HYDROGENATION OF CYCLOPENTADIENE TO FORM CYCLOPENTENE
01-12-1981 дата публикации
Номер:
CA1113510A
Автор: MENAPACE HENRY R, MENAPACE, HENRY R.
Принадлежит: GOODYEAR TIRE & RUBBER, GOODYEAR TIRE & RUBBER COMPANY (THE)
Контакты:
Номер заявки: 331038
Дата заявки: 03-07-1979
IMPROVEMENT IN HYDROGENATION OF CYCLOPENTADIENE TO FORM CYCLOPENTENE There is disclosed an improved process for selectively hydrogenating cyclopentadiene to form cyclopentene in the presence of a catalyst comprising (A) a hydrocarbon-soluble nickel compound such as nickel salts of carboxylic acids or organo nickel compounds, (B) an organo reducing agent such as organoaluminum compounds or lithium alkyl compounds and (C) pyridine, the improvement being that the soluble nickel compound and the pyridine are employed in amounts wherein the mole ratio of aluminum or lithium to the nickel ranges from 7/1 to 11/1 and the mole ratio of the pyridine to the nickel compound ranges from 1/1 to 2.5/1.