ACRYL EMULSION RESIN COMPOSITION FOR ROAD SURFACE MARKING WITH EXCELLENT WATER RESISTANCE AND BEAD ADHESIVE FORCE AND PAINT COMPOSITION FOR ROAD SURFACE MARKING USING SAME
The present invention refers to the surface of road having excellent water resistance and compression bead of road paint composition for the visibility protection acryl emulsion resin composition and relates to, more particularly quick drying paint composition available, has excellent water resistance and improved adhesion to glass beads road paint for composition of road and acryl emulsion resin composition are disclosed. Generally, a car holds a pavement indication, road safety and reduced smooth road surface for paving road traffic communication for representative of road traffic safety facility information various required number of useless under public affairs electromagnetic wave is disclosed. Such a pavement indication for a coating composition classification the-heating, room temperature-, water-soluble, fusion type, two-pack type or the like can be classification, thermoplastic resin prepared by the number using acrylic, vinyl, vinyl acrylic paint and hydro carbon orgin etc. hard resin fusion type received from the coating material and the like. Said paint for the next road such as properties required which, first, asphalt, road surface such as concrete by providing excellent adhesion and must, walk at night or dark street light and thereby to emit labels that allow excellent in bonding force with clear glass beads (Glass bead) accomplishing. Second, in addition to change little yellow result such as lowering gloss after curing by UV free hot water, excellent mechanical properties and is excellent in the supply pipe in a plasma according to a temperature change of the thermal stability, such as mobile vehicle etc. accomplishing excellent impact resistance. Third, mattress-step by lowering has excellent water resistance and adhesion without accomplishing rainwater to be deleted. Finally road sheet thereby are mobile and pedestrian passage of number is relayed within short time must be cured fast drying is, as follows. The conventional technique of road paint for look it off, (meta) acrylic to Korean registration patent 10 - 0429552 jade hour pro it will bloom trimethoxysilane, (meth) acrylic oxy profile tree (meta) acrylic silanes and [thok at the time of at least one silane monomer selected from the group consisting consisted jade hour pro the tree pro width city which will bloom 0. 2 ∼ 1. 0 weight % including 50 ∼ 90 parts by weight of acrylic ester monomer, aromatic vinyl monomer 10 ∼ 30 parts by weight and cold-crosslinked monomer 1. 0 ∼ 10 parts by weight of a monomer mixture in the mixing tank number; 10 ∼ 60 parts by weight of a monomer mixture obtained, number 0 surfactants. 2 ∼ 5 disclosure 0 parts by weight of a radical polymerization catalyst. 1 ∼ 1 parts by weight of a mixture by addition polymerization step number bath; number prepared by the addition polymerization mixture to a pH adjusting 9 ∼ 12; number 1 number 1 ∼ 10 parts by weight of a water-soluble substance including a crosslinked and cured as class diamine adding glass transition temperature which is publicly known in acrylic emulsion resin composition number 0 ∼ 20 °C over bath method. In addition, Korean registered in the total paint composition patent 10 - 1050507 carboethoxygermanium sesquioxide, 20 to 40 parts by weight of solid acrylic resin acrylic monomer solution obtained by dissolving a resin solution, 5 to 10 parts by weight of methyl methacrylate (MMA), hydroxy (HPMA) 0 hour pro the meta [khu relay [thu which will bloom. 5 to 5 parts by weight, vesicle number 0. 5 to 1 parts by weight, of surface number 0. 5 to 1 parts by weight, forbidden number 2 to 3 parts by weight of polymer, paraffin wax 0. 5 to 2 parts by weight, 10 to 20 parts by weight of colored pigment, extender pigment 40 to 50 parts by weight, dispersion number 0. 5 to 1 parts by weight, adhesion-promoting number 0. 1 to 0. 5 parts by weight, inorganic fillers 0. 1 to 0. 5 parts by weight, anti-oxidation number 0. 1 to 0. 5 parts by weight, UV stable number 0. 1 to 0. 5 parts by weight, and para - number 1 to 2 parts by weight of quick drying paint composition promoting [thol[thol] Base [tin[tin] based amine protection including publicly known in the nanometer range. In addition, the Korean registration patent 10 - 0519475 i) Tg is at least 0 °C in aqueous anionic stabilized polymeric binder, ii) (a) polymeric binder based on the total weight solids single monoethylenically unsaturated carboxylic acids, ethylenically unsaturated dicarboxylic acid half (half)- ester, ethylenically unsaturated dicarboxylic acids semi - amide, monomethyl lighter nose four [thu, monomethyl fumarate, monobutyl fumarate, acrylamido propane sulfonate, sodium vinyl sulfonate, 2 - acrylamido - 2 - methylpropanesulfonic acid, 2 - ethyl (meth) acrylate selected from meta metacryloxyethyl phosphor phosphate and at least one acid monomers 0. 3 - 20% by weight; and (b) at least one monomer; a multi-functional isocyanate amine polymer is polymerized from a monomer mixture including a monomer, and iii) pH multifunctional amine polymer composition essentially all said non - ion state up to a point where sufficient amount of volatile base mixture including risers in height to storage quickly - cured aqueous composition and publicly known in the nanometer range. In addition, Korean registration patent 10 - 1558876 which is acrylate or methacrylate repeating units, one by one or two number 2 is indicated aziridine group 3 including aziridine cured crosslinked acrylic resin, colored pigment and extender including water-soluble the visibility use freckles, said cross-linked acrylic resin cured acrylic monomer used in the polymerization aziridine number is 2 to 15 parts by weight based on the total content is characterized over road paint for publicly known water soluble composition. However, Korean registration patent 10 - 0429552 said crosslinkable monomers having a remanence of acrylic emulsion resin, i.e. acrylic silane excellent durability and resistance to abrasion and copolymerized to form the dry paint to form water inside of a door number one still vulnerable, methyl methacrylate (MMA) hour pro the meta [khu relay [thu which will bloom on the Korean registration patent 10 - 1558876 patent 10 - 1050507 Korean registration of coating composition for producing copolymer (HPMA) hydroxy, acrylate or methacrylate is a quick drying effect it can be copolymerized to form coating food for prevention expected, door number where the pour water resistance and compression bead, Korean registration patent 10 - 0519475 quick drying an aqueous composition of anionic stabilized polymeric binder dispersed state by pulverizing a composition comprised of water is not directly participate in polymerization reactions, durability and adhesion has been significantly vulnerable number point at the door. In addition, general plasma display and to said patent are acrylic monomer using glass beads slighted since time conductive by a constant time period has lapsed after the night or when a vehicle travels a recognition of traveling of the vehicle difficult to monsoon make it difficult and road sign, mattress-step number or address or cracks under weak paint for pavement moisture been point at the door. If the number points in the present invention refers to said door, for improving water reactive emulsifying number on acrylic monomer, acrylamide monomers copolymerized copolymer binder and inorganic cross-linking number to and elastic compression bead for improving adhesion to glass beads comprising the mixture composition has excellent water resistance and improved acryl emulsion resin composition and the number of road and road paint for composition under public affairs if the number less than 1000. The present invention refers to said a number and in order to solve, [formula 1] or [formula 2] number selected from reactive emulsion, acrylic monomer, acrylamide, elastic to monomer copolymerized copolymeric binder; and inorganic cross-linking number is indicated [formula 3]; by mixing a barium sulfate and bead comprising a compression circuit of acrylic emulsion resin composition and number of road excellent is interposed in 2000. [Formula 1] (In formula said, R and R ' are selected from the same or different and 1 to 3 alkyl carbon atoms, m and n are positive numbers of 1 to 10, X is NH4 Or Na are disclosed.) [Formula 2] [Formula 3] Said acrylic monomer is methyl meta arc relay [thu, meta acrylic acid, butyl meta arc relay [thu, hydroxypropyl methacrylate, ethylene glycol d meta arc relay [thu[thu], bisphenol - A [thok[thok] Hour [ley[ley] mote id isobornyl methacrylate ester, tetra ethylene glycol d meta arc relay [thu[thu], d meta arc relay [thu[thu] diethylene glycol, diethylene glycol methacrylate, hydroxyl ethyl dee child trouble [ley [thu triazole dimethylaminoethyl methacrylate, acrylic acid alkyl esters, acrylic hydroxy alkyl esters, hydroxyalkyl ester methacrylate acid, butylene glycol d meta arc relay [thu[thu], technetium d meta acryl rake ethylene glycol, polypropylene glycol d meta arc relay [thu[thu], bisphenol - A d meta arc relay [thu[thu], bisphenol - A [thok[thok] Hour [ley[ley] mote idd meta arc relay [thu[thu], pentaerythritol d meta arc relay [thu[thu], butylene glycol tree methacrylate, polyethylene glycol tree methacrylate, bisphenol - A tree methacrylate, bisphenol - A tree [thok[thok] Hour [ley[ley] mote id methacrylate, pen hit arc reel d this year tree methacrylate, alkyl methacrylate, 1 kill know methacrylate, ethyl methacrylate, isobutyl methacrylate, t - butyl methacrylate, jade [thil meta arc relay [thu n -, benzyl methacrylate, ISO-octyl methacrylate, vinyl gap claw [heyk thread 3 - methacrylate, 3. 3. 5 - trimethyl-cyclohexyl methacrylate, methacrylated acrylate, methacrylated acrylate, 1 - methyl methacrylate gap claw [heyk thread, propane d the d methyl arc relay [thu which comes, butanediol dimethyl acrylate, hexane d the d methyl arc relay [thu which comes, produces diol dimethyl acrylate, it plays but four d the d methyl arc relay [thu which comes, space d the d methyl arc relay [thu which comes, [thil[thil] Propane tree meta arc [ley[ley] [thu[thu] tree, tree the methyl the propane tree meta arc [ley which comes the [thu, 2 - hydroxy ethyl meta [khu reel a [thu, 2 - hydroxy pro the meta arc relay [thu which will bloom, 4 - hydroxy butyl acrylate, 2 - hydroxyethyl acrylate, 2 - hydroxypropyl acrylate, 4 - hydroxy butyl methacrylate, the car put arc relay [thu, the car put meta [khu relay [thu, caprolactone acrylate, [lak[lak] Ton meta [khu[khu] relay [thu[thu] caprolactam, id rock hour pro under d the arc reel which will bloom 2, 3 -, 2, 3 - d high [tu rock hour pro the meta [khu relay [thu which will bloom, polypropylene modified acrylate, polypropylene modified methacrylate, ethylene glycol ether, roh the butyl meta [khu relay [thu which rolls up, polycarbonate roh end [heyk thread meta [khu reel, 2 - ethyl [heyk[heyk] Thread meta [khu[khu] relay [thu[thu], cyclo [heyk[heyk] Thread meta [khu[khu] relay [thu[thu], methyl acrylate, propyl acrylate, isobutyl acrylate, roh the butyl arc relay [thu which rolls up, it shakes off, butyl arc relay [thu, 2 - ethyl [heyk[heyk] Thread arc relay [thu[thu], roh the jade which it rolls up [thil acryl a [thu, step neel arc [ley [thu isocyanate, is not less than 1 species selected from cycloalkyl [heyk[heyk] Thread arc relay [thu[thu] number and is interposed in 2000. In addition, said acrylic monomer is methyl meta arc relay [thu, meta acrylic acid, 2 - ethyl [heyk[heyk] Thread arc relay [thu[thu] roh it is a butyl arc relay [thu which rolls up and number and is interposed in a system is. In addition, imparting monomer d butyl [phwu male [thu (Dibutylfumalate) is interposed in said number system is elastic and melt viscosity of 0.1. In addition, the present invention refers to said bead preventing circuit of acrylic emulsion resin composition coating having excellent water resistance and by addition of road number, number on drying propensity, vesicle number, number surfactants, number of surface, number inhibited polymerization, colored pigment, extender pigment, dispersion number, number of adhesion-promoting, inorganic fillers, anti-oxidation number, UV stable number, number 3 promoting class amine orgin, curing number, warm-water composition comprising at least one selected from the group consisting of number 1 and number system is road road paint for composition is interposed. A compression bead of the present invention excellent water resistance and water protection acrylic emulsion resin composition for improving the surface of road on acrylate or methacrylate monomer is copolymerized polymer binder and reactive emulsifying number compression bead for improving inorganic cross-linking number included in the glass beads has excellent water resistance for durability and excellent effects in adhesion is improved road visibility of the flow tides. The present invention refers to, [formula 1] or [formula 2] number selected from reactive emulsion, acrylic monomer, acrylamide, elastic to monomer copolymerized copolymeric binder; and inorganic cross-linking number is indicated [formula 3]; by mixing a barium sulfate and bead comprising a compression circuit of acrylic emulsion resin composition characterized by excellent road technology of road surface. [Formula 1] (In formula said, R and R ' are selected from the same or different and 1 to 3 alkyl carbon atoms, m and n are positive numbers of 1 to 10, X is NH4 Or Na are disclosed.) [Formula 2] [Formula 3] Said acrylic monomer is methyl meta arc relay [thu, meta acrylic acid, butyl meta arc relay [thu, hydroxypropyl methacrylate, ethylene glycol d meta arc relay [thu[thu], bisphenol - A [thok[thok] Hour [ley[ley] mote id isobornyl methacrylate ester, tetra ethylene glycol d meta arc relay [thu[thu], d meta arc relay [thu[thu] diethylene glycol, diethylene glycol methacrylate, hydroxyl ethyl dee child trouble [ley [thu triazole dimethylaminoethyl methacrylate, acrylic acid alkyl esters, acrylic hydroxy alkyl esters, hydroxyalkyl ester methacrylate acid, butylene glycol d meta arc relay [thu[thu], technetium d meta acryl rake ethylene glycol, polypropylene glycol d meta arc relay [thu[thu], bisphenol - A d meta arc relay [thu[thu], bisphenol - A [thok[thok] Hour [ley[ley] mote idd meta arc relay [thu[thu], pentaerythritol d meta arc relay [thu[thu], butylene glycol tree methacrylate, polyethylene glycol tree methacrylate, bisphenol - A tree methacrylate, bisphenol - A tree [thok[thok] Hour [ley[ley] mote id methacrylate, pen hit arc reel d this year tree methacrylate, alkyl methacrylate, 1 kill know methacrylate, ethyl methacrylate, isobutyl methacrylate, t - butyl methacrylate, jade [thil meta arc relay [thu n -, benzyl methacrylate, ISO-octyl methacrylate, vinyl gap claw [heyk thread 3 - methacrylate, 3. 3. 5 - trimethyl-cyclohexyl methacrylate, methacrylated acrylate, methacrylated acrylate, 1 - methyl methacrylate gap claw [heyk thread, propane d the d methyl arc relay [thu which comes, butanediol dimethyl acrylate, hexane d the d methyl arc relay [thu which comes, produces diol dimethyl acrylate, it plays but four d the d methyl arc relay [thu which comes, space d the d methyl arc relay [thu which comes, [thil[thil] Propane tree meta arc [ley[ley] [thu[thu] tree, tree the methyl the propane tree meta arc [ley which comes the [thu, 2 - hydroxy ethyl meta [khu reel a [thu, 2 - hydroxy pro the meta arc relay [thu which will bloom, 4 - hydroxy butyl acrylate, 2 - hydroxyethyl acrylate, 2 - hydroxypropyl acrylate, 4 - hydroxy butyl methacrylate, the car put arc relay [thu, the car put meta [khu relay [thu, caprolactone acrylate, [lak[lak] Ton meta [khu[khu] relay [thu[thu] caprolactam, id rock hour pro under d the arc reel which will bloom 2, 3 -, 2, 3 - d high [tu rock hour pro the meta [khu relay [thu which will bloom, polypropylene modified acrylate, polypropylene modified methacrylate, ethylene glycol ether, roh the butyl meta [khu relay [thu which rolls up, polycarbonate roh end [heyk thread meta [khu reel, 2 - ethyl [heyk[heyk] Thread meta [khu[khu] relay [thu[thu], cyclo [heyk[heyk] Thread meta [khu[khu] relay [thu[thu], methyl acrylate, propyl acrylate, isobutyl acrylate, roh the butyl arc relay [thu which rolls up, it shakes off, butyl arc relay [thu, 2 - ethyl [heyk[heyk] Thread arc relay [thu[thu], roh the jade which it rolls up [thil acryl a [thu, step neel arc [ley [thu isocyanate, is not less than 1 species selected from cycloalkyl [heyk[heyk] Thread arc relay [thu[thu] characterized technology of. In addition, said acrylic monomer is methyl meta arc relay [thu, meta acrylic acid, 2 - ethyl [heyk[heyk] Thread arc relay [thu[thu] roh it is a butyl arc relay [thu which rolls up and characterized describes configuration. In addition, 0.1 d butyl [phwu male [thu (Dibutylfumalate) characterized technology of said elastic to monomer. In addition, the present invention refers to said bead preventing circuit of acrylic emulsion resin composition coating having excellent water resistance and by addition of road number, number on drying propensity, vesicle number, number surfactants, number of surface, number inhibited polymerization, colored pigment, extender pigment, dispersion number, number of adhesion-promoting, inorganic fillers, anti-oxidation number, UV stable number, number 3 promoting class amine orgin, curing number, number 1 composition comprising at least one selected from the group consisting of warm-road road technology of paint for composition characterized. First, a compression bead of the present invention excellent in water resistance and protection acrylic emulsion resin composition [formula 1] or [formula 2] road road selected from reactive emulsifying number, acrylic monomer, acrylamide, elastic to monomer copolymerized copolymeric binder; and [formula 3] inorganic cross-linking number is indicated; by mixing with each other. [Formula 1] (In formula said, R and R ' are selected from the same or different and 1 to 3 alkyl carbon atoms, m and n are positive numbers of 1 to 10, X is NH4 Or Na are disclosed.) [Formula 2] [Formula 3] [Formula 1] or [formula 2] is selected from said reactive emulsifying number said acrylic monomer to enhance water resistance, acrylamide, monomer to form a copolymer copolymerized directly in response to elastic for the protection of road does not exist an excellent water resistance paint composition are disclosed. The, [formula 1] or [formula 2] said selected from acrylic monomers include methyl meta arc relay [thu on a reactive emulsifying number presnece, meta acrylic acid, butyl meta arc relay [thu, hydroxypropyl methacrylate, ethylene glycol d meta arc relay [thu[thu], bisphenol - A [thok[thok] Hour [ley[ley] mote id isobornyl methacrylate ester, tetra ethylene glycol d meta arc relay [thu[thu], d meta arc relay [thu[thu] diethylene glycol, diethylene glycol methacrylate, hydroxyl ethyl dee child trouble [ley [thu triazole dimethylaminoethyl methacrylate, acrylic acid alkyl esters, acrylic hydroxy alkyl esters, hydroxyalkyl ester methacrylate acid, butylene glycol d meta arc relay [thu[thu], technetium d meta acryl rake ethylene glycol, polypropylene glycol d meta arc relay [thu[thu], bisphenol - A d meta arc relay [thu[thu], bisphenol - A [thok[thok] Hour [ley[ley] mote idd meta arc relay [thu[thu], pentaerythritol d meta arc relay [thu[thu], butylene glycol tree methacrylate, polyethylene glycol tree methacrylate, bisphenol - A tree methacrylate, methacrylate [thok[thok] Hour [ley[ley] mote id non-Professor li - A tree, tree pen hit arc reel d this year methacrylate, alkyl methacrylate, cycloalkyl methacrylate, ethyl methacrylate, isobutyl methacrylate, t - butyl methacrylate, n - jade [thil meta arc relay [thu, benzyl methacrylate, ISO-octyl methacrylate, vinyl gap claw [heyk thread 3 - methacrylate, 3. 3. 5 - trimethyl-cyclohexyl methacrylate, methacrylated acrylate, methacrylated acrylate, 1 - methyl methacrylate gap claw [heyk thread, propane d the d methyl arc relay [thu which comes, butanediol dimethyl acrylate, hexane d the d methyl arc relay [thu which comes, produces diol dimethyl acrylate, it plays but four d the d methyl arc relay [thu which comes, space d the d methyl arc relay [thu which comes, [thil[thil] Propane tree meta arc [ley[ley] [thu[thu] tree, tree the methyl the propane tree meta arc [ley which comes the [thu, 2 - hydroxy ethyl meta [khu reel a [thu, 2 - hydroxy pro the meta arc relay [thu which will bloom, 4 - hydroxy butyl acrylate, 2 - hydroxyethyl acrylate, 2 - hydroxypropyl acrylate, 4 - hydroxy butyl methacrylate, the car put arc relay [thu, the car put meta [khu relay [thu, caprolactone acrylate, [lak[lak] Ton meta [khu[khu] relay [thu[thu] caprolactam, id rock hour pro under d the arc reel which will bloom 2, 3 -, 2, 3 - d high [tu rock hour pro the meta [khu relay [thu which will bloom, polypropylene modified acrylate, polypropylene modified methacrylate, ethylene glycol ether, roh the butyl meta [khu relay [thu which rolls up, polycarbonate roh end [heyk thread meta [khu reel, 2 - ethyl [heyk[heyk] Thread meta [khu[khu] relay [thu[thu], cyclo [heyk[heyk] Thread meta [khu[khu] relay [thu[thu], methyl acrylate, propyl acrylate, isobutyl acrylate, roh the butyl arc relay [thu which rolls up, it shakes off, butyl arc relay [thu, 2 - ethyl [heyk[heyk] Thread arc relay [thu[thu], roh the jade which it rolls up [thil acryl a [thu, step neel arc [ley [thu isocyanate, selected from at least one cycloalkyl [heyk[heyk] Thread arc relay [thu[thu] be a 1. More preferably said acrylic monomer is methyl meta arc relay [thu, meta acrylic acid, 2 - ethyl [heyk[heyk] Thread arc relay [thu[thu] preferably n-roh the butyl arc relay [thu which rolls up and the public. Wherein said copolymer is acrylic monomer coating film hardness and flexibility (stretchable), words time, drying time, asphalt and concrete carried at the back of the adhesion, workability, storage can be presnece considering at least one inclination amount. In addition, imparting monomer d butyl [phwu male [thu (Dibutylfumalate) reacting said elastic copolymer coating film formed through the elastic surface of road marker, the exterior of crack to have, in addition, said inorganic cross-linking number is used for improving the visibility road coating sparged glass bead of the wafer and, the, said inorganic cross-linking number comprises water, ethylene glycol, propylene glycol, deep with it will bloom, [leyn the glycol, polyethylene glycol solvent selected from mixed with each other. Said bead of the present invention such as water resistance and toughness and abrasion protection acrylic emulsion resin composition has a glass transition temperature (Tg) by addition of road excellent range is 15 to 25 °C, 50 provided 200cps and viscosity, pH 10 - 11 is bigger range, said range of coating by using hardness and durability, adhesion, appropriate values can be flexible (elastic) to, antiseptic number can be stored further comprises stability I.e., when less than a glass transition temperature of acrylic emulsion resin composition of the present invention 15 °C, contaminants attached to poor visibility and drying coating film, and soft coating formed in poor abrasion resistance, higher than a glass transition temperature of 25 °C, renders it incapable of forming a uniform coating film-forming ability is poor to the first number is equal to the door. In addition, ammonia is used to adjust pH number additive is used, thereby allowing the pH range should a 10 - 11. PH during storage is less than 10 moved number where the solidifying agent causing crosslinking reaction viscosity is sometimes fails to door, which door is that emptiness adipic acid pH exceeds 11 is equal to the number. On the other hand, said bead having excellent water resistance and water protection acrylic emulsion resin composition by addition of road, coating preventing number, number on drying propensity, ammonia water, vesicle number, number surfactants, number of surface, number inhibited polymerization, colored pigment, extender pigment, TiO2, dispersion number, number of adhesion-promoting, inorganic fillers, calcium carbonate, methanol, fist size tank number, anti-oxidation number, UV stable number, number 3 promoting class amine orgin, curing number, number hot water heater, selected from the group consisting of composition comprising at least one thickening number 1 paint for road road number can be high pressure liquid coolant composition. Said coating preventing fatty acid (fatty acid) number (ethylene oxide) is added to ethylene oxide is a silica compounds can be, 2 - 10 mole number of ethylene oxide (ethylene oxide) improved drying said added polyethylene glycol (polyethylene glycol) and 2 - ethyl [heyk the thread it buys (2 a-ethylhexyl acid) polycondensation of a compound can be made. Said vesicle number number number or operation within a silicon-based antifoaming morning fair paint as a stand-alone dry paint by number space has bubbles appearance, using said vesicle number does not bubble strength and the use of parking or stopping a door number appearing opposite excess crater developing generated point. Said surfactants of anionic surfactants is preferably number using number. The content of paint composition in combination with said number surfactants may affect stability in storage stability because preferably using appropriate range. Said at least one selecting number is dispersed organic inorganic pigment can be wet dispersion number distribution number. Said number is dispersed in the coating toward the paint pigment and extender pigment is formed of an enhance visual effects and concealment force affecting the solenoid can be paint and storage stability. Said hot water heater in winter and number is used to constructing paint composition, is widely used in the field of paint added other plural number description supplied from a substrate. In the present invention hereinafter in the embodiment of the present invention preferred embodiment is hereinafter for person with skill in the art is provided to through to detailed as follows. However the present invention refers to several different can be embodied in the form, in the embodiment is not limited to the taught herein. [Of the present invention acrylic Emulsion Resin composition number bath] First, main reactor water 247. 038g, represented by [formula 1] a reactive emulsifying number 2 (Antox MS provided 60, Nippon Nyukazai yarn). 955g, sodium carbonate (Na2CO 3) 1. 296g-gate which can be heated above 80 °C. Next, emulsion bath water 153. 249g, represented by [formula 1] a reactive emulsifying number (Antox MS provided 60, Nippon Nyukazai yarn) 16. 777g, acrylamide (AAm) 2. 493g, d butyl [phwu male [thu (dibutylfumalate) 1. 999g, methyl meta arc relay [thu 248 (MMA). 962g, n - butyl acrylate (n-a BAM) 218. 295g, [heyk[heyk] Thread arc relay [thu[thu] ethyl 2 - (2 a-ethylhexylacrylate) 12. 268g, meta acrylic acid (MAA) 1. 959g an emulsifying and the right rear pre - emulsion (Pre-a E). Then week reaction apparatus temperature while checking a pre - 4 weight % emulsion in a reservoir which can be emulsion (Pre-a E) in week reaction apparatus, catalyst (water 4. 987g APS (Amonium Persulfate) to 1. 197g a seed) is put in the 30 minutes 1 difference reaction of abortion. 1 difference after reaction, water in week reaction apparatus 1. 344g which can, remaining free - 96% by weight emulsion bath emulsion (Pre-a E) following dosing with catalyst (water 27. 961g APS (Amonium Persulfate) to 1. 197g a seed) was dripped in a time 80 provided 88 °C 3. After dropping, aging is performed 1 time, cooling it. During the, (butyl peroxy hydroxide) aqueous solution t a-BHPO(water 2. 393g t a-BHPO 0 to. 02g for melting a) Sodium formaldehye sulfate (Rongalite) on (water 2. 393g Rongalite 0 to. 02g for melting a) was input. 13 then ammonia in 40 °C hereinafter. 403g chamber when a, Triton CF provided 10 (emulsion number, Dow yarn number bath) aqueous solution (water 8. 066g to Triton CF-a 10 9. 948g for melting a), inorganic crosslinking number aqueous solution (water 16. 131g [formula 3] the inorganic cross-linking number (Z-a 6030, dow Corning yarn number bath) 3. 63g for melting a), antiseptic number 0 (XL-a 2, DSM yarn number bath). 019g number resin composition of the present invention acrylic emulsion was followed by high pressure liquid coolant. [Table 1] said number prepared by the acrylic emulsion resin composition is 15 to 25 °C glass transition temperature (Tg) as shown in the variation range, viscosity and 50 provided 200cps, been pH range is 10 - 11. [In the embodiment 2 - 5 and comparison example 1] [Table 1] of the present invention such as shown by addition to the composition of excellent water resistance and bead number was high pressure liquid coolant onto the surface of road protection acryl emulsion resin composition and comparison. [Comparison example 1] A-a 102 is Cytec yarn number used in anionic emulsion are disclosed. [Properties test] [Comparison example 1] [in the embodiment 5 in the embodiment 1 to] and [table 2] according to the following test method to measure the property and compositions have shown. (Water resistance) The saline water discoloration exfoliation of 1 - 3 mm plate formed coating allowing the user to view abnormality was assessed. (Alkali) 1 - 3 mm to 10% caustic soda solution such as saline and slats plate formed film exfoliation than the observation of discoloration was assessed. (Concrete adhesion) About 50 - 100 micro m to concrete to be coated with a after drying, user X after the dead knife, corner it scrapes out, separating knife coating concrete and observation was assessed (Asphalt (Asphalt) adherent) About 50 - 100 μm vinyl aromatic hydrocarbon to the user after the dead it scrapes out, X knife after drying to be coated with a coating of asphalt separating knife corner observation was assessed. (Adhesion of glass beads) In tester 200 turns of about 300 kg under wheel vertical load during recovery test piece glass beads of attachment for a long time. As shown in the [table 2] said, excellent water resistance and bead protection acrylic emulsion resin composition by addition of road resistance, acid resistant, alkali, concrete and asphalt adhesion, excellent physical properties such glass beaded-opened by paint for composition of road can confirm it can be preferably used. [Paint composition for the visibility road number bath] In high pressure liquid coolant to said [in the embodiment 1] [table 3] number acrylic emulsion resin composition such as the composition of the paint composition number road road surface binding was shown high pressure liquid coolant. A feature of the present invention sends more description is provided to exemplify the generally described, the present invention if the properties of the present invention is provided to essentially inputted from deviating from a person with skill in the art in various modifications and deformable will. Thus, the present invention in the embodiment of the present invention are to define the disclosure but rather to explain the feature and, in the embodiment of the present invention by not the limited range of such feature. Under the protection range of the present invention must be interpreted by fee so as to range, and the range of the present invention feature in a range equal to all rights will be interpreted. The present invention relates to an acryl emulsion resin composition with excellent water resistance and improved adhesive force to glass beads, the acryl emulsion resin composition which is usable in a quick drying paint composition, and a paint composition for road surface marking using the acryl emulsion resin composition. More specifically, the present invention relates to an acryl emulsion resin composition for road surface marking with excellent water resistance and bead adhesive force, the acryl emulsion resin composition which is prepared by comprising and mixing a copolymer binder in which a reactive emulsifier selected from chemical formula 1 or chemical formula 2, an acryl monomer, an acrylamide and an elasticity providing monomer are copolymerized; and an inorganic cross-linking agent represented by chemical formula 3. In chemical formula 1, R and R′, which are the same as or different from each other, are alkyl groups having 1 to 3 carbon atoms, m and n are integers of 1 to 10, and X is NH_4 or Na. COPYRIGHT KIPO 2017 [Formula 1] or [formula 2] number selected from reactive emulsion, acrylic monomer, acrylamide, elastic to monomer copolymerized copolymeric binder; and [formula 3] inorganic cross-linking number is indicated; mixture composition including mounted, said acrylic monomer is methyl meta arc relay [thu, meta acrylic acid, butyl meta arc relay [thu, hydroxypropyl methacrylate, ethylene glycol d meta arc relay [thu[thu], bisphenol - A [thok[thok] Hour [ley[ley] mote id isobornyl methacrylate ester, tetra ethylene glycol d meta arc relay [thu[thu], diethylene glycol d meta arc relay [thu[thu], diethylene glycol methacrylate, hydroxyl ethyl dee child trouble [ley [thu triazole dimethylaminoethyl methacrylate, acrylic acid alkyl esters, acrylic hydroxy alkyl esters, hydroxyalkyl ester methacrylate acid, butylene glycol d meta arc relay [thu[thu], technetium d meta acryl rake ethylene glycol, polypropylene glycol d meta arc relay [thu[thu], bisphenol - A d meta arc relay [thu[thu], bisphenol - A [thok[thok] Hour [ley[ley] mote idd meta arc relay [thu[thu], pentaerythritol d meta arc relay [thu, butylene glycol tree methacrylate, polyethylene glycol tree methacrylate, bisphenol - A tree methacrylate, bisphenol - A tree [thok[thok] Hour [ley[ley] mote id methacrylate, pen hit arc reel d this year tree methacrylate, alkyl methacrylate, cycloalkyl methacrylate, ethyl methacrylate, isobutyl methacrylate, t - butyl methacrylate, jade [thil meta arc relay [thu n -, benzyl methacrylate, ISO-octyl methacrylate, vinyl gap claw [heyk thread 3 - methacrylate, 3. 3. 5 - trimethyl-cyclohexyl methacrylate, methacrylated acrylate, methacrylated acrylate, 1 - methyl methacrylate gap claw [heyk thread, propane d the d methyl arc relay [thu which comes, butanediol dimethyl acrylate, hexane d the d methyl arc relay [thu which comes, produces diol dimethyl acrylate, it plays but four d the d methyl arc relay [thu which comes, space d the d methyl arc relay [thu which comes, [thil[thil] Propane tree meta arc [ley[ley] [thu[thu] tree, tree the methyl the propane tree meta arc [ley which comes the [thu, 2 - hydroxy ethyl meta [khu reel a [thu, 2 - hydroxy pro the meta arc relay [thu which will bloom, 4 - hydroxy butyl acrylate, 2 - hydroxyethyl acrylate, 2 - hydroxypropyl acrylate, 4 - hydroxy butyl methacrylate, the car put arc relay [thu, the car put meta [khu relay [thu, caprolactone acrylate, [lak[lak] Ton meta [khu[khu] relay [thu[thu] caprolactam, id rock hour pro under d the arc reel which will bloom 2, 3 -, 2, 3 - d high [tu rock hour pro the meta [khu relay [thu which will bloom, polypropylene modified acrylate, polypropylene modified methacrylate, ethylene glycol ether, roh the butyl meta [khu relay [thu which rolls up, polycarbonate roh end [heyk thread meta [khu reel, 2 - ethyl [heyk[heyk] Thread meta [khu[khu] relay [thu[thu], cyclo [heyk[heyk] Thread meta [khu[khu] relay [thu[thu], methyl acrylate, propyl acrylate, isobutyl acrylate, roh the butyl arc relay [thu which rolls up, it shakes off, butyl arc relay [thu, 2 - ethyl [heyk[heyk] Thread arc relay [thu[thu], roh the jade which it rolls up [thil acryl a [thu, step neel arc [ley [thu isocyanate, cyclo [heyk[heyk] Thread arc relay [thu[thu] 1 and at least one selected from the, characterized in that said elastic to monomer (Dibutylfumalate) barium sulfate and bead d butyl [phwu male [thu in excellent protection acryl emulsion resin composition [formula 1] by addition of road (In formula said, R and R ' are selected from the same or different and 1 to 3 alkyl carbon atoms, m and n are positive numbers of 1 to 10, X is NH4 Or Na are disclosed.) [formula 2] [Formula 3] Back number According to Claim 1, said acrylic monomer is methyl meta arc relay [thu, meta acrylic acid, 2 - ethyl [heyk[heyk] Thread arc relay [thu[thu] roh it is a butyl arc relay [thu which rolls up and characterized by addition of road excellent barium sulfate and bead protection acryl emulsion resin composition Back number Number 1 or number 3 according to the surface of road having excellent water resistance and anti protection acrylic emulsion resin composition by addition anti bead, coating preventing number, number on drying propensity, vesicle number, number surfactants, number of surface, number inhibited polymerization, colored pigment, extender pigment, dispersion number, number of adhesion-promoting, inorganic fillers, anti-oxidation number, UV stable number, number 3 promoting class amine orgin, curing number, number 1 composition comprising at least one selected from the group consisting of warm-water heater characterized in that the paint composition for the visibility roadIn the embodiment 1 In the embodiment 2 In the embodiment 3 In the embodiment 4 In the embodiment 5 Comparison example 1 Water resistance Good Good Good Good Good Fine peeling Alkali resistance Good Good Good Good Good Good Concrete adhesion Good Good Good Good Good Good Asphalt adhesion Good Good Good Good Good Fine peeling Glass bead attachment condition Good Good Good Good Good Attaching