дата публикации
Номер:
CA1060482A
Принадлежит: HOECHST AG, HOECHST AKTIENGESELLSCHAFT
Контакты:
Номер заявки: 238542
Дата заявки: 29-10-1975



PROCESS FOR PREPARING PERFLUORINATED ETHERS Perfluorinated ethers containing carboxylic acid fluoride groups and optionally units derived from hexafluoropropene epoxide or tetrafluoroethylene epoxide are reacted with fluorine at temperatures of from 50 to 350.degree.C in the presence of metallic catalysts. During the reaction carbonyl difluoride is splitt off and an ether is obtained in high yield which is free of carboxylic acid fluoride groups. Metallic silver is well suited as catalyst.