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The present invention refers to organic light emitting devices relates to high efficiency properties, more particularly organic light emitting light emitting layer or a multilayer structure of dopant material used in host material by using, blue light emission with high efficiency are disclosed. (Organic light emitting diode, OLED) using a magnetic layer of a mixed organic light emitting surface of the light transmissive, thin large viewing angle as compared to a liquid crystal display, can be reflected and, fast response time have a steering wheel pull - color (full-a color) display or a lighting applications to expected disclosed. Packed in said organic light-emitting device according to materials used in the function layer, light-emitting material and a charge transporting material, such as a hole injection material, hole transporting material, an electron transport material, electron injection in order to remove can be classification. In addition, light emitting mechanism of the former along said material comprises a fluorescent material and derived from singlet phosphor material can be derived from electron triplet classification. On the other hand, when only one substance as a luminescent material, an intermolecular interaction by isolating means is moved in the long wavelength emission wavelength can fall out of the maximum thickness of the light emitting electric door number is reduced to comparison, increased safety device through one or more energy transitions in order to increase the host as a luminescent material for a luminescent dopant system - can. Energy band gap and pressure are formed in the light emitting layer host than small dopant small mixing, transported to a high efficiency light generated in a light emitting layer dopant into at 1000 ppm are disclosed. The, wavelength of dopant wavelength moves as host, depending on the type of dopant using a desired light in a wavelength can be achieved. This luminous layer dopant compounds as prior art Public Patent Notification number 10 - 2008 - 0015865 (2008. 02. 20) Include aryl amine indenofluorene derivatives such as coupled using organic and disclosure, Public Patent Notification number 10 - 2012 - 0047706 call (20012. 05. 14) In one intramolecular dibenzo furan or dibenzothiophene is exist or flue , benzofuran or dibenzothiophene is along with a carbazole compounds of the following structure using organic disclosure in the nanometer range. In addition light emitting layer host compounds as prior art Public Patent Notification number 10 - 2015 - 0043020 call (2015. 04. 22) Mixture for organic light emitting device including the fluorescent host usable as disclosed. However, said prior art preceding a nucleotide including better efficiency despite the need for development of organic light emitting devices are provided which is continuously being requested. Public Patent Notification number 10 - 2008 - 0015865 (2008. 02. 20) Public Patent Notification number 10 - 2012 - 0047706 call (2012. 05. 14) Public Patent Notification number 10 - 2015 - 0043020 call (2015. 04. 22) Thus, the technical objectives of this invention is a specific structure of high efficiency through the host with a dopant having a novel organic light-emitting device (organic light emitting diode, OLED) number are disclosed. The present invention refers to said specific techniques for in order to number, number 1 electrode; said number 1 number 2 electrode opposed to the electrode; and said number 1 and light emitting layer electrode for said number 2; including the organic light emitting device, [Formula A] or [formula B] to said light emitting layer is represented by amine compound; and [formula C] has a pyrene compound; at least one of which, in addition to [formula D] represented by compound; organic material including a number substrate. [Formula A] [Formula B] In said [formula A] and [formula B], A1, A2, and mutually the same or different from each E and F hereinafter, a substituted or unsubstituted aromatic hydrocarbon of 6 to 50 carbon atoms independently of each other a ring, or a substituted or unsubstituted aromatic heterocyclic and C12 2 to 40; Said A1 and two adjacent carbon atoms in an aromatic ring, an aromatic ring together with the carbon atoms in said W said A2 in adjacent two annular 5 by forming each fused ring form; Said connector L1 To L12 To the insulating layer and each hereinafter, are each independently a single bond, a substituted or unsubstituted 1 to 60 C12 alkylene, C12 justice neel the [khey which it will know [leyn 2 to 60 substituted or unsubstituted, a substituted or unsubstituted alkynyl in range of 2 to 60 C12, C12 claw alkyl [leyn justice at the time of a substituted or unsubstituted 3 to 60, 60 to a substituted or unsubstituted heterocyclic inhibitors of C12 2 hour claw alkyl [leyn, 6 to 60 it will be biting, [leyn of C12 substituted or unsubstituted or a substituted or unsubstituted heterocyclic inhibitors of C12 it will be biting, [leyn 2 to 60 in selected; The CR said W1 R2 , SiR1 R2 , GeR1 R2 , O, S, NR1 In selected, the M N a-R3 , CR4 R5 , SiR6 R7 , GeR8 R9 , O, S, Se selected among resistant; Said substituent R1 To R9 , To the first partition and the same or different from Ar1 Ar8 hereinafter, are each independently a hydrogen, deuterium, a substituted or unsubstituted alkyl 1 to 30 C12, C12 50 6 to a substituted or unsubstituted aryl, a substituted or unsubstituted 2 to 30 between the light-emitting of C12, C12 to a substituted or unsubstituted alkynyl of 2 to 20, a substituted or unsubstituted cycloalkyl group of 3 to 30 C12, 5 to 30 between the light-emitting C12 substituted or unsubstituted cycloalkyl, substituted or unsubstituted heteroaryl group of C12 2 to 50, 2 to 30 C12 heterocyclic inhibitors of a substituted or unsubstituted cycloalkyl, substituted or unsubstituted alkoxy group C12 1 to 30, 30 to a substituted or unsubstituted 6 of C12, C12 1 to 30 substituted or unsubstituted alkyl, substituted or unsubstituted carbon atoms of 6 to 30 substituted, 1 to 30 hydroxybutyrolactone C12 substituted or unsubstituted alkyl, a substituted or unsubstituted C12 of 6 to 30, 30 to a substituted or unsubstituted 1 C12 alkyl silyl group, a substituted or unsubstituted C12 of 6 to 30, 30 to 1 germanium C12 substituted or unsubstituted alkyl, a substituted or unsubstituted carbon atoms of 6 to 30 germanium it will be biting a cyano group, nitro, halogen is but the which it should to at least one selected from, Said R1 And R2 Are each connected alicyclic, aromatic polycyclic forms a ring can be a single ring aromatic compound, formed said alicyclic, aromatic single ring aromatic polycyclic ring carbon atoms N, O, P, Si, S, Ge, Se, Te selected from among one or more heteroatoms can be substitutionally replaced; An integer of 1 to 3 to each said p1 to p4, r1 r4, s1 to s4 is, these each 2 L or more each connector1 To L12 Hereinafter and the same or different from each other, Said x is integer number of 1 or 2, and the same or different from each y and z hereinafter, positive numbers of 0 to 3 independently of each other, Said Ar1 and Ar2, Ar4 Ar3 and, on Ar6 Ar5, and Ar7 Ar8 forms a ring can be connected and the first partition; In adjacent two carbon atoms of said ring in said formula A formula Q1 * A2 by being coupled fused ring is formed, Said A1 in adjacent two carbon atoms of said ring in said formula B formula Q2 * by being coupled fused ring is formed, said A2 in adjacent two carbon atoms of said ring structure Q1 * and form fused ring by being coupled. [Formula C] In said [formula C], R11 to R16 and the same or different from the first partition hereinafter, are each independently a hydrogen, deuterium, a substituted or unsubstituted alkyl 1 to 30 C12, C12 50 6 to a substituted or unsubstituted aryl, a substituted or unsubstituted 2 to 30 between the light-emitting of C12, C12 to a substituted or unsubstituted alkynyl of 2 to 20, a substituted or unsubstituted cycloalkyl group of 3 to 30 C12, 5 to 30 between the light-emitting C12 substituted or unsubstituted cycloalkyl, substituted or unsubstituted heteroaryl group of C12 2 to 50, 2 to 30 C12 heterocyclic inhibitors of a substituted or unsubstituted cycloalkyl, substituted or unsubstituted alkoxy group 1 to 30 C12, C12 6 to 30 of a substituted or unsubstituted, a substituted or unsubstituted alkyl C12 1 to 30, carbon atoms of 6 to 30 is substituted in substituted or unsubstituted, 1 to 30 hydroxybutyrolactone C12 substituted or unsubstituted alkyl, a substituted or unsubstituted C12 of 6 to 30, 30 to a substituted or unsubstituted 1 C12 alkyl silyl group, a substituted or unsubstituted C12 of 6 to 30, 30 to 1 germanium C12 substituted or unsubstituted alkyl, a substituted or unsubstituted C12 germanium it will be biting of 6 to 30, cyano group, nitro, catalyst in a halogen is selected from, Said R11 to R16 substituent are not aromatic ring carbon is coupled hydrogen and deuterium, Said h, i, j, k is an integer 0 to 3 respectively, R11 to R14 are each the same or different from each they 2 or more each and hereinafter, Said l and m is an integer 0 to 4 respectively, each R15 and R16 are identical to each other or different from each or more 2 they and hereinafter, Said R11 to R14 are each adjacent X1 to X8 on or connected to each other, or R11 to R14 each R11 to R14 on or more 2 respectively connected to each other alicyclic, aromatic polycyclic forms a ring can be a single ring aromatic compound, formed said alicyclic, aromatic single ring aromatic polycyclic ring carbon atoms N, O, P, Si, S, Ge, Se, in one or more heteroatoms selected from Te can be substitutionally replaced; Said X1 to X8 and hereinafter the same or different from the first partition, are each independently a hydrogen, deuterium, alkyl of 1 to 20 carbon atoms selected from substituent is but a substituted or unsubstituted, At least one said X1 to X8 X1, X2, X5 and X6 is a substituted or unsubstituted alkyl C12 1 to 20 are disclosed. [Formula D] In said [formula D], A substituted or unsubstituted substituted Ar9 6 to 50 is C12 aryl, or a substituted or unsubstituted heterocyclic inhibitors of C12 R and 2 to 50, Said R21 to R28 and or different socket are hereinafter, are each independently a hydrogen, deuterium, 1 to 30 C12 substituted or unsubstituted alkyl, a substituted or unsubstituted 2 to 30 between the light-emitting of C12, C12 for 2 to 30 of a substituted or unsubstituted alkynyl, substituted or unsubstituted cycloalkyl group of 3 to 30 C12, C12 cycloalkyl substituted or unsubstituted 5 to 30 between the light-emitting, 1 to 30 C12 substituted or unsubstituted alkoxy group, a substituted or unsubstituted C12 of 6 to 30, 1 to 30 C12 substituted or unsubstituted alkyl, a substituted or unsubstituted C12 of 6 to 30, 1 to 30 hydroxybutyrolactone C12 substituted or unsubstituted alkyl, a substituted or unsubstituted C12 of 6 to 30, 6 to 50 carbon atoms substituted or unsubstituted aryl, and a substituted or unsubstituted heterogeneous reactor O, having 2 to 50 carbon atoms or N S of a heteroaryl group, a substituted or unsubstituted 1 to 30 C12 of silyl group, cyano group, nitro, halogen to, among selected, Said R29 is deuterium, C12 1 30 to a substituted or unsubstituted alkyl, a substituted or unsubstituted 6 with allyl of C12 to 50 and selected from, Said linking group L is single bond, a substituted or unsubstituted 1 to 60 C12 alkylene, C12 justice neel the [khey which it will know [leyn 2 to 60 substituted or unsubstituted, a substituted or unsubstituted alkynyl in range of 2 to 60 C12, C12 claw alkyl [leyn justice at the time of a substituted or unsubstituted 3 to 60, 60 to a substituted or unsubstituted heterocyclic inhibitors of C12 2 hour claw alkyl [leyn, 6 to 60 it will be biting, [leyn of C12 substituted or unsubstituted or a substituted or unsubstituted heterocyclic inhibitors of C12 it will be biting, [leyn 2 to 60 in selected, X of '***' is binding with site and said connector L, Wherein, said [formula A], [formula B], [formula C] and [formula D] displayed in that 'a' in 'substituted or unsubstituted substituted' is deuterium, cyano group, a halogen, hydroxy, nitro, alkyl of 1 to 24 carbon atoms, 1 to 24 carbon atoms halogenated alkyl, 2 to 24 carbon atoms of the light-emitting, for alkynyl of 2 to 24 carbon atoms, heterocyclic inhibitors of 1 to 24 carbon atoms alkyl, 6 to 24 carbon atoms aryl, aryl-alkyl of 7 to 24 carbon atoms, aryl group or heterocyclic inhibitors of 2 to 24 carbon atoms 2 to 24 carbon atoms a variety of aryl-alkyl, alkoxy of 1 to 24 carbon atoms, 1 to 24 carbon atoms of alkyl-amino group, amino it will be biting 6 to 24 carbon atoms, 1 to 24 carbon atoms a variety of amino it will be biting, 1 to 24 carbon atoms alkyl silyl group, 6 to 24 carbon atoms of , with biting jade time of 6 to 24 carbon atoms selected from the group consisting of at least one substituted 1 which means that the other. Organic light-emitting device according to the present invention according to prior art can exhibit the effect of improved efficiency more than the organic light-emitting device. Figure 1 shows a schematic diagram of the organic light emitting device according to embodiments of the present invention also one are disclosed. Hereinafter, the present invention more detailed as follows. The present invention refers to said specific techniques for in order to number, number 1 electrode; said number 1 number 2 electrode opposed to the electrode; and said number 1 and light emitting layer electrode for said number 2; including the organic light emitting device, Said light emitting layer is represented by [formula A] or [formula B] said amine compound; and [formula C] has a pyrene compound; at least one of which, in addition said compound represented by [formula D]; organic material including a number substrate. On the other hand, in the present invention of said "C12 alkyl substituted or unsubstituted 1 to 30", "a substituted or unsubstituted 5 to 50 C12 aryl" range disposed on the side of the alkyl or, said carbon number of 5 to 50 carbon atoms 1 to 30 carbon atoms alkyl and each said substituent is substituted portion range without regard a substituted or unsubstituted alkyl or aryl portion when portion which the arrangement meaning that the carbon number are disclosed. For example, butyl substituted carbon atoms substituted at the para-position of the phenyl carbon atoms to a corresponding aryl phosphate of butyl 4 6 must substrate. Aryl substituted compounds of the present invention used in number one hydrogen by volatile organic radicals derived from aromatic hydrocarbons due, 5 to 7 won, preferably including a single or fused ring orgin 5 or 6 won which, when fuse (fused) to an aryl phosphate in addition said substituents at the neighboring substituent can be further formed. Specific examples said phenyl, non-phenyl o -, m - non-phenyl, p - non-phenyl, o -, m - , p - , me [phu, inside [thu reel, lung difficulty [thu reel, blood [ley neel, indenyl, five [ley neel and process for preparation thereof, draw or [phu 2, [leyn one vinyl, cryo imidazole, imidazole naphtha, aromatic group such as cited five column [theyn one process for preparation thereof, said one or more hydrogen atom of the aryl group deuterium atoms, halogen atom, hydroxy, nitro, cyano group, silyl group, amino group (- NH2 , - NH (R), - N (R ') (R "), R' and R" 1 to 10 carbon atoms and alkyl independently of each other, in this case a multi-"alkyl-amino group"), amino, hydrazine to, , carboxyl group, a sulfonic acid group, phosphoric acid, alkyl of 1 to 24 carbon atoms, 1 to 24 carbon atoms halogenated alkyl, of 1 to 24 carbon atoms between the light-emitting, for 1 to 24 carbon atoms of alkynyl, hetero alkyl of 1 to 24 carbon atoms, 6 to 24 carbon atoms aryl, aryl-alkyl of 6 to 24 carbon atoms, aryl group or heterocyclic inhibitors of 2 to 24 carbon atoms can be substituted heterocyclic inhibitors of 2 to 24 carbon atoms . N hetero aryl substituted compounds of the present invention use due, O, P, Si, S, Ge, Se, 1, 2 or 3 hetero atoms selected from Te of, the remaining ring atoms is 2 to 24 ring aromatic system which means C12 carbon may be used, said fused rings (fused) to an can be formed. And said one or more hydrogen atoms substituted heteroaryl group when said similar to pivotably. In addition in the present invention said aromatic heterocyclic aromatic ring carbon producing aromatic hydrocarbons by the one or more N, O, P, Si, S, Ge, Se, Te been substitutionally replaced one or more heteroatoms selected from meaning that the other. Specific examples used in the present invention due alkyl substituted methyl, ethyl, propyl, isopropyl, isobutyl, sec - butyl, tert - butyl, neopentyl, iso - amyl, hexyl or the like cited, when said at least one of said substituted alkyl hydrogen atoms atoms similar to pivotably. Specific examples of the present invention compound used in due alkoxy substituted methoxy, ethoxy, propoxy, [thil jade city, sec - butyl oxy, pen [thil jade city, iso - oh wheat jade city, such as ethylhexyloxy cited, said one or more hydrogen atoms substituted alkoxy when said similar to pivotably. Specific examples of the present invention substituted compounds due thread reel using trimethylsilyl, tree [thil it will be recorded, phenyl thread reel tree, tree , the d maul [thok hour phenyl it will be recorded, the d phenyl methyl it will be recorded, silyl, the d phenyl vinyl it will be recorded, methyl the gap claw view [thil it will be recorded, such as the [phyu the reel it will be recorded dimethyl cited, wherein said one or more hydrogen atoms substituted similar to when said pivotably. In the present invention according to said formula A or formula B amine compound is represented by said formula A in organic light-emitting device, including the formula Q1 is connected to a ring when said Ar1 Ar2 A2 and A2 has a structural features into engagement with the ring amine must, in addition formula B formula Q2 in A1 is connected to the ring, the formula Q1 is bound to said A2 A2 ring is a ring including an amine including structural features and Ar2 Ar1 must have. In addition, in the present invention said formula A or formula B A in1 , A2 , And the same or different from each E and F hereinafter, a substituted or unsubstituted aromatic hydrocarbon of 6 to 50 carbon atoms independently of each other can be a ring. Such as said, A1, A2 in formula A or formula B, E and F hereinafter respectively and the same or different, are each independently a substituted or unsubstituted aromatic hydrocarbon ring of 6 to 50 C12 numbers, a substituted or unsubstituted aromatic hydrocarbon ring of 6 to 50 said C12 and hereinafter the same or different, [formula 10] to [formula 21] independently of each other can be selected from any one. [Formula 10] [formula 11] [formula 12] [Formula 13] [formula 14] [formula 15] [Formula 16] [formula 17] [formula 18] [Formula 20] [formula 21] [formula 19] [Formula 10] to [formula 21] "- *" is in said W said annular forming or including 5 a, or said Q formula1 And Q2 A means for forming an annular binding site M including 5 in which, Said [formula 10] to [formula 21] aromatic hydrocarbon ring A1 A ring or2 While ring corresponding to formula Q1 Or formula Q2 If among these adjacent two carbon atoms bind to said Q formula1 Of formula Q * or engage with an2 * Of fused ring by being coupled to form; [Formula 10] to [formula 21] said aforementioned defined in said R R1 And R2 Is equal to, and m is an integer 1 to 8, m is 2 or more, 2 or more R or R is each be the same or different each other. In addition in the present invention, said formula A and formula B L in connector1 To L12, In formula D and L and socket are attached to or different from the hereinafter, single bond or, below [formula 22] to [formula 30] can be selected from any one. [Formula 22] [formula 23] [formula 24] [formula 25] [Formula 26] [formula 27] [formula 29] [formula 28] [Formula 30] Said linking group can be an aromatic ring carbon seats is coupled in hydrogen or deuterium. As the present invention according to one in the embodiment, in each said [formula A] or [formula B] to 1 or 2 and to s4 p1 p4, r1 to r4, s1, Wednesday 1 x is which, as in the embodiment 1 and each one more specific x and y, Wednesday 1 z is 0 or 1. As one in the embodiment, of the present invention represented by R1 to R9 [formula A] or [formula B] amine compound in substituents, the same or different from the first partition to Ar8 Ar1 and hereinafter, are each independently a hydrogen, deuterium, 6 to 20 C12 substituted or unsubstituted aryl, a substituted or unsubstituted 3 to 30 of C12 cycloalkyl group, a substituted or unsubstituted heterogeneous nuclear reactor and O, N, selected from one or more of Si and S C6 having 2 to 20 heteroaryl group, cyano group, halogen stability and either be a. [Formula A] or [formula B] in addition of the present invention based on the amine compound in, said A1, A2, E, F, Ar8, L1 to L12, R1 to R9 substituents in 'substituted' Ar1 to the cyano group, a halogen, alkyl of 1 to 6 carbon atoms, 6 to 18 carbon atoms aryl, aryl-alkyl of 6 to 18 carbon atoms, a heteroaryl group of 3 to 18 carbon atoms, 1 to 12 carbon alkyl silyl group, 6 to 18 carbon atoms selected from the group consisting of any one be a. On the other hand, organic light-emitting device in the present invention according to said formula C represented by pyrene represented in blood [leyn in structure described in picture 1, aryl amine supports located at 3, 8 can be. [Picture 1] Wherein, said coupled blood [leyn two aryl amine respectively, each coupled to at least one nitrogen atom as a reference position (ortho -) aryl aryl group a substituted or unsubstituted nitrogen atoms five [lu C12 alkyl substituted with 1 to 20 characterized by a microprocessor. I.e., represented by said formula C pyrene compounds, said X1 To X8 At least X1, X2, X5 X and6 A substituted or unsubstituted substituted alkyl of 1 to 20 C12 is characterized. In this case, the designated adjacent substituents are connected to one another in said contained within allyl substituted alicyclic, aromatic polycyclic forms a ring can be a single ring aromatic compound, formed said alicyclic, aromatic single ring aromatic polycyclic ring carbon atoms N, O, P, Si, S, Ge, Se, in one or more heteroatoms selected from Te can be substitutionally replaced. On the other hand, in said formula C said h, i, j, k each integer number of 0 to 2, 2 each R11 to R14 each when they be the same or different each other. In addition, R11 to R16 and socket are in said formula C or different hereinafter, are each independently a hydrogen, deuterium, a substituted or unsubstituted alkyl 1 to 30 C12, C12 50 6 to a substituted or unsubstituted aryl, a substituted or unsubstituted 3 to 30 of C12 cycloalkyl group, a substituted or unsubstituted alkoxy group 1 to 30 C12, C12 alkyl silyl group substituted or unsubstituted 1 to 30, a substituted or unsubstituted 6 to 30 can be selected from any one of C12 . In addition said formula C substituents R15 and R16 each represented pyrene compound be a hydrogen or deuterium. In addition, in the present invention said formula C two amine groups can be represented by pyrene compound is identical to one another, said two amine groups such as halogenated blood [leyn blood [leyn with the same di bromo when the same kind of amine can be obtained by reacting. In addition said formula C represented pyrene compounds are two amine groups on each other hereinafter can be asymmetric, two different amine groups if each different types of amine can be sequentially obtained by reacting. Said sequentially different amine such as when coupled one after reacting the amine radical as an intermediate deformation pyrene derivatives can be reacted with new number in a following step. If said obtained pyrene derivatives such as two different amine are obtained as the asymmetric compound to be coated. On the other hand, in the present invention represented by said formula D of compounds are as represented in picture 2 below, anthracene ring 9 is electrically coupled to the position L, or said anthracene is where there is a connectors directly, either substituted or unsubstituted phenyl ring carbon atoms and a dibenzo [phyu column 1 time or 2 position in which, in addition, R29 is substituted at positions opposite ring 6 carbon atoms characterized coupled to a microprocessor. Wherein, said substituent R29 is deuterium, C12 1 30 to a substituted or unsubstituted alkyl, a substituted or unsubstituted 6 with allyl of C12 to 50 may be selected from, preferably, a substituted or unsubstituted alkyl C12 1 to 30, C12 aryl selected from a substituted or unsubstituted 6 to 50 can be. [Picture 2] The present invention according to organic light emitting device with the light emitting layer includes a dopant and by host, Said amine compound represented by [formula A] or [formula B]; and [formula C] pyrene compound represented; and each used as dopant, said host compounds are used as represented by [formula D] by, according to the prior art may have the effect of blue light emission efficiency. In addition, in the present invention said formula D Ar9 of anthracene compounds can be represented by [formula 31] is substituted for. [Formula 31] [Formula 31] "- ****" in said formula D to said coupling site and is of anthracene, Said substituents R31 to R35 and hereinafter is used in the same or different, are each independently a hydrogen, deuterium, a substituted or unsubstituted alkyl 1 to 30 C12, C12 50 6 to a substituted or unsubstituted aryl, a substituted or unsubstituted cycloalkyl group of 3 to 30 C12, C12 substituted or unsubstituted heteroaryl group of 2 to 50, 1 to 30 carbon atoms selected from a substituted or unsubstituted alkoxy group substituted residue. In addition, in each of the present invention said formula D R21 to R28 and R31 to R35 substituents may be hydrogen or deuterium, or a single bond in said formula D L, it will be biting, [leyn fixed date of 6 to 20 carbon atoms or a substituted or non-substituted be. On the other hand, in the present invention [formula A] or [formula B] of said amine compound that is represented by [formula 1] to [formula 239] can be a selected from one, is not limited. Formula 1 formula 2<><><>formula 3 Formula 5 formula 4<><><>formula 6 Formula 7<>< > <>formula 8 formula 9 Formula 10><<><>formula 12 formula 11 Formula 13 > <><formula 15><formula 14 Formula 16><><><formula 17 formula 18 Formula 19 > <><formula 21><formula 20 Formula 22><><formula 24><formula 23 Formula 25<><formula 26 > <>formula 27 Formula 28>><formula 30><<formula 29 Formula 31<><formula 32><>formula 33 Formula 35><><><formula 34 formula 36 Formula 37<><formula 38><>formula 39 Formula 41 > <> > <<formula 40 formula 42 Formula 43<>< > <>formula 45 formula 44 Formula 47<><>formula 48><formula 46 Formula 49< > <><formula 51>formula 50 Formula 54>><><<formula 52 formula 53 Formula 55<><><>formula 57 formula 56 Formula 58<><formula 59><>formula 60 Formula 61<><><formula 63>formula 62 Formula 64<><formula 65><>formula 66 Formula 67<><formula 68><>formula 69 Formula 70<><><formula 72>formula 71 Formula 73<><formula 74><>formula 75 Formula 76<><><formula 78>formula 77 Formula 79< > <><formula 81>formula 80 Formula 82<><formula 83><>formula 84 Formula 85<><formula 86><>formula 87 Formula 88<><formula 89 > <>formula 90 Formula 91<><formula 92 > <>formula 93 Formula 94<><><>formula 96 formula 95 Formula 97<><formula 98><>formula 99 Formula 100 > < > <formula 101<>formula 102 Formula 104 > < > <formula 105><formula 103 Formula 106< > <formula 107 > <>formula 108 Formula 110 formula 109< > < > <>formula 111 Formula 112< > < > <formula 114>formula 113 Formula 115< > <formula 116 > <>formula 117 Formula 118< > < > <>formula 120 formula 119 Formula 121< > <formula 122 > <>formula 123 Formula 124 > << > <>formula 125 formula 126 Formula 127< > <formula 128 > <>formula 129 Formula 130< > <formula 131 > <>formula 132 Formula 133< > < > <formula 135>formula 134 Formula 136< > <formula 137 > <>formula 138 Formula 139< > <formula 140 > <>formula 141 Formula 142< > < > <formula 144>formula 143 Formula 145< > <formula 146 > <>formula 147 Formula 148< > <formula 149 > <>formula 150 Formula 151< > <formula 152 > <>formula 153 Formula 155< > <formula 156> > <formula 154 Formula 157< > <formula 158 > <>formula 159 Formula 160< > <formula 161 > <>formula 162 Formula 163< > <formula 164 > <>formula 165 Formula 166< > <formula 167 > <>formula 168 Formula 169< > <formula 170 > <>formula 171 Formula 172< > <formula 173 > <>formula 174 Formula 175< > <formula 176><>formula 177 Formula 178< > <formula 179 > <>formula 180 Formula 181< > <formula 182 > <>formula 183 Formula 184< > < > <formula 186>formula 185 Formula 187< > <formula 188 > <>formula 189 Formula 190< > <formula 191 > <>formula 192 Formula 193< > <formula 194 > <>formula 195 Formula 196< > < > <formula 198>formula 197 Formula 199< > <formula 200 > <>formula 201 Formula 202< > < > <formula 204>formula 203 Formula 205< > <formula 206 > <>formula 207 Formula 208< > < > <>formula 210 formula 209 Formula 211< > <formula 212 > <>formula 213 Formula 214< > <formula 215 > <>formula 216 Formula 217< > <formula 218 > <>formula 219 Formula 220< > <formula 221 > <>formula 222 Formula 223< > <formula 224 > <>formula 225 Formula 226< > <formula 227 > <>formula 228 Formula 229< > <formula 230 > <>formula 231 Formula 232< > <formula 233 > <>formula 234 Formula 235< > <formula 236 > <>formula 237 Formula 238< > <>formula 239 In addition in the present invention [formula C] of [formula 240] to [formula 284] pyrene compound that is represented by said selected can be a either, the number is not one. Formula 240<><formula 241><>formula 242 Formula 243<><formula 244><>formula 245 Formula 246<><><formula 248>formula 247 Formula 249<><formula 250><>formula 251 Formula 252<><formula 253><>formula 254 Formula 255<><formula 256><>formula 257 Formula 258<><formula 259><>formula 260 Formula 261<><formula 262><>formula 263 Formula 264<><formula 265><>formula 266 Formula 267<><formula 268><>formula 269 Formula 270<><formula 271><>formula 272 Formula 273<><formula 274><>formula 275 Formula 276<><><formula 278>formula 277 Formula 279<><formula 280><>formula 281 Formula 282<><><formula 284>formula 283 In addition, in the present invention said formula D [compound 1] to [compound 30] compounds represented by either can be a selected, the number is not one. 1 Compound 2 compound 3><><><compounds 4><><Compound 6><compound 5 compounds 7><><Compound 9><compound 8 compounds 10><><Compound 12><compound 11 compounds 13 14 15>>><Compound<compound<compounds 16 17 18>>><Compound<compound<compounds 19 20 21>>><Compound<compound<compounds Compound 22 23 24>>><compound<<compounds 25 26 27>>><Compound<compound<compounds Compound 28 29 30>>><compound<<compounds In the embodiment of the present invention as one, the present invention refers to number 1 electrode; said number 1 number 2 electrode opposed to the electrode; and said number 1 and light emitting layer electrode for said number 2; and, in the present invention represented by [formula A] or [formula B] of said amine compound; and [formula C] has a pyrene compound; wherein each helical twisting power, said as a host compound can be represented by [formula D]. The, in the present invention implies "1 comprising at least one organic compound (organic layer)", "(organic layer) of the present invention category belonging to 1 species of organic compound or said organic compound comprising a compound of at least one different belonging to category 2 can be" can be interpreted as. The, said reaction within the content of typically about 100 to about 0 in an host light emitting dopant. 01 To about 20 parts by weight of can be is selected from the range, limited to are not correct. In addition said emissive layer host with a dopant in said various host in addition various dopant further include materials can. In the present invention including a dopant in said host of said light emitting layer has a amine compound [formula A] or [formula B]; and [formula C] pyrene compound represented; suitable substituents in the selection, host compound represented by compound used [formula D]; through proper choice of light emitting can be more effectively implement. In addition, in addition said of the present invention acts as an electron hole injection layer, hole transporting layer, a hole injection function and hole transport used as functional layer, an electron transport layer, an electron injection layer additionally contains at least one of selected and can. While in the present invention said electron transport include an electron injection electrode (Cathode) from stably delivering electrons injected to those which function can be publicly known as of electron transport material. Examples of publicly known of electron transport materials, quinoline derivatives, in particular tris (8 - ) aluminum (Alq3), TAZ, Balq, bis (benzo [khwi glow - 10 - hexanoate) beryllium (beryllium bis (benzoquinolin provided 10 a-olate: Bebq2), ADN, compound 201, compound 202, BCP, oxadiazole derivative PBD, BMD, such as four-line material but BND, limited to are not correct. TAZ BAlq <Compound 201 202>><compounds < BCP> Organic light emitting through broadcast receiver 1 also described hereinafter of the present invention. Figure 1 shows a cross-section indicating the structure of the organic light emitting device of the present invention also are disclosed. The present invention according to acts as an anode (20), hole (40), an organic luminous layer (50), alkali metal-containing fullerene (60) and a cathode (80) which, if necessary hole injection (30) and with an (70) can be further includes, in addition to the 1 or 2 which further pattern has an intermediate layer, and further forming a hole obstruction layer or electronic a field oxidation disapproval. The organic light emitting diode manufacturing method of the present invention with reference to the residual also 1 as follows. First substrate (10) for upper located one or more anode (20) and form. Wherein the substrate (10) is provided for use in conventional organic EL substrate of which transparency, surface smoothness, handling water-resistant organic substrate or transparent plastic substrate preferably selectively. And, indium tin oxide (ITO) anode electrode for title search using a polymer electrolyte clear, zinc indium oxide (IZO), tin oxide (SnO2 ), Zinc oxide (ZnO) etc.. Said anode (20) electrode hole injection layer material to vacuum thermal deposition, or spin coating to hole injection layer (30) formed on the substrate. Then said hole injection layer (30) by vacuum thermal deposition or spin coating on top of the transport layer material hole (40) formed on the substrate. Said hole injection material is typically used in which the art not specially number can be one using, e.g. [4, 4 ', 4" - tris (2 a-naphthylphenyl non-phenylamino) - triphenylamine] 2 a-TNATA, NPD [N, N' - di (1 a-naphthyl) - N, N'- diphenylbenzidine)], TPD [N, N' - diphenyl-a N, N'- bis (3 a-methylphenyl) - 1, 1' - biphenyl-a 4, 4 '- diamine], DNTPD [N, N' - diphenyl-a N, N'- bis - [4 - (phenyl-a m-a tolyl a-amino) - phenyl] - biphenyl-a 4, 4' - diamine] can be use. The present invention but are not necessarily limited to are not correct. In addition said contrast material it is to become a number one hole commonly used particularly not, e.g., N, N'- bis (3 - methylphenyl) - N, N' - diphenyl - [1, 1 - biphenyl] - 4, 4 '- diamine (TPD) or N, N' - di (naphthalene - 1 - yl) - N, N' - d phenyl [peyn_ci (a non-NPD) can be use. The present invention but are not necessarily limited to are not correct. Then, said hole (40) on top of an organic luminous layer (50) said laminated an organic luminous layer (50) (not shown) hole obstruction layer selectively on top of vacuum deposition method, or spin coating method can be as thin film. Said timing relay having the organic function layer cathode hole obstruction layer through holes of life is reduced efficiency HOMO (Highest Occupied Molecular Orbital) level by using very low material preventing such door number could be bonded each other. At this time, a hole transport material are specially used but one number higher ionization potential should have electronic transport capacity 802.11a packets while having light-emitting compound which typically BAlq, BCP, can be TPBI is used as the alkali. This hole from harmful alkali metal-containing fullerene (60) vacuum deposition method, or spin coating method after deposited with an (70) is formed with an said (70) on top of a metal layer cathode vacuum thermal deposition by cathode (80) electrode layer 4 on a substrate the organic EL element. A silicon carbide single crystal for forming cathodes in a excitation (Li), magnesium (Mg), aluminum (Al), aluminum - lithium (Al provided Li), calcium (Ca), magnesium (Mg provided In) indium -, magnesium - (Mg a-Ag) can be the use, in order to obtain the ITO front element, IZO using transmissive cathode can be used. In addition, the embodiments of the present invention, said light emitting layer has a thickness preferably in 50 to 2,000 Å. In addition, in the present invention said hole injection layer, hole transport layer, a hole injection function and hole transport used as functional layer, electronic obstruction layer, light emitting layer, hole obstruction layer, with an alkali metal-containing fullerene and deposited on the monomolecular layer is selected from one or more can be formed by processes or solution. Wherein said light is deposited on the material used for the material for forming the heated in vacuum or low pressure state thin film is formed by a method such as evaporation through components, said solvent solution for forming each layer of the material used for the same material is mixed with an inkjet printing, roll-to-roll coating, screen printing, spray coating, dip coating, thin film formation method such as spin coating method through means other. In addition in the present invention first and second of said flat panel display device; flexible display device; and monochrome or white for plane light source device; and monochrome or white flexible for illumination device; selected from one device can be used. Hereinafter, the present invention for example preferred embodiment more detailed as follows. However, the present invention is more specifically to account for these in the embodiment, of the present invention is not one that the party industry to range the person with skill in the art will-case number. (In the embodiment) I. Number attainments of the dopant compound Synthesis example 1: synthesis of formula 1 Synthesis example 1 - (1): synthesis of intermediates 1 a-a A compound according to 1, intermediate 1 a-a and copiers. 1><Reactive 1 A-a><intermediates Methyl 5 - bromo - 2 - 500 ml reactor eye coordinate of the benzoate (25. 0G, 73mmol), 4 - dibenzo the [phyu column step theory it buys (18. 7G, 88mmol), tetrakis (triphenyl phosphine) palladium (1. 7G, 0. 15Mmol), potassium purification (20. 2 G, 146. 7Mmol) and toluene into 125 ml, 125 ml tetrahydrofuran mixable, been painted with 50 ml water. Reactor 10 have been stirring time temperature temperature 80 into the road. The end point of the reaction temperature of ethyl acetate at room temperature reaction period particularly as organic layer was separated. The organic layer after column chromatography separated><intermediates 1 provided a cream (75. 0G, 60. 1%) Are obtained. Synthesis example 1 - (2): synthesis of intermediates 1 a-b A compound according to 2 1 a-b intermediates and copiers: 2><Reactive 1 A-a 1 a-b intermediates><><intermediates 500 Ml reactor 1 provided a><intermediates (17. 0G, 45mmol), sodium hydroxide (2. 14G, 54mmol), 170 ml ethanol and reflux stirring time was placed in the 48. , Thin film chromatography was cooled down to room temperature after confirmation to the completion. 2 - Cooled enemy normal hydrochloric acid solution, 30 minutes stirring was generated acidifying the solids after filtering. Dichloro methane and is recrystallised with normal><intermediates 1 a-b (14. 5G, 88. 6%) Are obtained. Synthesis example 1 - (3): synthesis of intermediates 1 a-c A compound according to intermediates 1 a-c 3 and copiers: 3><Reactive 1 A-b intermediates 1 a-c>><<intermediates 250 Ml reactor><intermediates 1 a-b (14. 5G, 39mmol), methanesulphonic acid 145 ml by stirring time was 3 80 into and out of the elevated road. been cooled to room temperature after confirmation to the completion. After stirring 30 minutes was 150 ml reaction solution comprises a enemy slowly. The resulting solids after the water and methanol good for me. 1 A-c><intermediates (11. 50G, 83. 4%) Are obtained. Synthesis example 1 - (4): synthesis of intermediates 1 a-d A compound according to intermediates 1 a-d 4 and copiers: 4><Reactive 1 A-c 1 a-d><intermediates><intermediates 1L reactor><intermediates 1 a-c (11. 5G, 33mmol>, dichloro methane into 300 ml was stirred at ordinary temperature. Bromine (3. 4 Ml, 66mmol) dichloro methane dilution to the enemy to 50 ml, 8 time was stirring at room temperature. After completion of the reaction the reaction vessel 100 ml acetone with concave-gate. The resulting solids after the acetone wash me. Solid which is recrystallised><intermediates 1 a-d to mono chlorobenzene (11. 0G, 78%) are obtained. Synthesis example 1 - (5): synthesis of intermediates 1 a-e A compound according to intermediates 1 a-e 5 and copiers: 5><Reactive 1 A-d><intermediates 1 a-e><intermediates 250 Ml reactor 2 - bromo biphenyl (8. 4G, 0. 036Mol) was placed in the nitrogen atmosphere minus 78 110 ml tetrahydrofuran mixable and road cooling. Cooled reaction solution roh the butyl lithium which it rolls up (19. 3 Ml, 0. 031Mol) enemy-gate the same temperatures. 2 Reaction solution comprises a stirring time after 1 a-d><intermediates (11. 0G, 0. 026Mol) was stirred at room temperature into a little at a time. The TLC confirmed that the reaction terminated reaction solution changes color. H2O 50 ml ethyl acetate extracted from the reactive ends and placed in the water. After separating organic layer concentrated to 1 a-e>knight reel is recrystallised<degassed acetoacetoxy-functional intermediates (12. 2G, 81. 5%) Are obtained. Synthesis example 1 - (6): synthesis of intermediates 1 a-f A compound according to intermediates 1 a-f 6 and copiers: 6><Reactive 1 A-e 1 a-f><intermediates><intermediates 250 Ml reactor 1 a-e><intermediates (12. 0G, 0. 021Mol) 120 ml with acetic acid, 2 ml sulfate and 5 placed in the reflux time was stirring. Solid once created was cooled down to room temperature after confirmation to the completion. The resulting solids after the H2O, methanol good for a repulsion mono chlorobenzene to by silica gel filtration, after cooling the room temperature concentrated<intermediates>1 a-f (10. 7G, 90%) by Congress. Synthesis example 1 - (7): synthesis of formula 1 A compound according to formula 1 configurated 7: 7><Reactive Formula 1 1 a-f><><intermediates 250 Ml reactor 1 a-f><intermediates (5. 0G, 0. 009Mol), bis (4 - ) amine (6. 0G, 0. 021Mol), palladium (II) acetate (0. 08G, 0. 4Mmol), sodium it shakes off, department [thok side (3. 4G, 0. 035Mol), tree it shakes off, butyl gun spin (0. 07G, 0. 4Mmol), 60 ml toluene reflux stirring 2 frame and time-gate. After completion of reaction was cooled at room temperature. Reaction solution comprises a extracted from the dichloro methane into methane. The organic layer separated was cream after magnesium alkylsulfate to anhydride. After separating column material is positive number is recrystallised<>dichloro methane and formula 1 acetone (3. 1G, 36%) was obtained. MS (MALDI-a TOF): m/z 964. 5 [M+ ] Synthesis example 2: synthesis of formula 33 Synthesis example 2 - (1): synthesis of intermediates 2 a-a A compound according to 8, intermediates 2 a-a and copiers: 8><Reactive 2 A-a><intermediates 2L reactor same compound 4 - bromo (100. 0G, 0. 405Mol), ethynyl tree (47. 7G, 0. 486Mol), dichloro [1, 1' - bis () ferrocene] palladium (9. 92G, 0. 012Mol), copper iodide (2. 31G, 0. 012Mol), triphenyl phosphine (10. 6G, 0. 040Mol), reflux stirring in nitrogen atmosphere triethylamine 700 ml was placed in the 5 time. After completion of reaction was 500 ml heptane and cooling reaction end is placed. This [thu and silica gel pad filtration was minced and seasoned 2000. The pressure-reducing concentrated filtrate><intermediates 2 a-a (130g, 84%) are obtained. Synthesis example 2 - (2): synthesis of intermediates 2 a-b A compound according to 9, 2 a-b intermediates and copiers: 9><Reactive 2 A-b intermediates>><<intermediates 2 a-a 2L reactor 2 provided a><intermediates (130g, 0. 492Mol), potassium carbonate (101. 9G, 0. 738Mol), methanol 650 ml, 650 ml tetrahydrofuran mixable and 2 placed in the stirring time was at room temperature. After completion of the reaction was reacted terminate into 500 ml heptane. Filtering the reaction solution comprises water and ethyl acetate extracted from the filtrate. Separating organic layer was followed by filtration processing anhydride magnesium alkylsulfate to cream. Oil in the form of intermediates 2 a-b<>(82g, 84%) are obtained. Synthesis example 2 - (3): synthesis of intermediates 2 a-c A compound according to 10, intermediates 2 a-c and copiers: 10><Reactive 2 A-b intermediates 2 a-c>><<intermediates 2L reactor 2 - bromo biphenyl (66. 0G, 0. 283Mol),><intermediates 2 a-b (65. 3G, 0. 340Mol), [1, 1' - bis () ferrocene] decrypts with palladium (6. 94G, 0. 008Mol), copper iodide (1. 62G, 0. 008Mol), triphenyl phosphine (7. 4G, 0. 028Mol), reflux stirring in nitrogen atmosphere triethylamine 500 ml was placed in the 5 time. After completion of reaction was placed 400 ml heptane and cooling reaction end. This [thu and silica gel pad filtration was minced and seasoned 2000. To combine the resulting solids contained in the pressure-reducing concentrated<intermediates 2 a-c>(80g, 82%) are obtained. Synthesis example 2 - (4): synthesis of intermediates 2 a-d A compound according to 11, intermediates 2 a-d and copiers: 11><Reactive 2 A-c><intermediates 2 a-d><intermediates 2L reactor><intermediates 2 a-c (80. 0G, 0. 232Mol) 960 ml dichloro methane into the nitrogen atmosphere was reconstituted with a minus 78 road cooling. One ammonium child five [tin cooled solution (278. 4 Ml, 0. 279Mol) enemy-gate 12 and a stirring time at room temperature. Saturated aqueous solution sodium gap five opinion pay [thu after completion of the reaction with concave-gate. Dichloro methane and water separating organic layer extracted was cream. The circle><intermediates 2 a-d determined methanol (67g, 61. 3%) Are obtained. Synthesis example 2 - (5): synthesis of intermediates 2 a-e A compound according to 12, intermediates 2 a-e and copiers: 12><Reactive <Intermediates 2 a-d>><intermediates 2 a-e 500 Ml reactor><intermediates 2 a-d (54. 8G, 0. 117Mol) and tetra 150 ml was placed under nitrogen atmosphere minus 78 road cooling after melting. Cooled solution 1. 6 Mole roh the butyl loom which it rolls up (62. 4 Ml, 0. 1Mol) enemy same temperatures and a stirring time-gate 1. 9 - [Ley rice field flow five (15. 0G, 0. 083Mol) stirring at room temperature for 1 to 3 and 8 to 50 ml tetrahydrofuran mixable enemy time-gate. Ethyl acetate extracted from the water after completion of the reaction. The organic layer separated was followed by filtration processing anhydride magnesium alkylsulfate to cream. Oil in the form of intermediates 2 a-e<>(33. 2G, 76%) are obtained. Synthesis example 2 - (6): synthesis of intermediates 2 a-f A compound according to 13, intermediates 2 a-f and copiers: 13><Reactive 2 A-f 2 a-e><intermediates><intermediates 1L reactor><intermediates 2 a-e (33. 3G, 0. 063Mol) 330 ml with acetic acid, sulfuric acid and reflux stirring time was 3 ml into 3. was cooled down to room temperature after confirmation to the completion. The resulting solids after the H2O, methanol good for's desire. 2 A-f><intermediates (28. 6G, 88%) are obtained. Synthesis example 2 - (7): synthesis of intermediates 2 a-g A compound according to 14, intermediates 2 a-g and copiers: 14><Reactive <Intermediates 2 a-f 2 a-g>><intermediates 1L reactor><intermediates 2 a-f (20. 0G, 0. 039Mol) placed on a 200 ml dichloro methane ofhis anger. During stirring at room temperature bromine (6 ml, 0. 118Mol) 40 ml dichloro methane to the enemy a dilution-gate. It does, 12 100 ml methanol at room temperature stirring time after completion of the reaction the resulting solids into filtered methanol good for me. Material is 1, 2 - dichloro benzene and acetone is recrystallised><intermediates 2 a-g (16g, 60%) are obtained. Synthesis example 2 - (8): synthesis of formula 33 A compound according to 15, and copiers formula 33: 15><Reactive Formula 33>><<intermediates 2 a-g Said synthesis example 1 - (7) 1 a-f 2 a-g instead<intermediates in the range of 0.1 and the number >><intermediates, using the same method<>formula 33 (2. 5G, 31%) was obtained. MS (MALDI-a TOF): m/z 1064. 5 [M+ ] Synthesis example 3: synthesis of formula 89 Synthesis example 3 - (1): synthesis of intermediates 3 a-a A compound according to 16, intermediates 3 a-a and copiers: 16><Reactive ><Intermediates 3 a-a 2L reactor my [phu mask it buys 1 - hydroxy 2 - (50g, 266mmol), 1000 ml methanol, 100 and 100 ml was placed in the sulfuric acid reflux stirring time. TLC was cooling to room temperature after confirmation to the completion. After cream solution is extracted from the dichloro methane into methane. Organic layer pattern to anhydrous magnesium alkylsulfate after filtration, filled to excess heptane after crystallization><intermediates 3 a-a cream (39g, 72. 6%) Are obtained. Synthesis example 3 - (2): synthesis of intermediates 3 a-b A compound according 3 a-b intermediates 17 and copiers: 17><Reactive 3 A-b intermediates>><<intermediates 3 a-a 1L reactor><intermediates 3 a-a (39. 0G, 193mmol), 390 ml acetic acid-gate into stirring at ordinary temperature. 80 Ml acetic acid brominated (11. 8 Ml, 231mmol) dilution was enemy to a reactive solution. Reaction solution comprises 5 at room temperature stirring time-gate. After completion of reaction resulting solids have filtering, heptane slurry after><intermediates 3 a-b (50g, 90%) are obtained. Synthesis example 3 - (3): synthesis of intermediates 3 a-c A compound according to intermediates 3 a-c 18 and copiers: 18><Reactive 3 A-c 3 a-b intermediates>><<intermediates 2L reactor><intermediates 3 a-b (50g, 178mmol) dichloro methane and with concave up. Nitrogen atmosphere pyridine (28. 1G, 356mmol) 20 minutes into the reaction solution was stirred at room temperature. 0 Reaction solution comprises a road after cooling under nitrogen atmosphere triple nick base oro methane opinion gun id anhydro-synchronized (65. 24G, 231mmol) enemy a-gate. 3 TLC after confirming the completion time to stirring, 20 ml 10 minutes stirring into water and-gate. After<intermediates 3 a-c>cream reaction solution comprises a separating column (45g, 61%) are obtained. Synthesis example 3 - (4): synthesis of intermediates 3 a-d A compound according to intermediates 3 a-d 19 and copiers: 19><Reactive <Intermediates 3 a-c 3 a-d>><intermediates 1L reactor><intermediates 3 a-c (45. 0G, 0. 109Mol), 4 - dibenzo (25. 4G, 0. 120Mol), tetrakis (triphenyl phosphine) palladium (2. 5G, 0. 22Mmol), potassium purification (30. 1 G, 0. 218Mol) and placed in 300 ml toluene, 130 ml ethanol, been painted with 90 ml water. Reactor temperature then 5 have been stirring time temperature road 80. The end point of the reaction temperature of ethyl acetate at room temperature reaction period particularly as organic layer was separated. The organic layer after column chromatography separated<intermediates 3 a-d>cream (22. 0G, 46. 1%) Are obtained. Synthesis example 3 - (5): synthesis of intermediates 3 a-e A compound according to intermediates 3 a-e 20 and copiers: 20><Reactive <Intermediates 3 a-d>><intermediates 3 a-e 1L reactor><intermediates 3 a-d (22. 0, 0. 051Mol), sodium hydroxide (2. 65G, 0. 066Mol) frame and reflux stirring time was 48. After the reaction was cooled down to room temperature. 2 - Cooled enemy normal hydrochloric acid solution, 30 minutes stirring was generated acidifying the solids after filtering. Dichloro methane and is recrystallised with normal><intermediates 3 a-e (17. 6G, 82. 7%) Are obtained. Synthesis example 3 - (6): synthesis of intermediates 3 a-f A compound according to intermediates 3 a-f 21 and copiers: 21><Reactive <Intermediates 3 a-e>><intermediates 3 a-f 500 Ml reactor><intermediates 3 a-e (17. 6G, 0. 042Mol), stirring time was 3 to 170 ml methanesulphonic acid 80 into and out of the elevated road. been cooled to room temperature after confirmation to the completion. After stirring 30 minutes was 150 ml reaction solution comprises a enemy slowly. The resulting solids after the water and methanol good for me. Filtering the solids was mono chlorobenzene for 1 to 3 silica gel pad. After heating concentrated acetone filtrate is recrystallised><intermediates 3 a-f (12g, 71%) are obtained. Synthesis example 3 - (7): synthesis of intermediates 3 a-g A compound according to intermediates 3 a-g 22 and copiers: 22><Reactive <Intermediates 3 a-f 3 a-g>><intermediates 1L reactor><intermediates 3 a-f (12. 0G, 0. 030Mol) dichloro methane to 360 ml to the fire. During stirring at room temperature bromine (3. 1 Ml, 0. 06Mol) 40 ml dichloro methane to the enemy a dilution-gate. It does, 12 100 ml methanol at room temperature stirring time after completion of the reaction the resulting solids into filtered methanol good for me. Material is 1, 2 - dichloro benzene and acetone is recrystallised><intermediates 3 a-g (10. 3G, 71. 7%) Are obtained. Synthesis example 3 - (8): synthesis of intermediates 3 a-h A compound according to 23, intermediates 3 a-h and copiers: 23><Reactive 3 A-h><intermediates 1L round bottom [phul [su pen jade hour aniline 2 - reactor (25. 0, 0. 135Mol) and hydrochloric acid in 30 ml, 150 ml water and cool the stirring time was placed in the road 0 1. Sodium age tree [thu same temperatures (11. 2G, 0. 162Mol) enemy 1 75 ml aqueous solution reaction solution after stirring time-gate. Potassium iodide (44. 8G, 0. 270Mol) enemy 75 ml aqueous solution when a temperature of the reaction solution 5 degree not enemy attention beyond the and-gate. 5 Stirring at room temperature it does as a favor, reaction time after completion of water extracted from the ethyl acetate washed the aqueous solution sodium gap five opinion pay [thu. The organic layer after separating the positive number<intermediates 3 a-h>cream separation column (22. 6G, 56. 5%) Are obtained. Synthesis example 3 - (9): synthesis of intermediates 3 a-i A compound according to 24, intermediates 3 a-i and copiers: 24><Reactive 3 A-g><intermediates 3 a-h><intermediates 3 a-i><intermediates Said synthesis example 1 - (5) instead of 2 - bromo 1 a-d><intermediates 3 a-g><intermediates in a number in the range of 0.1 and the ><intermediates 3 a-h instead of biphenyl, using the same method><intermediates 3 a-i (19. 6 G, 70. 4%) By Congress. Synthesis example 3 - (10): synthesis of intermediates 3 a-j A compound according to 25, intermediates 3 a-j and copiers: 25><Reactive <Intermediates 3 a-i>><intermediates 3 a-j Said synthesis example 1 - (6) instead of in the range of 0.1<intermediates 3 a-i>><intermediates 1 a-e and the number, using the same method><intermediates 3 a-j (14. 2 G, 74. 7%) By Congress. Synthesis example 3 - (11): synthesis of formula 89 A compound according to 26, a configurated formula 89: 26><Reactive Formula 89>><<intermediates 3 a-j Said synthesis example 1 - (7) instead of a>><intermediates 3 a-j 1 a-f<intermediates in bis (4 - ) amine instead of 1, 1' - (4 - methylphenyl - 4 - it shakes off, the [le butyl phenyl) amine and a number in the range of 0.1 , using the same method<>formula 89 (2. 4G, 28%) by Congress. MS (MALDI-a TOF): m/z 980. 5 [M+ ] Synthesis example 4: synthesis of formula 97 Synthesis example 4 - (1): synthesis of intermediates 4 a-a A compound according to 27, intermediates 4 a-a and copiers: 27><Reactive ><Intermediates 4 a-a 2L reactor 4 - dibenzo (85. 0G, 0. 401Mol), bismuth (III) nitrate (99. 2G, 0. 200Mol), nitrogen atmosphere into 400 ml toluene 70 road 3 stirring time-gate. After completion of reaction was filtering cooling resulting solids at room temperature. After the toluene wash is carried out 4 provided a><intermediates (61. 5G, 72%) are obtained. Synthesis example 4 - (2): synthesis of 4 a-b intermediates A compound according to intermediates 4 a-b 28 and copiers: 28><Reactive 4 A-b intermediates>><<intermediates 4 a-a 2L reactor ethyl acetate monohydrate (202. 9G, 1. 794Mol) on dimethylformamide amide 500 ml to the fire. Potassium hydroxide (67. 10G, 1. 196Mol), inside anger between potassium (38. 95G, 0. 598Mol) and dimethylformamide was stirred into 200 ml amide into at ordinary temperature. 4 A-a reactive solution><intermediates (127. 5G, 0. 737Mol) 50 whereupon the oxidation film is in the stirring time-gate 72. Reaction after completion of an aqueous sodium hydroxide (25%) and reflux stirring into 200 ml-gate. 3 Have room temperature stirring time after cooling, acetate extracted from the water. Separating the organic layer concentrated to have positive number<intermediates 4 a-b>degassed crow e toe yes defendant separation column (20. 0G, 16%) are obtained. Synthesis example 4 - (3): synthesis of intermediates 4 a-c A compound according to intermediates 4 a-c 29 and copiers: 29><Reactive 4 A-b intermediates 4 a-c>><<intermediates 2L reactor><intermediates 4 a-b (20. 0G, 0. 096Mol), 600 ml ethanol, an aqueous potassium hydroxide (142. 26G, 2. 53Mol) 170 ml into time-gate 12 and reflux stirring. On completion of the reaction was cooled at room temperature. 6 Normal hydrochloric acid reactive solution after 20 minutes stirring into 400 ml and acidifying the resulting solids have been filtered. After washing the solids into ethanol is carried out 4 a-c><intermediates (17. 0G, 88. 5%) Are obtained. Synthesis example 4 - (4): synthesis of intermediates 4 a-d A compound according to intermediates 4 a-d 30 and copiers: 30><Reactive <Intermediates 4 a-c>><intermediates 4 a-d 2L reactor><intermediates 4 a-c (17. 0G, 0. 075Mol), 15 ml sulfate [neh with a reflux stirring time-gate 72. After completion of reaction at room temperature after cooling ethyl acetate extracted from the water. Separating the organic layer with an aqueous solution sodium bicarbonate wash me. The organic layer into excess methanol during cream resulting solids contained in><intermediates 4 a-d (14. 0G, 77. 6%) Are obtained. Synthesis example 4 - (5): synthesis of intermediates 4 a-e A compound according to intermediates 4 a-e 31 and copiers: 31><Reactive <Intermediates 4 a-d>><intermediates 4 a-e Said synthesis example 3 - (8) instead of 2 - 4 a-d in the range of 0.1 and ><pen jade hour aniline intermediates in the number, using the same method><intermediates 4 a-e (9. 1G, 48%) was obtained. Synthesis example 4 - (6): synthesis of intermediates 4 a-f A compound according to 32, intermediates 4 a-f and copiers: 32><Reactive 4 A-f><intermediates Same compound 1 - bromo 500 ml reactor (20. 0G, 0. 081Mmol), bis (blood or cola earth) diboron (26. 7G, 0. 105Mol), [1, 1' - bis () ferrocene] decrypts with palladium (1. 3G, 0. 002Mol), potassium acetate (19. 9G, 0. 202Mol), 1, 4 - dioxane and placed in 200 ml 10 reflux stirring time-gate. After completion of reaction was filtering 2000 light pad. After separating the filtrate with the methane [heyp it burnt is recrystallised<intermediates 4 a-f have pressure-reducing concentrated column dichloro>(17. 0G, 70%) are obtained. Synthesis example 4 - (7): synthesis of intermediates 4 a-g A compound according to intermediates 4 a-g 33 and copiers: 33><Reactive 4 A-e 4 a-f><intermediates><intermediates><intermediates 4 a-g Said synthesis example 1 - (1) - 2 - methyl 5 - bromo 4 - 4 a-e the [phyu column step theory it buys a coordinate of the benzoate instead<intermediates>child instead a number in the range of 0.1 ><intermediates 4 a-f and a dibenzoylmethane, using the same method><intermediates 4 a-g (5. 3 G, 52. 3%) Are obtained. Synthesis example 4 - (8): synthesis of intermediates 4 a-h A compound according to intermediates 4 a-h 34 and copiers: 34><Reactive ><Intermediates 4 a-h><intermediates 4 a-g Said synthesis example 1 - (2) instead of in the range of 0.1><intermediates 1 provided a number and the ><intermediates 4 a-g, using the same method 4 a-h><intermediates (4. 5G, 88. 1%) Are obtained. Synthesis example 4 - (9): synthesis of intermediates 4 a-i A compound according to intermediates 4 a-i 35 and copiers: 35><Reactive 4 A-h><intermediates 4 a-i><intermediates Said synthesis example 1 - (3) instead of 1 a-b intermediates 4 a-h><><intermediates in the range of 0.1 and the number, using the same method<intermediates 4 a-i>(3. 8G, 88. 8%) Are obtained. Synthesis example 4 - (10): synthesis of intermediates 4 a-j A compound according to intermediates 4 a-j 36 and copiers: 36><Reactive <Intermediates 4 a-i>><intermediates 4 a-j Said synthesis example 1 - (4) instead of in the range of 0.1<intermediates 4 a-i>><intermediates 1 a-c and the number, using the same method><intermediates 4 a-j (3g, 55%) are obtained Synthesis example 4 - (11): synthesis of intermediates 4 a-k A compound according to intermediates 4 a-k 37 and copiers: 37><Reactive ><Intermediates 4 a-k><intermediates 4 a-j Said synthesis example 1 - (5) instead of 1 a-d><intermediates in the range of 0.1 and the number ><intermediates 4 a-j, using the same method<intermediates 4 a-k>(2. 5G, 64%) are obtained Synthesis example 4 - (12): synthesis of intermediates 4 a-l A compound according to intermediates 4 a-l 38 and copiers: 38><Reactive 4 A-k><intermediates 4 a-l><intermediates Said synthesis example 1 - (6) instead of in the range of 0.1>><intermediates 4 a-k<intermediates 1 a-e and the number, using the same method<intermediates 4 a-l>(2. 2G, 90. 4%) Are obtained Synthesis example 4 - (13): synthesis of intermediates 4 a-m A compound according to intermediates 4 a-m 39 and copiers: 39><Reactive ><Intermediates 4 a-m 1 - Bromo - 4 - 250 ml reactor (2 - naphthyl) benzene (10. 0G, 0. 035Mol), 4 - it shakes off, butyl aniline (5. 8G, 0. 039Mol), tris (d it cuts qualitative the acetone which is burnt) (0) (0. 65G, 0. 0007Mol), sodium it shakes off, department [thok side (6. 79G, 0. 0706Mol), 2, 2 '- bis () - 1, 1' - bi-naphthalene (0. 44G, 0. 0007Mol) into 100 ml toluene reflux stirring and time-gate 3. After completion of reaction at room temperature cooling weight ethyl acetate extracted from the water. The organic layer separated was cream after magnesium alkylsulfate to anhydride. Separating the positive number><intermediates 4 a-m column (10g, 80%) by Congress. Synthesis example 4 - (14): synthesis of formula 97 A compound according to formula 97 40 configurated: 40><Reactive 4 A-m formula 97><><intermediates 4 a-l><intermediates Said synthesis example 1 - (7) using 1 a-f><intermediates 4 a-l><intermediates in instead of bis (4 - ) amine intermediates 4 a-m a number in the range of 0.1 and ><instead, using the same method<>formula 97 (1. 6G, 38%) was obtained. MS (MALDI-a TOF): m/z 1194. 5 [M+ ] Synthesis example 5: synthesis of formula 105 Synthesis example 5 - (1): synthesis of intermediates 5 a-a A compound according to 41, intermediates 5 a-a and copiers: 41><Reactive 5 A-a><intermediates 2L reactor my [phu mask it buys 1 - hydroxy 2 - (50g, 266mmol), 1000 ml methanol, 100 and 100 ml was placed in the sulfuric acid reflux stirring time. TLC was cooling to room temperature after confirmation to the completion. After cream solution is extracted from the dichloro methane into methane. Organic layer pattern to anhydrous magnesium alkylsulfate after filtration, filled to excess heptane after crystallization><intermediates 5 a-a cream (39g, 72. 6%) Are obtained. Synthesis example 5 - (2): synthesis of 5 a-b intermediates A compound according to 5 a-b intermediates 42 and copiers: 42><Reactive 5 A-a 5 a-b intermediates><><intermediates 1L ><intermediates 5 provided a reactor (39. 0G, 193mmol), 390 ml acetic acid-gate into stirring at ordinary temperature. 80 Ml acetic acid brominated (11. 8 Ml, 231mmol) dilution was enemy to a reactive solution. Reaction solution comprises 5 at room temperature stirring time-gate. After completion of reaction resulting solids have filtering, heptane slurry after><intermediates 5 a-b (50g, 90%) are obtained. Synthesis example 5 - (3): synthesis of intermediates 5 a-c A compound according to intermediates 5 a-c 43 and copiers: 43><Reactive 5 A-b intermediates 5 a-c>><<intermediates 2L<> reactor 5 a-b intermediates (50g, 178mmol) dichloro methane and with concave up. Nitrogen atmosphere pyridine (28. 1G, 356mmol) 20 minutes into the reaction solution was stirred at room temperature. 0 Reaction solution comprises a road after cooling under nitrogen atmosphere triple nick base oro methane opinion gun id anhydro-synchronized (65. 24G, 231mmol) enemy a-gate. 3 TLC after confirming the completion time to stirring, 20 ml 10 minutes stirring into water and-gate. 5 A-c are separated from each other after cream reaction solution comprises a column<intermediates>(45g, 61%) are obtained. Synthesis example 5 - (4): synthesis of intermediates 5 a-d A compound according to intermediates 5 a-d 44 and copiers: 44><Reactive 5 A-c><intermediates 5 a-d><intermediates 1L reactor><intermediates 5 a-c (45. 0G, 0. 109Mol), 4 - dibenzo (25. 4G, 0. 120Mol), tetrakis (triphenyl phosphine) palladium (2. 5G, 0. 22Mmol), potassium purification (30. 1 G, 0. 218Mol) and placed in 300 ml toluene, 130 ml ethanol, been painted with 90 ml water. Reactor temperature then 5 have been stirring time temperature road 80. The end point of the reaction temperature of ethyl acetate at room temperature reaction period particularly as organic layer was separated. The organic layer after separating column 5 a-d as well as intermediates cream are obtained. (22. 0G, 46. 1%) Synthesis example 5 - (5): synthesis of intermediates 5 a-e A compound according to 45, intermediates 5 a-e and copiers: 45><Reactive 5 A-d><intermediates 5 a-e><intermediates 500 Ml reactor bromobenzene (25. 46G, 0. 163Mol) was placed in the nitrogen atmosphere to 170 ml tetrahydrofuran mixable -78 road cooling. Cooled reaction solution roh the butyl lithium which it rolls up (1. 6 Mole) (95. 6 Ml, 0. 153Mol) enemy a-gate. After stirring 1<intermediates 3 a-d>same time temperature (22. 0G, 0. 051Mol) having been added at room temperature stirring time was 3. After 30 minutes stirring into water 50 ml reaction and-gate. Separating the organic layer concentrated ethyl acetate after extraction was degassed water. Material 200 ml concentrated acetic acid, hydrochloric acid 1 ml stirring and temperature-gate 80 placed in the road. After completion of reaction was have cooling filtration resulting solids. After><intermediates 5 a-e is good for a methanol (20. 0G, 73%) are obtained. Synthesis example 5 - (6): synthesis of intermediates 5 a-f A compound according to 46, intermediates 5 a-f and copiers: 46><Reactive 5 A-f 5 a-e><intermediates><intermediates 1L reactor><intermediates 5 a-e (20. 0G, 0. 037Mol) 600 ml chloroform on to the fire. During stirring at room temperature bromine (5. 7 Ml, 0. 112Mol) 40 ml chloroform in the dilution-gate to the enemy. It does, 12 100 ml methanol at room temperature stirring time after completion of the reaction the resulting solids into filtered methanol good for me. Material is 1, 2 - dichloro benzene and acetone is recrystallised><intermediates 5 a-f (14. 0G, 61. 7%) Are obtained. Synthesis example 5 - (7): synthesis of intermediates 5 a-g A compound according to 47, intermediates 5 a-g and copiers: 47><Reactive 5 A-g><intermediates Said synthesis example 4 - (13) in 1 - bromo 4 - (2 - naphthyl) - 4 - (trimethylsilyl) benzene instead of 1 - bromo benzene a number in the range of 0.1 and, using the same method><intermediates 5 a-g (13. 1G, 72. 1%) By Congress. Synthesis example 5 - (8): synthesis of formula 105 A compound according to 48, a configurated formula 105: 48><Reactive 5 A-f 5 a-g><><intermediates><intermediates formula 105 Said synthesis example 1 - (7) 1 a-f 5 a-f><intermediates using><intermediates in instead of bis (4 - ) amine instead a number in the range of 0.1 and 5 a-g><intermediates, using the same method<>formula 105 (3. 0G, 35%) was obtained. MS (MALDI-a TOF): m/z 1048. 5 [M+ ] Synthesis example 6: synthesis of formula 240>< Synthesis example 6 - (1): synthesis of intermediates 6 a-a A compound according to 49, intermediates 6 a-a and copiers: 49><Reactive ><Intermediates 6 a-a Bromo benzene (8. 0 G, 0. 050 Mol), 2, 6 - dimethylaniline (6. 2 G, 0. 050 Mol), palladium acetate (0. 22 G, 1 mmol), 2, 2 '- bis () - 1 - 1' - bi-naphthyl (1. 3 G, 2 mmol), sodium it shakes off, review [thok side (12. 2 G, 0. 120 Mol) with respect to the sugar syrup is toluene 100 ml 12 hours reflux. Column chromatography ethyl acetate is then cooled to room temperature after separating><intermediates 6 a-a (7. 3 G, 73%) was obtained. Synthesis example 6 - (2): synthesis of formula 240 A compound according to 50, a configurated formula 240: 50><Reactive Formula 240>><<intermediates 6 a-a 1, 6 - With d [pu wool pie [leyn (4 g, 0. 011 Mol),><intermediates 6 a-a (5. 0 G, 0. 025 Mol), sodium it shakes off, review [thok side (5. 3 G, 0. 055 Mol), palladium acetate (0. 1 G, 0. 44 Mmol), tree it shakes off, review [thil gun spin (0. 36 G, 1. 7 Mmol) with respect to the sugar syrup is toluene 50 ml 24 hours reflux. Reduce a temperature extraction column chromatography ethyl acetate at ambient temperature after separating><formula 240 (3. 1 G, 48%) was obtained. MS (MALDI-a TOF): m/z 592. 29 [M+ ] Synthesis example 7: synthesis of formula 241<> Synthesis example 7 - (1): synthesis of intermediates 7 a-a A compound according to 51, intermediates 7 a-a and copiers: 51><Reactive 7 Provided a><intermediates Said synthesis example 7 - (1) instead of 2, 6 - 2, 6 - dimethylaniline in d ethyl aniline number using the same method and in the range of 0.1 ><intermediates 7 a-a (8. 7G, 75%) are obtained. Synthesis example 7 - (2): synthesis of formula 241 A compound according to 52, a configurated formula 241: 52><Reactive 7 Provided a formula 241>><<intermediates Said synthesis example 6 - (2) instead of a><><intermediates 6 a-a in the range of 0.1 and intermediates 7 provided a number using the same method <>formula 241 (6. 6G, 63%) by Congress. MS (MALDI-a TOF): m/z 648. 35 [M+ ] Synthesis example 8: synthesis of formula 242>< Synthesis example 8 - (1): synthesis of intermediates 8 a-a A compound according to 53, intermediates 8 a-a and copiers: 53><Reactive 8 A-a><intermediates Said synthesis example 6 - (1) instead of 2, 6 - 2, 6 - dimethylaniline in isopropyl aniline diaryl number using the same method in the range of 0.1 and 8 provided a><intermediates (5. 5G, 75%) are obtained. Synthesis example 8 - (2): synthesis of formula 242 A compound according to 54, a configurated formula 242: 54><Reactive 8 A-a formula 242>><<intermediates Said synthesis example 6 - (2) instead of a><><intermediates 6 a-a in the range of 0.1 and intermediates 8 provided a number using the same method <>formula 242 (4. 7G, 56%) by Congress. MS (MALDI-a TOF): m/z 704. 41 [M+ ] Synthesis example 9: synthesis of formula 245<> Synthesis example 9 - (1): synthesis of intermediates 9 a-a A compound according to 55, intermediates 9 a-a and copiers: 55><Reactive 9 Provided a><intermediates Said synthesis example 6 - (1) instead of 1 - bromo - 4 - bromobenzene in trimethylsilyl benzene using the same method in the range of 0.1 and 9 provided a number ><intermediates (6. 1G, 78%) are obtained. Synthesis example 9 - (2): synthesis of formula 245 A compound according to 56, a configurated formula 245: 56><Reactive 9 Provided a formula 245>><<intermediates Said synthesis example 6 - (2) instead of a<><intermediates 6 a-a in the range of 0.1 and 9 provided a number >intermediates using the same method<>formula 245 (3. 9G, 70%) by Congress. MS (MALDI-a TOF): m/z 736. 37 [M+ ] Synthesis example 10: synthesis of formula 246>< Synthesis example 10 - (1): synthesis of intermediates 10 a-a A compound according to 57, intermediates 10 a-a and copiers. 57><Reactive 10 Provided a><intermediates Said synthesis example 6 - (1) instead of 1 - bromo - 4 - bromobenzene in it shakes off, review [thil the benzene number using the same method in the range of 0.1 and 10 provided a><intermediates (6. 6G, 77%) are obtained. Synthesis example 10 - (2): synthesis of formula 246 A compound according to 58, a configurated formula 246: 58><Reactive 10 Provided a formula 246>><<intermediates Said synthesis example 6 - (2) instead of a<><intermediates 6 a-a in the range of 0.1 and 10 provided a number >intermediates using the same method<>formula 246 (5. 9G, 75%) by Congress. MS (MALDI-a TOF): m/z 704. 41 [M+ ] Synthesis example 11: synthesis of formula 247<> Synthesis example 11 - (1): synthesis of intermediates 11 a-a A compound according to 59, intermediates 11 a-a and copiers: 59><Reactive 11 A-a><intermediates 1 - Butyl - 3, 5 - dimethyl benzene - tertiary (15 g, 0. 246 Mol) stirring is placed 60 ml acetic chains. 40 Ml sulfuric acid and 20 minutes-gate 1:1 mixture of an enemy. After cooling to room temperature slowly with respect to the temperature to 45 °C. A size slightly larger than ethyl acetate water extracted from the reactants. Organic layer 1. 0 M potassium hydroxide aqueous solution was wash 3 times. Organic layer generates a condensed hexane determining<intermediates 11 provided a>(27g, 53%) by Congress. Synthesis example 11 - (2): synthesis of 11 a-b intermediates A compound according to 60, 11 a-b intermediates and copiers: 60><Reactive 11 A-b intermediates><><intermediates 11 a-a 11 A-a><intermediates (15 g, 0. 072 Mol), cystine chloride (41 g, 0. 216 Mol) with respect to the 24 hours reflux is placed 300 ml ethanol. Potassium hydroxide aqueous solution after cooling with concave chains. After column chromatography ethyl acetate extraction><intermediates 11 a-b are separated from each other (7g, 55%) was obtained. Synthesis example 11 - (3): synthesis of intermediates 11 a-c A compound according to 61, intermediates 11 a-c and copiers: 61><Reactive 11 A-c><intermediates 1, 3 - Dibromo - 5 - fluorobenzene (10 g, 0. 039 Mol), 1 - me [phu step theory it buys (6. 7 G, 0. 039 Mol), tetrakis (triphenyl phosphine) palladium (0. 9 G, 0. 78 Mmol), potassium carbonate (16. 2 G, 0. 117 Mol) is toluene 150 ml, 50 ml distilled water with respect to the sugar syrup 12 hours reflux. Ethyl acetate extraction and cooling after column chromatography separated><intermediates 11 a-c (8. 5 G, 72%) by Congress. Synthesis example 11 - (4): synthesis of intermediates 11 a-d A compound according to 62, intermediates 11 a-d and copiers: 62><Reactive 11 A-b 11 a-c 11 a-d<intermediates><intermediates>><intermediates Said synthesis example 6 - (1) instead of 2, 6 - dimethylaniline in><intermediates 11 a-b using, instead of a number in the range of 0.1 >bromobenzene<intermediates 11 a-c using the same method and><intermediates 11 a-d (8. 3G, 74%) are obtained. Synthesis example 11 - (5): synthesis of formula 247 A compound according to 63, a configurated formula 247: 63><Reactive 11 A-d formula 247><><intermediates Said synthesis example 6 - (2) in a>><intermediates 6 provided a number in the range of 0.1 and instead<intermediates 11 a-d using the same method <>formula 247 (11. 5G, 56%) are obtained. MS (MALDI-a TOF): m/z 992. 49 [M+ ] Synthesis example 12: synthesis of formula 249>< Synthesis example 12 - (1): synthesis of intermediates 12 a-a A compound according to 64, intermediates 12 a-a and copiers: 64><Reactive 12 Provided a><intermediates Said synthesis example 6 - (1) - 2, 6 - dimethyl aniline instead of 2, 6 - dimethylaniline in number the same method and trimethylsilyl 4 - in the range of 0.1 to 12 provided a><intermediates (7. 4G, 66%) are obtained. Synthesis example 12 - (2): synthesis of formula 249 A compound according to 65, and copiers formula 249: 65><Reactive 12 Provided a formula 249>><<intermediates Said synthesis example 6 - (2) instead of 12 a-a><><intermediates 6 a-a in a number in the range of 0.1 intermediates using the same method and formula 249<>(10. 6G, 58%) are obtained. MS (MALDI-a TOF): m/z 820. 46 [M+ ] Synthesis example 13: synthesis of formula 250<> Synthesis example 13 - (1): synthesis of intermediates 13 a-a A compound according to 66, intermediates 13 a-a and copiers: 66><Reactive 13 Provided a><intermediates Said synthesis example 6 - (1) 2, 6 - dimethyl - 2, 6 - dimethyl aniline instead of 4 - dimethylaniline in this cow pro it will bloom and it will be recorded in the range of 0.1 number using the same method and 13 provided a><intermediates (15. 3G, 81%) are obtained. Synthesis example 13 - (2): synthesis of formula 250 A compound according to 67, a configurated formula 250: 67><Reactive 13 Provided a formula 250>><<intermediates Said synthesis example 6 - (2) instead of a<><intermediates 6 a-a in the range of 0.1 and intermediates 13 provided a number using the same method><>formula 250 (9. 3G, 51%) are obtained. MS (MALDI-a TOF): m/z 792. 43 [M+ ] Synthesis example 14: synthesis of formula 251>< Synthesis example 14 - (1): synthesis of intermediates 14 a-a A compound according to 68, intermediates 14 a-a and copiers: 68><Reactive 11 A-b intermediates 14 provided a>><<intermediates Said synthesis example 6 - (1) instead of 2, 6 - dimethylaniline<intermediates 11 a-b in a number using the same method and in the range of 0.1><intermediates 14 provided a>(11. 1G, 79%) are obtained. Synthesis example 14 - (2): synthesis of intermediates 14 a-b A compound according to 69, 14 a-b intermediates and copiers: 69><Reactive 14 Provided a 14 a-b intermediates>><<intermediates Said synthesis example 6 - (2) instead of a<><intermediates 6 a-a in the range of 0.1 and 14 provided a number the same method >intermediates using><intermediates 14 a-b (6. 8G, 62%) are obtained. Synthesis example 14 - (3): synthesis of intermediates 14 a-c A compound according to the 70, intermediates 14 a-c and copiers: 70><Reactive 14 A-b intermediates 12 provided a formula 251><>><<intermediates Said synthesis example 6 - (2) instead of using<><intermediates 6 a-a in intermediates 12 provided a>with d [pu wool pie [leyn a number in the range of 0.1 and 1, 6 - 14 a-b intermediates instead<><>formula 251 using the same method (6. 6G, 47%) was obtained. MS (MALDI-a TOF): m/z 762. 44 [M+ ] II. Host compound number attainments Synthesis example 15: synthesis of compound 1 Synthesis example 15 - (1): synthesis of intermediates 15 a-a A compound according to 71, 15 provided a intermediates and copiers: 71><Reactive 15 Provided a><intermediates 1L 1 - bromo -2 reactor under nitrogen atmosphere. 6 - (50g, 230mmol), 400 ml tetrahydrofuran mixable melting into and out of the other. Also lowers the temperature to minus 78, roh the butyl lithium which it rolls up (167 ml, 280mmol) decodes the enemy. After stirring at a temperature the same time 2 methyl step [ley [thu tree (36 ml, 320mmol) into and out of the-gate night stirring at room temperature. After completion of reaction 2 stored in the normal hydrochloric acid acidic by enemy slowly. Ethyl acetate extraction of water and organic layer after separation magnesium alkylsulfate moisture number been stand-alone. After the pressure-reducing material [heyp it burnt with toluene to concentrate is recrystallised<intermediates 15 provided a>(20. 8G, 50%) are obtained. Synthesis example 15 - (2): synthesis of intermediates 15 a-b A compound according to 72, 15 a-b intermediates and copiers: 72><Reactive 15 Provided a 15 a-b intermediates><><intermediates ><intermediates 15 provided a 500 ml reactor (20. 8G, 110mmol), 1 - 2 - 3 - bromo benzene relative coordinate of the child fluorine (28. 7G, 95mmol), tetrakis (triphenyl phosphine) palladium (33g, 29mmol), sodium carbonate (30. 3G, 290mmol) and placed in the 200 ml toluene, ethanol 60 ml, 60 ml water was held. 12 Hours after the end point of the reaction temperature of ethyl acetate at room temperature stirring reaction period particularly as organic layer are isolated each other. The organic layer are separated from each other after column chromatography 15 a-b intermediates><cream (22. 3G, 63%) are obtained. Synthesis example 15 - (3): synthesis of intermediates 15 a-c A compound according to 73, intermediates 15 a-c and copiers: 73><Reactive 15 A-b intermediates 15 a-c>><<intermediates 500 Ml reactor><intermediates 15 a-b (22. 3G, 72mmol), phenyl (10. 5G, 86mmol), tetrakis (triphenyl phosphine) palladium (2. 5G, 2. 2Mmol), purification of potassium (29. 7G, 22mmol), 160 ml toluene, ethanol 70 ml, 70 ml water stirring night through the chains. The reaction temperature of room temperature water and ethyl acetate reaction end period particularly as organic layer was separated. The organic layer is recrystallised><intermediates 15 a-c after heptane to cream (16. 3G, 74%) are obtained. Synthesis example 15 - (4): synthesis of intermediates 15 a-d A compound according to 74, intermediates 15 a-d and copiers: 74><Reactive 15 A-d 15 a-c><intermediates><intermediates 500 Ml reactor><intermediates 15 a-c (16. 3G, 53mmol), hydrobromic acid (48 ml, 260mmol), stirring time-gate 12 into and out of the 100 ml acetic acid. After completion of the reaction with water then heated with stirring at ambient temperature for 25. Ethyl acetate was removed water organic extraction of reactants. The organic layer after filtration and dried to cream or heptane to 15 a-d><reprioritized intermediates (14g, 95%) are obtained. Synthesis example 15 - (5): synthesis of intermediates 15 a-e A compound according to 75, intermediates 15 a-e and copiers: 75><Reactive <Intermediates 15 a-d 15 a-e>><intermediates 500 Ml reactor><intermediates 15 a-d (14g, 50mmol), potassium purification (20. 7G, 150mmol), N - methyl - 2 - pyrrolidone 112 ml 12 into and out of the stirring time-gate. Ethyl acetate at room temperature after cooling water is removed after completion of the reaction was organic extraction. The pressure-reducing material is recrystallised><intermediates 15 a-e to heptane concentrated (10. 5G, 81%) are obtained. Synthesis example 15 - (6): synthesis of intermediates 15 a-f A compound according to 76, intermediates 15 a-f and copiers: 76><Reactive 15 A-e 15 a-f><intermediates><intermediates 500 Ml reactor under nitrogen atmosphere ><intermediates 15 a-e (10. 5G, 40mmol) into and out of the dichloro methane 136 ml through the melting chamber. A reaction solution 0 road after cooling pyridine (10 ml, 110mmol) whereupon a triple neel base five [lu methane opinion guns high dry [tu it freezes (12. 7G, 68mmol) maintain the same temperature-gate enemy. After stirring at room temperature stirring into and out of the water 20 ml reaction solution 12 time etched. After the separation of the organic layer is concentrated to heptane dichloro methane extraction water pressure is recrystallised><intermediates 15 a-f (7. 5G, 47%) are obtained. Synthesis example 15 - (7): synthesis of compound 1 A compound according to 77, compound 1 and copiers: 77><Reactive 1><><Intermediates compounds 15 a-f 250 Ml reactor><intermediates 15 a-f (7. 5G, 19mmol), anthracene - 9 - phenyl - 10 - (d5) boronic acid (7g, 23mmol), tetrakis (triphenyl phosphine) palladium (0. 66G, 0. 6Mmol), purification of potassium (7. 9G, 57mmol) frame and 53 ml toluene, 23 ml ethanol, 23 ml water 12 through the entire stirring time. After separating organic layer was poured into the reaction reactants been rapidly lowers the methanol at ambient temperature. The organic layer after toluene and acetone<>cream is recrystallised compound 1 (6g, 63%) by Congress. MS (MALDI-a TOF): m/z 501. 21 [M +] Synthesis example 16: synthesis of compound 4 Synthesis example 16 - (1): synthesis of compound 4 A compound according to 78, compound 4 and copiers: 78><Reactive 4><Compounds Synthesis example 15 - said (3) instead of naphthalene - 2 - boronic acid a number in the range of 0.1 and use in phenyl ><compound 4 according to the same method (23g, 57%) are obtained. MS (MALDI-a TOF): m/z 551. 23 [M +] Synthesis example 17: synthesis of compound 5 Synthesis example 17 - (1): synthesis of compound 5 A compound according to 79, compound 5 and copiers: 79><Reactive 5><Compounds Synthesis example 15 - said (3) instead of in the range of 0.1 and 1 - me [phu step theory it buys phenyl use in number according to the same method ><compound 5 (18g, 41%) are obtained. MS (MALDI-a TOF): m/z 551. 23 [M +] Synthesis example 18: synthesis of compound 10 Synthesis example 18 - (1): synthesis of intermediates 18 a-a A compound according to 80, intermediates 18 a-a and copiers: 80><Reactive 15 Provided a><intermediates 18 provided a><intermediates Said synthesis example 15 - (2) 1 - 2 - 3 - 2 - 1 - bromo - 3 - methyl benzene instead of fluorine fluorine in the relative coordinate of the child in the range of 0.1 and number benzene relative coordinate of the child using the same method><intermediates 18 a-a (22. 3G, 63%) are obtained. Synthesis example 18 - (2): synthesis of intermediates 18 a-b A compound according to 81, 4 a-b intermediates and copiers: 81><Reactive 18 Provided a 18 a-b intermediates>><<intermediates Said synthesis example 15 - (4) instead of 15 a-c><intermediates in a number in the range of 0.1 ><intermediates 18 a-a using the same method and><intermediates 18 a-b (16g, 59%) are obtained. Synthesis example 18 - (3): synthesis of intermediates 18 a-c A compound according to 82, 18 a-c intermediates and copiers: 82><Reactive 18 A-b intermediates 18 a-c><><intermediates Said synthesis example 15 - (5) 15 a-d><intermediates in a number in the range of 0.1 and instead<intermediates 18 a-b using the same method>><intermediates 18 a-c (19. 9G, 71%) are obtained. Synthesis example 18 - (4): synthesis of intermediates 18 a-d A compound according to 83, intermediates 18 a-d and copiers: 83><Reactive 18 A-d 18 a-c><intermediates><intermediates Said synthesis example 15 - (6) instead of 15 a-e><intermediates in a number in the range of 0.1 ><intermediates 18 a-c using the same method and 18 a-d><intermediates (17. 7G, 74%) are obtained. Synthesis example 18 - (5): synthesis of compound 10 A compound according to 84, a configurated compound 10: 84><Reactive 18 A-d 10>><<intermediates compounds Said synthesis example 15 - (7)<intermediates in a number in the range of 0.1 >><intermediates 18 a-d 15 a-f instead and><compound 10 using the same method (11. 7G, 49%) was obtained. MS (MALDI-a TOF): m/z 439. 20 [M +] Synthesis example 19: synthesis of compound 22 Synthesis example 19 - (1): synthesis of compound 22 A compound according to 85, compound 22 and copiers: 85><Reactive ><Compound 22 Said synthesis example 15 - (1) instead of 2 - bromo - 1, 3 - bromo - 1, 4 - in the range of 0.1 and 2 - d maul [thok hour benzene number using the same method according to><compound 22 (20. 6G, 51%) are obtained. MS (MALDI-a TOF): m/z 501. 21 [M +] In the embodiment 1 to 15: number of organic light-emitting bath 2 Mm × mm ITO glass sized to cathode-gate after cleaning. Said ITO glass is mounted on the vacuum chamber base pressure 1 × 10-7 On torr is to expose said ITO HAT provided CN (50 Å), α-a NPD (600 Å) order-gate film. The light emitting layer dopant to a host table 1 (5 wt %) forming film mixing (200 Å) and then, after electron transport layer [formula E-a 1] and [formula E-a 2] 300 Å a 1:1 ratio, to a 10 Å with an [formula E-a 1], Al (1000 Å) order number was high pressure liquid coolant is organic light emitting film. The Eu 0 said organic light-emitting device. 4 MA in a long time. [HAT provided CN] [α-a NPD] [Formula E-a 1] [formula E-a 2] Comparison example 1 - 8 As a substrate for table 1, in the embodiment to instead of using one of a host compound used in which, in addition to compounds described in table 1 for helical twisting power using the same heating agent it does, small number, said structure of to as follows. [BH 1] [BH 2] [BH 3] [BH 4] Comparison example 9 - 12 As a substrate for table 1, in the embodiment instead of the dopant compound used in [BD 1] or [BD 2] wherein, in addition to table 1 compounds described as host agent using the same heating it does, small number, said structure of [BD 1] and [BD 2] as follows. [BD 1]: [BD 2]: 4, 4' bis [2 - (4 a-N, N - d phenyl amino phenyl) vinyl] biphenyl On said in the embodiment 1 to 15, 1 to 12 organic light emitting device prepared by the number according to comparison example, measured transmissibility and efficiency [table 1] means to have shown. In the present invention said table 1 as compared to example 12 comparison example 1 using the compound of the organic light emitting device by an organic light emitting device is an organic light emitting element applied apart show an excellent effect can be highly applicable knew. Disclosed is an organic light-emitting diode, comprising: a first electrode; a second electrode facing the first electrode; and a light-emitting layer interposed therebetween, wherein the light-emitting layer contains at least one selected from among the amine compounds represented by the following Chemical Formula A or Chemical Formula B and the pyrene compound represented by the following Chemical Formula C, plus the anthracene compound represented by the following Chemical Formula D. The structures of Chemical Formulas A to D are as defined in the specification. Number 1 electrode; said number 1 number 2 electrode opposed to the electrode; and a light emitting layer electrode for said number 1 said number 2; including the organic light emitting device, said light emitting layer is represented by [formula B] to [formula A] or amine compound; and [formula C] has a pyrene compound; at least one of which, in addition to compounds represented by [formula D]; organic light emitting device including a [formula A] [Formula B] In said [formula A] and [formula B], A1, A2, and mutually the same or different from each E and F hereinafter, a substituted or unsubstituted aromatic hydrocarbon of 6 to 50 carbon atoms independently of each other a ring, or a substituted or unsubstituted aromatic heterocyclic and C12 2 to 40; and two adjacent carbon atoms in an aromatic ring in said A1, said A2 adjacent carbon atoms in an aromatic ring with an annular 5 by forming two said W each fused ring wherein; said connector L1 To L12 To the insulating layer and each hereinafter, are each independently a single bond, a substituted or unsubstituted 6 to 60 it will be biting, [leyn 2 to 60 carbon atoms or a substituted or non-substituted C12 of selected among a variety of it will be biting, [leyn; said W is CR1 R2 , SiR1 R2 , GeR1 R2 , O, S, NR1 In selected, the M N a-R3 , CR4 R5 , SiR6 R7 , GeR8 R9 , O, S, Se selected among resistant; said substituent R1 To R9 , To the first partition and the same or different from Ar1 Ar8 hereinafter, are each independently a hydrogen, deuterium, a substituted or unsubstituted alkyl 1 to 30 C12, C12 50 6 to a substituted or unsubstituted aryl, a substituted or unsubstituted cycloalkyl group of 3 to 30 C12, 2 to 50 of C12 substituted or unsubstituted heteroaryl group, a substituted or unsubstituted heterocyclic inhibitors of 2 to 30 C12 cycloalkyl, 1 to 30 C12 alkyl substituted or unsubstituted silyl group, a substituted or unsubstituted C12 of 6 to 30, cyano group, halogen is but for at least one selected from the which it should, said R1 And R2 Are each connected alicyclic, aromatic polycyclic forms a ring can be a single ring aromatic compound, formed said alicyclic, aromatic single ring aromatic polycyclic ring carbon atoms N, O, Si, S selected from among one or more heteroatoms can be substitutionally replaced; said p1 r4, s1 to 1 to 3 to each integer is to p4, r1 s4, these each 2 L or more each connector1 To L12 Hereinafter and the same or different from each other, and said x is 1, and the same or different from each y and z hereinafter, positive numbers of 1 to 0 independently of each other, and said Ar1 Ar2, Ar4 Ar3 and, on Ar6 Ar5, and Ar7 Ar8 and can be connected to the first partition forms a ring; in adjacent two of said carbon atoms in said formula A formula Q1 * A2 ring by being coupled fused ring is formed, said formula B in adjacent two carbon atoms of said ring in said A1 * formula Q2 form a condensed ring by being coupled, said A2 in adjacent two carbon atoms of said ring structure Q1 * form fused ring by being coupled pivotably. [Formula C] In said [formula C], R11 to R16 and the same or different from the first partition hereinafter, are each independently a hydrogen, deuterium, a substituted or unsubstituted alkyl 1 to 30 C12, C12 50 6 to a substituted or unsubstituted aryl, a substituted or unsubstituted cycloalkyl group of 3 to 30 C12, C12 1 to 30 wherein a substituted or unsubstituted alkyl, a substituted or unsubstituted C12 of 6 to 30, 1 to 30 germanium C12 substituted or unsubstituted alkyl, a substituted or unsubstituted C12 germanium it will be biting of 6 to 30, cyano group, halogen is selected from low molecular weight catalyst in, said R11 to R16 substituent of hydrogen and deuterium are not aromatic ring carbon is coupled, said h, i, j, k each integer is 0 to 3, R11 to R14 are each the same or different from each they 2 or more each and hereinafter, each said l and m is an integer 0 to 4, or more each R15 and R16 each 2 they are equal to each other or different from and hereinafter, said R11 to R14 are each adjacent X1 to X8 on or connected to each other, or R11 to R14 each R11 to R14 on or more 2 respectively connected to each other alicyclic, aromatic polycyclic forms a ring can be a single ring aromatic compound, formed said alicyclic, aromatic single ring aromatic polycyclic ring carbon atoms N, O, Si, S selected from among one or more heteroatoms can be substitutionally replaced; said X1 to X8 and hereinafter the same or different from the first partition, be independently of each other hydrogen, deuterium, alkyl of 1 to 20 carbon atoms selected from a substituted or unsubstituted substituent is but, at least said X1 to X8 X1, X2, X5 and X6 is a substituted or unsubstituted alkyl C12 1 to 20 are disclosed. [Formula D] In said [formula D], substituted or unsubstituted substituted Ar9 is 6 to 50 C12 aryl, or a substituted or unsubstituted heterocyclic inhibitors of C12 R and 2 to 50, and said R21 to R28 or different socket are hereinafter, are each independently a hydrogen, deuterium, 1 to 30 C12 substituted or unsubstituted alkyl, substituted or unsubstituted cycloalkyl group of 3 to 30 C12, 6 to 50 C12 substituted or unsubstituted aryl, a substituted or unsubstituted heterogeneous nuclear reactor and O, or a heteroaryl group having 2 to 50 carbon atoms of N S, 1 to 30 of C12 substituted or unsubstituted silyl group, cyano group, halogen catalyst in a selected, said R29 C12 1 to 30 is a substituted or unsubstituted alkyl, a substituted or unsubstituted 6 with allyl of C12 to 50 is selected from, said linking group L is single bond, a substituted or unsubstituted 6 to 60 it will be biting, [leyn of C12 in selected, X of '***' is binding with site and said connector L, said [formula A], [formula B], [formula C] and [formula D] displayed in that 'a' in 'substituted or unsubstituted substituted' is deuterium, cyano group, a halogen, alkyl of 1 to 24 carbon atoms, 1 to 24 carbon atoms halogenated alkyl, a variety of 1 to 24 carbon atoms alkyl, 6 to 24 carbon atoms aryl, aryl-alkyl of 7 to 24 carbon atoms, aryl group or heterocyclic inhibitors of 2 to 24 carbon atoms 2 to 24 carbon atoms a variety of aryl-alkyl, alkyl silyl group 1 to 24 carbon atoms, 6 to 24 carbon atoms of , with biting jade time of 6 to 24 carbon atoms selected from the group consisting of at least one substituted 1 which means that the other. According to Claim 1, said organic light emitting device with the light emitting layer includes a dopant and by host, said amine compound represented by [formula A] or [formula B]; and [formula C] pyrene compound represented; and each used as dopant, characterized in that said host compound represented by [formula D] used as organic light emitting devices According to Claim 1, in said formula A or formula B A1 , A2 , And the same or different from each E and F hereinafter, independently of each other a substituted or unsubstituted aromatic hydrocarbon ring 6 to 50 C12 characterized in organic light emitting devices. According to Claim 3, substituted or unsubstituted aromatic hydrocarbon ring of 6 to 50 said C12 and the same or different from the hereinafter, independently of each other selected from [formula 10] to [formula 21] characterized one of organic light emitting devices. [Formula 10] [formula 11] [formula 12] [Formula 13] [formula 14] [formula 15] [Formula 16] [formula 17] [formula 18] [Formula 20] [formula 21] [formula 19] [Formula 10] to [formula 21] "- *" is in said W said annular forming or including 5 a, or said Q formula1 And Q2 A means for forming an annular binding site M including 5 in which, said [formula 10] to [formula 21] aromatic hydrocarbon ring A1 A ring or2 While ring corresponding to formula Q1 Or formula Q2 If among these adjacent two carbon atoms bind to said Q formula1 Of formula Q * or engage with an2 * Of fused ring by being coupled form; said R in R is defined according to Claim 1 [formula 10] to [formula 21] said1 And R2 Is equal to, and m is an integer 1 to 8, m is 2 or more R or R is 2 or more each be the same or different each other. According to Claim 1, linking group L in said formula A and formula B1 To L12, In formula D and L and socket are attached to or different from the hereinafter, single bond or, below [formula 22] to [formula 30] characterized in any one selected from organic light emitting devices. [Formula 22] [formula 23] [formula 24] [formula 25] [Formula 26] [formula 27] [formula 29] [formula 28] [Formula 30] Said linking group can be an aromatic ring carbon seats is coupled in hydrogen or deuterium. According to Claim 1, in said formula C said h, i, j, k each integer number of 0 to 2, each R11 to R14 are each the same or different when they each 2 characterized in organic light emitting devices. According to Claim 1, characterized in that said R15 and R16 each hydrogen or deuterium is in said formula C organic light emitting devices. According to Claim 1, represented by said formula D Ar9 is substituted for [formula 31] characterized in organic light emitting devices. [Formula 31] [Formula 31] "- ****" is represented in said coupling site and to of said formula D, said substituents R31 to R35 and hereinafter is used in the same or different, are each independently a hydrogen, deuterium, a substituted or unsubstituted alkyl 1 to 30 C12, C12 50 6 to a substituted or unsubstituted aryl, a substituted or unsubstituted cycloalkyl group of 3 to 30 C12, 2 to 50 of C12 substituted or unsubstituted heteroaryl group, a substituted or unsubstituted alkoxy group C12 1 to 30 selected from substituted residue. According to Claim 1, characterized in that said formula C two amine groups in pyrene compound is identical to one another organic light emitting devices. According to Claim 1, in pyrene compound of said formula C two amine groups on each other asymmetric hereinafter characterized in organic light emitting devices. Back number According to Claim 1, said amine compound that is represented by [formula A] or [formula B] [formula 1] to [formula 239] characterized in any one selected from organic light emitting devices. Formula 1 formula 2<><><>formula 3 Formula 5 formula 4<><><>formula 6 Formula 7<>< > <>formula 8 formula 9 Formula 10><<><>formula 12 formula 11 Formula 13 > <><formula 15><formula 14 Formula 16><><><formula 17 formula 18 Formula 19 > <><formula 21><formula 20 Formula 22><><formula 24><formula 23 Formula 25<><formula 26 > <>formula 27 Formula 28>><formula 30><<formula 29 Formula 31<><formula 32><>formula 33 Formula 35><><><formula 34 formula 36 Formula 37<><formula 38><>formula 39 Formula 41 > <> > <<formula 40 formula 42 Formula 43<>< > <>formula 45 formula 44 Formula 47<><>formula 48><formula 46 Formula 49< > <><formula 51>formula 50 Formula 54>><><<formula 52 formula 53 Formula 55<><><>formula 57 formula 56 Formula 58<><formula 59><>formula 60 Formula 61<><><formula 63>formula 62 Formula 64<><formula 65><>formula 66 Formula 67<><formula 68><>formula 69 Formula 70<><><formula 72>formula 71 Formula 73<><formula 74><>formula 75 Formula 76<><><formula 78>formula 77 Formula 79< > <><formula 81>formula 80 Formula 82<><formula 83><>formula 84 Formula 85<><formula 86><>formula 87 Formula 88<><formula 89 > <>formula 90 Formula 91<><formula 92 > <>formula 93 Formula 94<><><>formula 96 formula 95 Formula 97<><formula 98><>formula 99 Formula 100 > < > <formula 101<>formula 102 Formula 104 > < > <formula 105><formula 103 Formula 106< > <formula 107 > <>formula 108 Formula 110 formula 109< > < > <>formula 111 Formula 112< > < > <formula 114>formula 113 Formula 115< > <formula 116 > <>formula 117 Formula 118< > < > <>formula 120 formula 119 Formula 121< > <formula 122 > <>formula 123 Formula 124 > << > <>formula 125 formula 126 Formula 127< > <formula 128 > <>formula 129 Formula 130< > <formula 131 > <>formula 132 Formula 133< > < > <formula 135>formula 134 Formula 136< > <formula 137 > <>formula 138 Formula 139< > <formula 140 > <>formula 141 Formula 142< > < > <formula 144>formula 143 Formula 145< > <formula 146 > <>formula 147 Formula 148< > <formula 149 > <>formula 150 Formula 151< > <formula 152 > <>formula 153 Formula 155< > <formula 156> > <formula 154 Formula 157< > <formula 158 > <>formula 159 Formula 160< > <formula 161 > <>formula 162 Formula 163< > <formula 164 > <>formula 165 Formula 166< > <formula 167 > <>formula 168 Formula 169< > <formula 170 > <>formula 171 Formula 172< > <formula 173 > <>formula 174 Formula 175< > <formula 176><>formula 177 Formula 178< > <formula 179 > <>formula 180 Formula 181< > <formula 182 > <>formula 183 Formula 184< > < > <formula 186>formula 185 Formula 187< > <formula 188 > <>formula 189 Formula 190< > <formula 191 > <>formula 192 Formula 193< > <formula 194 > <>formula 195 Formula 196< > < > <formula 198>formula 197 Formula 199< > <formula 200 > <>formula 201 Formula 202< > < > <formula 204>formula 203 Formula 205< > <formula 206 > <>formula 207 Formula 208< > < > <>formula 210 formula 209 Formula 211< > <formula 212 > <>formula 213 Formula 214< > <formula 215 > <>formula 216 Formula 217< > <formula 218 > <>formula 219 Formula 220< > <formula 221 > <>formula 222 Formula 223< > <formula 224 > <>formula 225 Formula 226< > <formula 227 > <>formula 228 Formula 229< > <formula 230 > <>formula 231 Formula 232< > <formula 233 > <>formula 234 Formula 235< > <formula 236 > <>formula 237 Formula 238< > <>formula 239 According to Claim 1, represented by said [formula C] [formula 240] to [formula 284] pyrene compound that is characterized in that at least one selected from any one organic light emitting devices. Formula 240<><formula 241><>formula 242 Formula 243<><formula 244><>formula 245 Formula 246<><><formula 248>formula 247 Formula 249<><formula 250><>formula 251 Formula 252<><formula 253><>formula 254 Formula 255<><formula 256><>formula 257 Formula 258<><formula 259><>formula 260 Formula 261<><formula 262><>formula 263 Formula 264<><formula 265><>formula 266 Formula 267<><formula 268><>formula 269 Formula 270<><formula 271><>formula 272 Formula 273<><formula 274><>formula 275 Formula 276<><><formula 278>formula 277 Formula 279<><formula 280><>formula 281 Formula 282<><><formula 284>formula 283 According to Claim 1, said [formula D] [compound 1] to [compound 30] represented by compound that is selected from any one characterized in that the organic light emitting devices. 1 Compound 2 compound 3><><><compounds 4><><Compound 6><compound 5 compounds 7><><Compound 9><compound 8 compounds 10><><Compound 12><compound 11 compounds 13 14 15>>><Compound<compound<compounds 16 17 18>>><Compound<compound<compounds 19 20 21>>><Compound<compound<compounds Compound 22 23 24>>><compound<<compounds 25 26 27>>><Compound<compound<compounds Compound 28 29 30>>><compound<<compounds According to Claim 1, said other than layer acts as an electron hole injection layer, hole transporting layer, a hole injection function and hole transport used as functional layer, an electron transport layer, the metal layer of at least one of selected and characterized further including organic light emitting devices. According to Claim 15, said at least one layer selected from each layer formed by deposition process or solution characterized in organic light emitting devices. According to Claim 1, said first and second flat panel display device; flexible display device; monochrome or white for plane light source device; and, monochrome or white flexible for illumination device; characterized in either selected from organic light emitting devices. Host Dopant Cd/A CIEx CIEy Comparison example 1 BH 1 Formula 1 7. 4 0. 136 0. 112 Comparison example 2 BH 2 Formula 33 7. 9 0. 138 0. 115 Comparison example 3 BH 3 Formula 89 8. 1 0. 136 0. 117 Comparison example 4 BH 4 Formula 97 7. 7 0. 137 0. 114 Comparison example 5 BH 1 Formula 240 7. 5 0. 133 0. 121 Comparison example 6 BH 2 Formula 241 8. 1 0. 138 0. 128 Comparison example 7 BH 3 Formula 247 7. 6 0. 136 0. 124 Comparison example 8 BH 4 Formula 250 7. 3 0. 134 0. 131 Comparison example 9 Compound 1 BD 1 7. 8 0. 141 0. 150 Example 10 comparison Compound 4 BD 2 6. 4 0. 150 0. 182 Comparison example 11 Compound 10 BD 1 7. 6 0. 140 0. 151 Comparison example 12 Compound 22 BD 2 6. 6 0. 148 0. 178 In the embodiment 1 Compound 1 Formula 1 9. 7 0. 132 0. 109 In the embodiment 2 Compound 1 Formula 33 9. 4 0. 138 0. 111 In the embodiment 3 Compound 1 Formula 240 8. 9 0. 137 0. 120 In the embodiment 4 Compound 4 Formula 33 9. 5 0. 135 0. 108 In the embodiment 5 Compound 4 Formula 240 8. 8 0. 136 0. 122 In the embodiment 6 Compound 4 Formula 241 8. 6 0. 138 0. 119 In the embodiment 7 Compound 5 Formula 89 9. 4 0. 137 0. 108 In the embodiment 8 Compound 5 Formula 242 9. 0 0. 136 0. 125 In the embodiment 9 Compound 5 Formula 245 8. 9 0. 135 0. 121 In the embodiment 10 Compound 10 Formula 97 9. 3 0. 136 0. 100 In the embodiment 11 Compound 10 Formula 246 8. 9 0. 133 0. 124 In the embodiment 12 Compound 10 Formula 247 9. 2 0. 134 0. 121 In the embodiment 13 Compound 22 Formula 105 9. 2 0. 137 0. 104 In the embodiment 14 Compound 22 Formula 250 9. 3 0. 132 0. 123 In the embodiment 15 Compound 22 Formula 251 9. 1 0. 136 0. 118
