ADHESIVE RESIN COMPOSITION AND LAMINATE MADE USING THE SAME AS ADHESIVE LAYER

The present invention adhesion-resin composition at least unsaturated carboxylic acid or derivative thereof grafted amount 0.01 ∼ 30 weight % having a part or wholly grafted modified α-olefin/aromatic vinyl compound random copolymer and comprising at.

The present invention adhesion-resin composition (A) ingredient below-mentioned characteristic e.g. mol, in total of acetone (B) and 100 parts by weight:

(A) unsaturated carboxylic acid or derivative thereof grafted amount 0.01 ∼ 30 weight % having a part or wholly grafted ethylene/aromatic vinyl compound copolymer, 1 ∼ 80 parts by weight; and

(B) α-olefin of 3 ∼ 20 carbon atoms derived from an ethylene constituting unit constituting unit derived from molar ratio of 45/55 ∼ 95/5 (ethylene / α-olefin) is an ethylene / α-olefin copolymer, and apparatus for proportioning and mixing content 5 ∼ 40 weight % α-olefm polymer that has a/vinyl acetate copolymer selected from 1 the minimum one of ductile polymer is a composition 20 ∼ 99 parts by weight of.

The present invention adhesion-resin composition ethylene polymer or modified water, and/or propylene polymer or modified product a part or all modified α-olefin/aromatic vinyl random copolymer mol, in total of acetone (B) polymer and ductility (A) 100 parts by weight. particles may further include 0.1 ∼ 50 parts by weight.

The adhesive resin composition of the present invention the hot fill or packaging [...] in retort container for forming a device for displaying information for elevator as an adhesive, use can be made of, preferably.

Stack number 1 by the present invention:

(I) polyester unit has a sliding unit,

(II) said adhesive resin composition to an adhesive layer formed from, and

151 a saponified olefin/vinyl acetate copolymer (III) are composed.

The laminate of the present invention number 2;

(I) poly [...] ,

(II) said adhesive resin composition to an adhesive layer formed from, and

151 a saponified olefin/vinyl acetate copolymer (III) are composed.

The hot fill or [...] in retort container by the present invention said laminate formed from packaging.

For solar the best of the present invention embodiment

Composition resin composition adhesion-the present invention a laminate using a detailed a.

First, adhesive resin composition a described.

The present invention adhesion-resin composition based on graft modified α-olefin/aromatic vinyl which random copolymer in which the, other, an ethylene / α-olefin copolymer or ethylene/vinyl acetate copolymer such as flexible polymer and comprising at. The described to these components.

Graft modified α-olefin/aromatic vinyl compound random copolymer

The present invention used a graft modified α-olefin/aromatic vinyl compound random copolymer (to often "modified copolymer" referred signals from the input circuit) the α-olefin/aromatic vinyl random copolymer in which the unsaturated carboxylic acid or a part or derivatives is produced by-modified wholly grafted.

Graft modified α-olefin/aromatic vinyl random copolymer preparation start material α-olefin/aromatic vinyl random copolymer may comprise ethylene and aromatic vinyl compound carboxylic acid and a random copolymer of (ethylene/aromatic vinyl compound copolymer,) or ethylene, α-olefin and 3 ∼ 20 carbon atoms of carboxylic acid and a random copolymer of aromatic vinyl compound (ethylene / α-olefin/aromatic vinyl compound copolymer,) is.

Ethylene/aromatic vinyl compound copolymer, in, the amount of of a constituting unit derived from ethylene 99.95 ∼ 70 mol %, preferably 99.90 ∼ 80 mol %, more preferably 99.00 ∼ 88 mol % ; of a constituting unit derived from aromatic vinyl compound the amount of 0.05 ∼ 30 mol %, preferably 0.10 ∼ 20 mol %, more preferably is 1.00 ∼ 12 mol %.

Of a constituting unit derived from aromatic vinyl compound combines received said less than the amount of if the key, are compositions produced of heat resistance and adhesion force often is lowering. Of a constituting unit derived from aromatic vinyl compound the amount of if not, the mobile the upper limit range of said, are compositions produced of heat resistance and adhesion force often is lowering.

Examples of aromatic vinyl compound styrene; o-methylstyrene, m-methylstyrene, p-methylstyrene, o, p-dimethyl styrene, o-ethyl styrene, m-ethyl styrene and styrene polyalkyl or mono such as styrene-ethyl p; [...] , [...] , acid, methyl vinyl benzoate, vinyl benzyl acetate, hydroxystyrene, o-chloro styrene, p-chloro styrene and divinylbenzene such as functional group-containing styrene derivative; 3-phenyl propylene; 4-phenyl butene and α-methylstyrene as to the aromatic hydrocarbon. [...] preferably 4-styrene and is selected from them.

In ethylene/aromatic vinyl compound random copolymer, ethylene α-olefin other than having different diameters copolymerizable with vinyl compound polyaromatic preferably. Α-olefin examples of propylene, 1-butene, 3-methyl-1-butene, 4-methyl-1-butene, 1-pentene, 1-hexene, 4-methyl-1-pentene, 1-hepten, 1-octene, 1-nonene, 1-hexadecene, 1- fortune it counted , 1-dodecene, 1-hexadecene tree, tetra 1-hexadecene, 1- the pen it burnt and it counted , 1-hexadecene, 1- [...] , 1-octadecene, 1-1-and it plays but it counted can carbons such as pherocene eicosa of α-olefin: 3 ∼ 20. These polyolefin is a-α, alone or in combination on the paper 2, use can be made of,.

Ethylene / α-olefin/aromatic vinyl compound copolymer, in,

Derived from α-olefin of 3 ∼ 20 carbon atoms of a constituting unit of a constituting unit derived from an ethylene molar ratio of the (ethylene / α-olefin) 99/1 ∼ 70/30, preferably 99/1 ∼ 80/20, more preferably is 99/1 ∼ 90/10;

Can and the carbon of a constituting unit derived from ethylene α-olefin of 3 ∼ 20 of a constituting unit derived from the 99.95 ∼ 70 mol % mol, in total of acetone, preferably 99.90 ∼ 80 mol %, more preferably is 99.00 ∼ 88 mol %;

Of a constituting unit derived from aromatic vinyl compound the amount of 0.05 ∼ 30 mol %, preferably 0.10 ∼ 20 mol %, more preferably is 0.10 ∼ 12 mol %.

Amount of of a constituting unit derived from ethylene, α-olefin derived from 3 ∼ 20 of carbon atoms of a constituting unit derived from aromatic vinyl compound and amount of the amount of each of a constituting unit when said range, generating composition possesses superior heat resistance and pressure resistance and adhesion.

Α in random copolymer in which the-olefin/aromatic vinyl, nonconjugated diene and then preferably dots sum public monomers. Examples of nonconjugated diene 1, 4-cyclopentadiene, 1, 4-hexadiene, [...] 4-methyl -1, 5-n, 5-methylene-2-norbornene, 5-ethylidene-2-norbornene, 5-isopropenyl--2-norbornene, 2, 5-nor [...] n, crow jade other D cycle 1, 6-n, 2-ethylene -2, 5-nor [...] n, 2-isopropenyl--2, 5-nor [...] n, d it is cheap this crow pen hit D n, 1, 6-octadiene, 1, 7-octadiene, tree it is cheap this crow pen hit D n, and d high draw D it is cheap to this crow pen hit D the Neel jade hour ethylene ester and unsaturated carboxylic acid (e.g.: acrylic acid, methacrylic acid, itaconic, maleic acid and fumaric acid) :. On the paper 2 or alone is nonconjugated diene, use can be made of, combination.

Α-olefin/aromatic vinyl of random copolymers measured among decalines 135 °C extreme viscosity the 0.1 ∼ 10 dl/g, preferably 0.5 ∼ 8 dl/g, more preferably is 1 ∼ 5 dl/g. As measured by means of a in differential scanning calorimeter in addition α-olefin/aromatic vinyl of random copolymers in endothermic curve , the 60 ∼ 125 °C maximum peak the temperature of the radiation unit (Tm), preferably is 70 ∼ 110 °C. In this case having excellent heat resistance may yield an adhesion resin composition.

Α in random copolymer in which the-olefin/aromatic vinyl, aromatic vinyl compound configured derived from aromatic vinyl compound unit 2 at least derived from the ratio of continuous a structural unit of two 1% hereinafter, preferably preferably is 0.1% hereinafter. Aromatic vinyl compound derived from the subsequent rate in units of both components 2¹³ C-NMR is determined by Tc.

Α-olefin/aromatic vinyl random copolymer when ethylene/aromatic vinyl compound copolymer, copolymer¹³ C-NMR B estimated equation a spectral, 0.80 ∼ 2.00 value, preferably 0.90 ∼ 1.50, more preferably 0.95 ∼ 1.45, is in particular preferably 1.00 ∼ 1.40.

B= [P_SE] / (2, [P_E], [P_S])

Formula [P_E] of ethylene/aromatic vinyl compound copolymer, in constituting unit derived from ethylene (% of an ethylene unit and) is acid, [P_S] of ethylene/aromatic vinyl compound copolymer, in constituting unit derived from aromatic vinyl compound (aromatic vinyl compound units and having an at) is acid, [P_SE] of ethylene/aromatic vinyl compound copolymer, in all of the diameter can [...] an ethylene unit-aromatic vinyl compound units and having an at is immediately successive, or the proportion of.

Copolymer value B % of an ethylene unit and in is index distribution of and aromatic vinyl compound units and having an at, J. C. Randall of report (Macromolecules, 15,353 (1982)) based on the save.

For a larger value B, ethylene or continuous form of blocks of aromatic vinyl compound units and having an at, resulting, from an existing set of short. Is ethylene units and aromatic vinyl compound units and having an at blades, presenting a uniformity of the distribution of. When B value smaller than 1, % of an ethylene unit and and aromatic vinyl compound units and having an at which having a uniform distribution of, ethylene or long continuous form of blocks of aromatic vinyl compound units and having an at the free surfaces.

Then α-olefin/aromatic vinyl random for the preparation of a copolymer a describes a method.

The present invention for use in α-olefin/aromatic vinyl random copolymer may comprise ethylene, aromatic vinyl compound, and optionally carbon atoms thereby 3 ∼ 20 of α-olefins in the presence of (a) metallocene can be are prepared by copolymerizing.

Metallocene as (a), and commonly used with end entrusting whip catalyst and similar to various catalytic such as catalyst in special without limitation, use can be made of,. In particular, (b) metallocene compound, metal transition (and transion metal compound employable), organic aluminium oxy compound (c) and/or ionization ionic compounds which are using a catalyst which comprises a compound of (d) it is preferable that the.

Examples of suitable metallocene compound, (b) revision method designated IUPAC inorganic chemistry (1989) that is represented as group 1-18 of (other leaf tranion ring cotter pin and core liner) of periodic table at selected from group 4 metallocene compound, metal transition, high yield general formula (1) can be mentionned with the harmony which it counts it will ask metal represented by.

MLx (1)

Said type (1) in, M family element 4 of the periodic table and transion metal compound employable selected from, for example, zirconium, titanium or half [...] , is transition has x metal atoms.

L in metal transmittivity coordination coordinating the transition. At least one ligand to crow pen hit D Neel substituted L strips even when they have a coordination to metals as compared with the good transmittivity.

Examples's coordination to metals as compared with to crow pen hit D Neel cycle to crow pen hit D Neel cycle, methyl it is cheap to this crow pen hit D Neel , ethyl it is cheap to this crow pen hit D Neel , n or i it is cheap to this crow pen hit D Neel -propyl, n-, i-, it is cheap to this crow pen hit D Neel -butyl t or second, [...] , [...] , dimethyl it is cheap to this crow pen hit D Neel , tree the methyl it is cheap to this crow pen hit D Neel , tetra the methyl it is cheap to this crow pen hit D Neel , the pen hit methyl it is cheap to this crow pen hit D Neel , methyl the ethyl it is cheap to this crow pen hit D Neel , methyl pro it blooms and it is cheap to this crow pen hit D Neel , methyl the butyl it is cheap to this crow pen hit D Neel , methyl [...] , methyl it cuts quality to be cheap to this crow pen hit D Neel , ethyl the butyl it is cheap to this crow pen hit D Neel , ethyl [...] and methyl [...] such as alkyl or cycle can be mentionned neel it will raise to crow pen hit D cycle alkyl substituted chroman.

Furthermore, indenyl, 4, 5, 6, 7-tetra neel it is a draw flue and can be mentionned [...].

Trialkylsilyl or halogen atom are for. may be substituted.

Said coordination the connection is between two, in particular preferably alkyl replacement it is cheap to this crow pen hit D the Neel giga.

Said type (1) compounds represented by ligand having skeleton to crow pen hit D Neel buildup if the one or more 2, user 2 to crow pen hit D Neel cycle coordination to metals as compared with polypropylene or ethylene dog 1015 per square meter, pro it will bloom it was burnt with[...][...] substituted such as isocyanate, [...] , or dimethyl [...] , [...] methyl or [...][...] substituted such as preferably as described above may be joined to one another via.

to crow pen hit D Neel cycle coordination to metals as compared with examples of L other other than character 1-12 hydrocarbon group of carbon atoms, alkoxy groups, biting jade time , the opinion phone it buys containing (-SO₃ R¹), can be hydrogen atoms or halogen atom. Wherein R¹ the alkyl, halogen atoms, substituted alkyl, aryl, or aryl group is substituted with alkyl or halogen atom.

Examples hydrogen hydrocarbons 1-12 alkyl carbon atoms, alkyl chroman cycle, aryl and [...] surface of the radioactive part into contact and, more specifically, methyl, ethyl, n-propyl, isopropyl, n-butyl, isobutyl, second-butyl, t-butyl, neopentyl, cyclohexyl, octyl, dodecyl and midifiers targeting such as alkyl;

Such as alkyl chroman cycle [...] cycle [...] cycle;

Phenyl and tolyl such as aryl;

Benzyl and Neo such as hotfill as to the aromatic hydrocarbon of emitting layer and the anode. Alkoxy groups examples of methoxy, ethoxy, n-propoxy, isopropoxy, n-butoxy, isobutoxy, second-butoxy, t-butoxy, [...] , as to the aromatic hydrocarbon [...] and [...].

biting jade time , is phenoxy for example.

the opinion phone it buys containing (-SO₃ R¹) sulfinato sulfoalkyl methane examples of, sulfinato sulfoalkyl-toluic p, trifluoromethane sulfonate and. users can sulfinato sulfoalkyl p-trichlorobenzene.

Examples of halogen atom, fluorine, chlorine, bromine and can be mentionned liquid crystal.

Valency metal transition 4 in said type (1) metallocene compound, (b), particularly at one represented (2) is represented by:

R²_k R³_l R⁴_m R⁵_n M (2)

Said in formula, the transition M metal and , preferably zirconium and titanium, R² has one cycle each skeleton to crow pen hit D Neel (ligand) and, R³, R⁴ and a R⁵ which each same or different from the, independently cycle or double having skeleton to crow pen hit D Neel said type (1) at the time coordination to metals as compared with to crow pen hit D Neelother than character L hard mask as an etching mask, the k and integer larger than or equal to 1, is k+l+m+n = 4.

Furthermore, one represented and transion metal compound employable sheetring, and a bridge (A) using (metallocene compound,) may be loaded with.

In said type (A), M¹ IV metal family of the periodic table, for example, titanium, zirconium or hafnium is.

R¹ and R² good the same or different from the, each hydrogen, alkyl 1-3 preferably 1-10 carbon atoms, preferably alkoxy group 1-3 1-10 carbon atoms, carbon atoms preferably 6-10 6-8 aryl, preferably 6-10 6-8 biting jade time of carbon atoms, preferably 2-10 2-4 of alkenyl group carbon atoms, carbon atoms preferably 7-40 7-10 of aralkyl, aryl alkyl 7-12 preferably 7-40 carbon atoms, preferably 8-40 8-12 [...] of carbon atoms, or halogen atom is preferably chlorine.

R³ and a R⁴ which the same or different from the, each hydrogen, halogen preferably fluorine, chlorine or bromine, halogen may be reinitialized 1-10 carbon atoms, preferably 1-4 alkyl, halogen may be reinitialized 6-10 carbon atoms preferably 6-8 aryl, or-NR¹⁰₂, -SR¹⁰, -OSiR¹⁰₃, -SiR¹⁰₃ or-PR¹⁰₂ and, wherein R¹⁰ the halogen atom, preferably chlorine, preferably 1-10 1-3 alkyl carbon atoms, carbon atoms or aryl group of 6-8 preferably 6-10.

R³ and a R⁴ each hydrogen is preferably in particular.

R⁵ and a R⁶ each same or different from the preferably is similar to that of but good, R⁵ and a R⁶ each hydrogen is not the except R³ and a R⁴ equal to 10 Ps as, may be preferably a halogenated each carbon atoms 1-4 alkyl for example, methyl, ethyl, propyl, isopropyl, butyl, isobutyl or trifluoromethyl is, is preferably methyl,.

R⁷ the

=BR¹¹, =AlR¹¹, -Ge-, -Sn-, -O-, -S-, =SO, =SO₂, =NR¹¹, =CO, =PR¹¹ or =P (O) R¹¹ and, wherein R¹¹, R¹² and R¹³ which the same or different from the, each hydrogen, halogen atom, alkyl 1-4 preferably 1-10 carbon atoms, more preferably, methyl, preferably a fluoroalkyl group of 1-10 carbon atoms CF₃, 6 ∼ 10 carbon atoms preferably 6 ∼ 8 aryl, aryl group of fluorothermoplastic 6-10 carbon atoms preferably pentafluorophenyl, alkoxy group 1-4 preferably 1-10 carbon atoms in particular preferably methoxy, 2-4 of alkenyl group preferably 2-10 carbon atoms, aralkyl of 7-10 preferably 7-40 carbon atoms, preferably 8-40 8-12 [...] of carbon atoms, aryl alkyl 7-12 preferably 7-40 carbon atoms, or R¹¹ and R¹², or R¹¹ and R¹³ they with atoms, which is bound. crystal face may be formed ring.

M² a silicon, germanium or tin, preferably silicon or germanium is.

R⁷ preferably =CR¹¹ R¹², =SiR¹¹ R¹², =GeR¹¹ R¹², -O-, -S-, =SO, =PR¹¹ or =P (O) R¹¹ is.

R⁸ and R⁹ which each same or different from the, each R¹¹ as equal to.

N and m which each same or different from the, 0, 1 or 2 preferably each and 0 or 1, preferably 0, 1 or 2 the m+n is 1 or 0.

Said requirements in particular a series preferably one represented with the harmony which it counts it asked (iii)-(i) is compounds represented by general.

Said type (i), in (iii) and (ii), M¹ the Zr or Hf and, R¹ and R² each methyl or chlorine and, R⁵ and a R⁶ each methyl, ethyl or trifluoromethyl, R⁸, R⁹, R¹¹ and R¹² equal to as the stomach.

Said type (i), compounds represented by (iii) and in (ii), then compound preferably in particular:

Rac-dimethyl methylene-bis (indenyl) zirconium d claw id ,

Rac-dimethyl methylene-bis (2-methyl-1-indenyl) zirconium d claw id ,

Rac- [...] -bis (2-methyl-1-indenyl) zirconium d claw id ,

Rac-ethylene-bis (2-methyl-1-indenyl) zirconium d claw id ,

Rac-dimethyl silylene-bis (2-methyl-1-indenyl) zirconium d claw id ,

Rac-dimethyl silylene-bis (2-methyl-1-indenyl) zirconium dimethyl,

Rac-ethylene-bis (2-methyl-1-indenyl) zirconium dimethyl,

Rac-phenyl (methyl) silylene-bis (2-methyl-1-indenyl) zirconium d claw id ,

Rac- [...] -bis (2-methyl-1-indenyl) zirconium d claw id ,

Rac-methyl ethylene-bis (2-methyl-1-indenyl) zirconium d claw id , and

Rac-dimethyl silylene-bis (2-ethyl-1-indenyl) zirconium d claw id.

These metal with the harmony which it counts it asked conventional can be produced by publicly known method (for example, (EP 485822 corresponding) [...] 4-268307

In the present invention, one represented and transion metal compound employable sheetring bridges represented by (B) (metallocene compound,) may be loaded with using.

Type (B) in, which transition group IVB metal M the periodic table, specifically titanium, zirconium or hafnium is.

R¹ and R² independently from each other hydrogen, halogen atom, hydrocarbon group of 1-20 carbon atoms, halogen 1-20 anger hydrocarbon carbon atoms, silicon containing , oxygen containing , hwang containing , containing is or containing is nitrogen.

Examples of halogen atom fluorine, chlorine, bromine and can be mentionned liquid crystal.

hydrogen hydrocarbons 1-20 carbon atoms examples methyl, ethyl, profile, butyl, ethylhexyl, [...] cycle, octyl, nonyl, dodecyl, eicosa chamber, alkyl such as norbornyl and adamantyl; vinyl, propenyl and such as alkenyl group [...] ; benzyl, phenylethyl and phenylpropyl such as aralkyl; and, tolyl, dimethylphenyl, trimethylphenyl, ethyl phenyl, epoxypropyl-phenyl, biphenyl, naphthyl, naphthyl methyl, such as [...] and do not sprout three Neel can be mentionned aryl group.

hydrogen by halogenated hydrocarbons said substituted halogen atoms, examples can be mentionned groups carbide.

Silicon containing examples, dimethylsilyl and dimethylsilyl methyl hydrocarbon replacement room reel mono such as; dimethylsilyl and d phenyl thread reeld carbonization hydrogen replacement it will be recorded such as; trimethylsilyl, triethylsilyl, pro it will bloom and it will be recorded tree, tree [...] , tree phenyl thread reel , dimethyl phenyl thread reel , methyl d phenyl thread reel , tree [...] and [...]hydrocarbon replacement room reel tree such as; trimethylsilyl ether hydrocarbons hydrogen replacement room reel silyl ether; tree methyl thread reel methyl alkyl substituted silicon such as; and methyl thread reel phenyl as to the aromatic hydrocarbon replacement allyl silicon such as.

Examples containing oxygen, hydroxy group; methoxy, ethoxy, propoxy and butoxy such as alkoxy groups; phenoxy, methylphenoxy, dimethyl phenoxy and biting jade time[...] such as; phenyl as methoxy and phenylethoxy such as can be mentionned will be biting and the cock time which it will know. Examples hwang containing , containing oxygen exemplified in said oxygen in those substituted sulfur can be mentionned.

Examples of nitrogen containing , amino group; methylamino, dimethylamino, diethylamino, deep with the amino which will bloom , [...] and d butyl amino such as alkylamino; phenylamino, d phenyl amino , [...] , dinitrate, such as methyl phenyl amino amino and [...]the biting amino it will raise alkyl or arylamino can be mentionned.

Examples containing is , dimethyl [...] and [...] can be mentionned blood anger of such as.

At, R¹ hydrocarbon group is preferably, in particular preferably 1-3 carbon atoms of hydrocarbon group is (methyl, ethyl or profile). R² the preferably, the hydrogen, hydrocarbon group, in particular preferably, the hydrogen or carbon atoms of hydrocarbon group 1-3 is (methyl, ethyl or profile).

R³, R⁴, R⁵ and R⁶ independently from each other hydrogen, halogen atom, hydrocarbon group of 1-20 1-20 carbon atoms or halogenated hydrocarbon group is carbon atoms. At, hydrogen, preferably hydrogen giga by halogenated hydrocarbons or hydrocarbon. R³ and a R⁴, R⁴ and a R⁵, or R⁵ and a R⁶ at least one combination of these linked thereto at only annular aromatic nucleus with the carbon atoms. crystal face may be formed.

Malanyl group that forms except that the, hydrocarbon chain of at least 2 anger hydrocarbon giga halogen or group if present, combination with one another. crystal face may be formed ring. R⁶ is when deadline substituted other than aromatic said, it. is preferable.

Said halogen atom, hydrocarbon group of carbon atoms and 1-20 1-20 by halogenated hydrocarbons of said examples hydrogen R¹ and R² as equal to.

said R³ and a R⁴, R⁴ and a R⁵, or R⁵ and a R⁶ combination of at least one of formed by containing only annular aromatic nucleus , as a ligand coordinated thereto as a ligand in addition M, then can be mentionned and.

At, type (1) preferably self coordination which can be reproduced are displayed.

Said aromatic the halogen atom, carbon atoms of carbon atoms or hydrocarbon 1-20 1-20. may be is replaced by the processing result halogenated hydrocarbon.

Said aromatic ring for block substitution halogen atom, hydrocarbon group of carbon atoms and 1-20 1-20 by halogenated hydrocarbons of examples hydrogen R¹ and R² as equal to.

X¹ and X² independently from each other hydrogen, halogen atom, hydrocarbon group of 1-20 carbon atoms, halogen 1-20 anger hydrocarbon carbon atoms, is hwang containing or containing oxygen.

Said halogen atom, hydrocarbon group of 1-20 carbon atoms, carbon atoms examples containing and oxygen anger hydrocarbon halogen 1-20 R¹ and R² as equal to.

Said examples hwang containing , R¹ and R² equal to 10 Ps as; sulfinato sulfoalkyl methyl in addition, sulfinato sulfoalkyl trifluoromethane, sulfinato sulfoalkyl phenyl, benzyl sulfoalkyl sulfinato, sulfinato sulfoalkyl-toluic p, trimethyl benzene sulfinato sulfoalkyl, sulfinato sulfoalkyl benzene isobutyl tree, such as trichlorobenzene-p [...] and sulfinato sulfoalkyl nATO sulfoalkyl; and methyl sulfinato, phenyl sulfinato, benzyl sulfinato, p-toluic sulfinato, trimethyl benzene sulfinato and such as further can be mentionned [...]nATO sulfinyl.

1-20 anger hydrogen recarburizing 2 of the Y carbon atoms, carbon atoms of halogen anger hydrocarbon 1-20 2, 2 it will gocone containing , [...] shop 2, 2 californiathree boxes organic, -O-, -CO-, -S-, -SO-, -SO₂-, -NR⁷-, -P (R⁷)-, -P (O) (R⁷)-, -BR⁷-or-AlR⁷-and, wherein R⁷ hydrogen, halogen atom, hydrocarbon group of 1-20 1-20 carbon atoms or halogenated hydrocarbon group is carbon atoms.

2 methylene examples anger hydrogen recarburizing 1-20 of carbon atoms, dimethyl methylene, 1, 2-ethylene, dimethyl -1, 2-ethylene, 1, 3-trimethylene, tetramethylene 1, 4, 1, 2-1, 4-and [...] cycle [...] cycle such as 1015 per square meter; and diphenyl [...] can be mentionned [...] such as ethylene -1, 2-.

2 examples halogen carbonization hydrogen , for example, such as methylene chloro, halogenated said 1-20 2 of the hydrocarbon which quenches the carbon atoms can be mentionned groups.

2 examples cone containingit will go , methyl silylene, dimethyl silylene, [...] , di (n-propyl) silylene, di (i-propyl) silylene, di ([...] cycle) silylene, methyl [...] , [...] , di (p-tolyl) silylene and d (p-chlorophenyl) silylene such as alkyl silylene, alkyl [...] and [...] ; and -1, 2-tetramethyl -1, 2-tetraphenyl and [...][...][...] alkyl such as, alkyl [...] and [...] can be mentionned.

2 examples [...] shop, said 2 it will gocone containing of silicon at the this germanium-peptide antagonists of: those.

2 examples of brassware three boxescalifornia , in said it will gocone containing 2 tin silicon can be mentionned those substituted.

R⁷ the halogen atom, and hydrocarbon group of carbon atoms of 1-20 1-20 RIS by halogenated hydrocarbons, examples include R¹ and R² as equal to.

Role to said, it will gocone containing 2, 2 and 2 shop california[...]three boxes organic are preferably present in the salt, more preferably is cone containingit will go 2. At, in particular preferably alkyl silylene, alkyl [...] and is [...].

Type (B) 18a, 18b transition represented by. based on below, and by e.g..

^* 1:R⁵ and a R¹¹ is combined the 5-membered ring is formed on.

Me: methyl; Et: ethyl ; Ph: phenyl

^* 2:R³ and R¹², and R⁶ and R¹⁵ membered ring 5 is provided to be easily assembled and each is formed on.

Me: methyl; Ph: phenyl

Me: methyl

Furthermore, in the present invention said zirconium compounds for an intermingled transitional substituted titanium or hafnium may be loaded with using metallic compound.

Conventional metallic compound said transition minute body olefin polymerizing catalyst, but used in the form of an, in the form of body S or body R may be loaded with.

is and the induction body which is burnt ligand transition 18a, 18b according to conventional organic synthesis, for example represented reaction route can be compound solution to prepare a mixture solution.

Said reaction in formula, A, B, each C is halogen.

metallic compound metal compound use in the present invention, for example, (corresponding EP485822) [...] 4-268307 such as from those described to, conventional according to publicly known method, these is and the induction body which is burnt can be synthesis from.

In the present invention one represented and transion metal compound employable sheetring a bridge represented by (C) (metallocene compound,) may be loaded with using.

In said type (C), M, R¹, R², R³, R⁴, R⁵ and a R⁶ the type (B) as equal to.

R³, R⁴, R⁵ and R⁶ during, R³ including 2 or more is alkyl is preferably in an, R³ and a R⁵, or R³ and a R⁶ more preferably, the is. These alkyl three class alkyl strangeness or thereof by their preferably, .may be substituted containing crossroad silicon or halogen atom. As containing and silicon halogen atom, said R¹ and R² in can be mentionned substituents.

R³, R⁴, R⁵ and R⁶ during, other than alkyl is preferably, the hydrogen each it is different.

1-20 hydrocarbons hydrogen one example of carbon atoms, methyl, ethyl, n-propyl, i-propyl, n-butyl, i-butyl, second-butyl, tert-butyl, neopentyl, cyclohexyl, [...] cycle, [...] , octyl, nonyl, dodecyl, eicosa chamber, norbornyl and adamantyl such as alkyl and an annular chain-like alkyl ; benzyl, phenylethyl, phenyl profile and can be mentionned the biting alkyl it will raise[...] such as. These the double bonds or preferably resistance in spite of its containing triple bond.

R³, R⁴, R⁵ and R⁶ selected from aromatic bonded together-input 2 other than annularitymulti annularity or only annularity. crystal face may be formed.

Examples of halogen atom said R¹ and R² as equal to.

X¹, X², Y and R⁷ the type (B) as equal to.

Type (C) (and transion metal compound employable) metallocene compound, represented by an example of the described hereinafter.

Rac-dimethyl silylene-bis (4, 7-dimethyl-1-indenyl) zirconium d claw id ,

Rac-dimethyl silylene-bis (2, 4, 7-trimethyl-1-indenyl) zirconium d claw id ,

Rac-dimethyl silylene-bis (2, 4, 6-trimethyl-1-indenyl) zirconium d claw id ,

Rac-dimethyl silylene-bis (2, 5, 6-trimethyl-1-indenyl) zirconium d claw id ,

Rac-dimethyl silylene-bis (2, 4, 5, 6-tetramethyl-1-indenyl) zirconium d claw id ,

Rac-dimethyl silylene-bis (2, 4, 5, 6, 7-pentamethyl-1-indenyl) zirconium d claw id ,

Rac-dimethyl silylene-bis (2-methyl-4-n-propyl-7-methyl-1-indenyl) zirconium d claw id ,

Rac-dimethyl silylene-bis (4-i-propyl-7-methyl-1-indenyl) zirconium d claw id ,

Rac-dimethyl silylene-bis (2-methyl-4-i-propyl-7-methyl-1-indenyl) zirconium d claw id ,

Rac-dimethyl silylene-bis (2-methyl-4-i-propyl-6-methyl-1-indenyl) zirconium d claw id ,

Rac-dimethyl silylene-bis (2-methyl-4-methyl-6-i-propyl-1-indenyl) zirconium d claw id ,

Rac-dimethyl silylene-bis (2-methyl-4-i-propyl-5-methyl-1-indenyl) zirconium d claw id ,

Rac-dimethyl silylene-bis (2-methyl -4, 6-di (i-propyl)-1-indenyl) zirconium d claw id ,

Rac-dimethyl silylene-bis (2-methyl -4, 6-di (i-propyl)-7-methyl-1-indenyl) zirconium d claw id ,

Rac-dimethyl silylene-bis (2-methyl-4-i-butyl-7-methyl-1-indenyl) zirconium d claw id ,

Rac-dimethyl silylene-bis (2-methyl-4-sec-butyl-7-methyl-1-indenyl) zirconium d claw id ,

Rac-dimethyl silylene-bis (2-methyl -4, 6-di (second-butyl)-1-indenyl) zirconium d claw id ,

Rac-dimethyl silylene-bis (2-methyl-4-tert-butyl-7-methyl-1-indenyl) zirconium d claw id ,

Rac-dimethyl silylene-bis (2-methyl-4- [...] cycle-7-methyl-1-indenyl) zirconium d claw id ,

Rac-dimethyl silylene-bis (2-methyl-4-benzyl-7-methyl-1-indenyl) zirconium d claw id ,

Rac-dimethyl silylene-bis (2-methyl-4-phenylethyl-7-methyl-1-indenyl) zirconium d claw id ,

Rac-dimethyl silylene-bis (2-methyl-4-phenyl dichloro methyl-7-methyl-1-indenyl) zirconium d claw id ,

Rac-dimethyl silylene-bis (2-methyl-4-chloromethyl-7-methyl-1-indenyl) zirconium d claw id ,

Rac-dimethyl silylene-bis (2-methyl-4-tree methyl thread reel methyl -7-methyl-1-indenyl) zirconium d claw id ,

Rac-dimethyl silylene-bis (2-methyl-4-process for the production of methyl-7-methyl-1-indenyl) zirconium d claw id ,

Rac- [...] -bis (2-methyl-4-i-propyl-7-methyl-1-indenyl) zirconium d claw id ,

Rac-di (i-propyl) silylene-bis (2-methyl-4-i-propyl-7-methyl-1-indenyl) zirconium d claw id ,

Rac-di (n-butyl) silylene-bis (2-methyl-4-i-propyl-7-methyl-1-indenyl) zirconium d claw id ,

Rac-di ([...] cycle) silylene-bis (2-methyl-4-i-propyl-7-methyl-1-indenyl) zirconium d claw id ,

Rac-methyl [...] -bis (2-methyl-4-i-propyl-7-methyl-1-indenyl) zirconium d claw id ,

Rac- [...] -bis (2-methyl-4-i-propyl-7-methyl-1-indenyl) zirconium d claw id ,

Rac- [...] -bis (2-methyl-4-di (i-propyl)-1-indenyl) zirconium d claw id ,

Rac-di (p-tolyl) silylene-bis (2-methyl-4-i-propyl-7-methyl-1-indenyl) zirconium d claw id ,

Rac-di (p-chlorophenyl) silylene-bis (2-methyl-4-i-propyl-7-methyl-1-indenyl) zirconium d claw id ,

Rac-dimethyl silylene-bis (2-methyl-4-i-propyl-7-methyl-1-indenyl) zirconium [...] ,

Rac-dimethyl silylene-bis (2-methyl-4-i-propyl-7-methyl-1-indenyl) zirconium dimethyl,

Rac-dimethyl silylene-bis (2-methyl-4-i-propyl-7-methyl-1-indenyl) zirconium methyl chloride,

Rac-dimethyl silylene-bis (2-methyl-4-i-propyl-7-methyl-1-indenyl) zirconium-bis (methane opinion gun four toe),

Rac-dimethyl silylene-bis (2-methyl-4-i-propyl-7-methyl-1-indenyl) zirconium-bis (raffinate bisulphate-phenyl p is lengthwisely),

Rac-dimethyl silylene-bis (2-methyl-3-methyl-4-i-propyl-6-methyl-1-indenyl) zirconium d claw id ,

Rac-dimethyl silylene-bis (2-ethyl-4-i-propyl-6-methyl-1-indenyl) zirconium d claw id , and

Rac-dimethyl silylene-bis (2-phenyl-4-i-propyl-6-methyl-1-indenyl) zirconium d claw id.

Said compounds for zirconium transition be imparted to the derivative by substituting titanium metal or half [...]metallic compound , use can be made of, in addition.

Said transition metal compound is typically but form to a racemate, S or body R can be coating the parabolic antenna with chromium form.

Transition said e.g. ligand metallic compound indene derivatives through a reaction route according to of a general organic synthesis method can be so that the synthesised particles.

Type (C) represented by (metallocene compound,) and transion metal compound employable example [...] the prior 4-268307 said by publicly known method can be synthesis from indene derivative.

In the present invention one represented and transion metal compound employable assistance a bridge represented by (D) (metallocene compound,), use can be made of, in addition also.

Type (D) during, M, R¹, X¹, X² and Y the type (B) or (C) as equal to.

R¹hydrogen giga preferably hydrocarbons, more preferably methyl, ethyl, 1 ∼ 4 carbons such as butyl profile and is hydrocarbon group of can.

X¹ and a X² each 1 ∼ 20 carbon atoms or halogen atom preferably hydrogen giga hydrocarbons.

R² has carbon atoms, as 6 ∼ 16 aryl, e.g. phenyl, α-naphthyl, β-naphthyl, do not sprout three Neel , [...] , carbonil respirator, [...] , is ([...] ferrimagnetic) or asian[...][...]. Preferably sends a response to the or phenyl is selected from them. Said membered is R¹ such as, halogen atom, hydrocarbon group of 1 ∼ 20 carbon atoms or carbon atoms of 1 ∼ 20. may be the dispersibility by halogenated hydrocarbons.

Type (D) (metallocene compound) represented by examples of and transion metal compound employable to equal.

Rac-dimethyl silylene-bis (4-phenyl-1-indenyl) zirconium d claw id ,

Rac-dimethyl silylene-bis (2-methyl-4-phenyl-1-indenyl) zirconium d claw id ,

Rac-dimethyl silylene-bis (2-methyl-4-(α-naphthyl)-1-indenyl) zirconium d claw id ,

Rac-dimethyl silylene-bis (2-methyl-4-(β-naphthyl)-1-indenyl) zirconium d claw id ,

Rac-dimethyl silylene-bis (2-methyl-4-(1- do not sprout three Neel)-1-indenyl) zirconium d claw id ,

Rac-dimethyl silylene-bis (2-methyl-4-(2- do not sprout three Neel)-1-indenyl) zirconium d claw id ,

Rac-dimethyl silylene-bis (2-methyl-4-(9- do not sprout three Neel)-1-indenyl) zirconium d claw id ,

Rac-dimethyl silylene-bis (2-methyl-4-(9- [...])-1-indenyl) zirconium d claw id ,

Rac-dimethyl silylene-bis (2-methyl-4-(p-fluorophenyl)-1-indenyl) zirconium d claw id ,

Rac-dimethyl silylene-bis (2-methyl-4-(pentafluorophenyl)-1-indenyl) zirconium d claw id ,

Rac-dimethyl silylene-bis (2-methyl-4-(p-chlorophenyl)-1-indenyl) zirconium d claw id ,

Rac-dimethyl silylene-bis (2-methyl-4-(m-chlorophenyl)-1-indenyl) zirconium d claw id ,

Rac-dimethyl silylene-bis (2-methyl-4-(o-chlorophenyl)-1-indenyl) zirconium d claw id ,

Rac-dimethyl silylene-bis (2-methyl-4-(o, p-dichlorophenyl) phenyl-1-indenyl) zirconium d claw id ,

Rac-dimethyl silylene-bis (2-methyl-4-(p-bromo phenyl)-1-indenyl) zirconium d claw id ,

Rac-dimethyl silylene-bis (2-methyl-4-(p-tolyl)-1-indenyl) zirconium d claw id ,

Rac-dimethyl silylene-bis (2-methyl-4-(m-tolyl)-1-indenyl) zirconium d claw id ,

Rac-dimethyl silylene-bis (2-methyl-4-(o-tolyl)-1-indenyl) zirconium d claw id ,

Rac-dimethyl silylene-bis (2-methyl-4-(o, o '-dimethyl-phenyl)-1-indenyl) zirconium d claw id ,

Rac-dimethyl silylene-bis (2-methyl-4-(p-ethyl phenyl)-1-indenyl) zirconium d claw id ,

Rac-dimethyl silylene-bis (2-methyl-4-(p-i-epoxypropyl-phenyl)-1-indenyl) zirconium d claw id ,

Rac-dimethyl silylene-bis (2-methyl-4-(p-benzyl phenyl)-1-indenyl) zirconium d claw id ,

Rac-dimethyl silylene-bis (2-methyl-4-(p-biphenyl)-1-indenyl) zirconium d claw id ,

Rac-dimethyl silylene-bis (2-methyl-4-(m-biphenyl)-1-indenyl) zirconium d claw id ,

Rac-dimethyl silylene-bis (2-methyl-4-( methyl thread reel phenyl -p)-1-indenyl) zirconium d claw id ,

Rac-dimethyl silylene-bis (2-methyl-4-(m- methyl thread reel phenyl)-1-indenyl) zirconium d claw id ,

Rac-dimethyl silylene-bis (2-ethyl-4-phenyl-1-indenyl) zirconium d claw id ,

Rac- [...] -bis (2-ethyl-4-phenyl-1-indenyl) zirconium d claw id ,

Rac-dimethyl silylene-bis (2-phenyl-4-phenyl-1-indenyl) zirconium d claw id ,

Rac-dimethyl silylene-bis (2-n-propyl-4-phenyl-1-indenyl) zirconium d claw id ,

Rac- [...] -bis (2-methyl-4-phenyl-1-indenyl) zirconium d claw id ,

Rac-di-(i-propyl) silylene-bis (2-methyl-4-phenyl-1-indenyl) zirconium d claw id ,

Rac-di-(n-butyl) silylene-bis (2-methyl-4-phenyl-1-indenyl) zirconium d claw id ,

Rac- [...] -bis (2-methyl-4-phenyl-1-indenyl) zirconium d claw id ,

Rac-methyl [...] -bis (2-methyl-4-phenyl-1-indenyl) zirconium d claw id ,

Rac- [...] -bis (2-methyl-4-phenyl-1-indenyl) zirconium d claw id ,

Rac-di (p-tolyl) silylene-bis (2-methyl-4-phenyl-1-indenyl) zirconium d claw id ,

Rac-di (p-chlorophenyl) silylene-bis (2-methyl-4-phenyl-1-indenyl) zirconium d claw id ,

Rac-methylene-bis (2-methyl-4-phenyl-1-indenyl) zirconium d claw id ,

Rac-ethylene-bis (2-methyl-4-phenyl-1-indenyl) zirconium d claw id ,

Rac-dimethyl [...] -bis (2-methyl-4-phenyl-1-indenyl) zirconium d claw id ,

Rac-dimethyl [...] -bis (2-methyl-4-phenyl-1-indenyl) zirconium d claw id ,

Rac-dimethyl silylene-bis (2-methyl-4-phenyl-1-indenyl) zirconium [...] ,

Rac-dimethyl silylene-bis (2-methyl-4-phenyl-1-indenyl) zirconium dimethyl,

Rac-dimethyl silylene-bis (2-methyl-4-phenyl-1-indenyl) zirconium methyl chloride,

Rac-dimethyl silylene-bis (2-methyl-4-phenyl-1-indenyl) zirconium chloride SO₂ Me, and

Rac-dimethyl silylene-bis (2-methyl-4-phenyl-1-indenyl) zirconium chloride OSO₂ Me.

Said compounds, zirconium transition be imparted to the derivative by substituting titanium metal or half [...]metallic compound , use can be made of, in the present invention.

Type (D) the transition metal compound represented by "Journal of organometallic Chem.", 288 (1985), pp.63-67 patent 0,320,762 and Europe (specification and in the embodiment) based on the, method of the doped region is to be formed..

Reaction in formula, Z chlorine, bromine, iodine or o is-tosylate,

H₂ R^a the

A common and transion metal compound employable but form to a racemate (D), S or body R, use can be made of, in the form of.

In the present invention, one represented (3) for compounds represented by general metallocene compound, in addition, use can be made of, as (b).

L¹ M² Z¹₂ (3)

Formula M² family of 4 of the periodic table which has which gas having a lanthanide-based alloy containing a copper metal;

L¹ a non-localization the metal derivatives coupler-π M² limited to active site that imparts geometry;

Z¹ which each same or different from the, and R3 and R4 are each H, halogen, 20 hereinafter carbon atoms, silicon atoms or hydrocarbon group having it rolls up the bud atom germanosilicided, is pushing, germanosilicided or silyl group.

Type (3) in (b) metallocene compound, formula (4) preferred are those compounds represented by.

Type (4) during, M³ the titanium, zirconium or hafnium; Z¹ equal to the weight, and is economical;

The Cp η⁵-fitting manner in one of at M³ to to crow pen hit D Neel with-binding π, which its derivatives or it is cheap to this crow pen hit D Neel substituted;

W¹ oxygen, sulfur, boron, or element periodic table group 14 containing group won water exhibits any oligomer;

V¹ nitrogen, in, which graphitic coordination of a sulfur-containing, or oxygen;

W¹ and V¹. crystal face may be formed condensed ring together. In addition Cp and a W¹ crystal face may be formed condensed ring together.

Type (4) represented by Cp in a preferred example of to crow pen hit D Neel cycle, indenyl, is of flue [...] and their saturated derivatives. Atoms having photocatalytic function comprise metal atoms derivatives and these (M³) form a ring together with a.

car Bill properties carbon atoms in to crow pen hit D Neel cycle, 1 one or more hydrogen atoms in car Bill substituted substituted halogen atoms, metal with id 14 periodic table group selected from hydrocarbyl-substituted and highly with id metal selected from the group are the same or different substituted or unsubstituted may be.. In addition 2 one or more substituted. crystal face may be formed condensed ring cooperate. Cycle 1 containing one hydrogen atom at least in to crow pen hit D Neel instead substituted hydrocarbyl and substituted hydrocarbyl during and 1 ∼ 20 carbon atoms preferably, alkyl branch linear and in addition, annular hydrocarbon group, alkyl substituted annular hydrocarbon group, substituted aromatic alkyl aromatic groups and includes strips. A preferred organic with metal idcar Bill hydrogel examples 1 ∼ 20 carbon atoms each and, an element of group 14 periodic table mono-, tri-substituted organic with metal id is d and. A preferred organic with metal id a specific example trimethylsilyl, triethylsilyl, ethyl byte FONT register, methyl d ethyl thread reel , phenyl byte FONT register, methyl d phenyl thread reel , phenyl thread reel tree, tree can be mentionned [...] and [...].

Type (4) during Z¹ represented by examples of lead hydrate, halogen, alkyl, silyl, germanosilicided mill, aryl, amide, aryloxy, alkoxy, pos it will be noted that we have, also sulfinyl, acyl, pseudo halide (e.g.: cyanide, azido), sulfinato alkylacetoacetoates acetyl can be mentionned mixture thereof with a lock brake system. Z¹ each are represented by same or different from the preferably.

As metallocene compound, (b), type (3) polymerization to form the metallocene compound represented by transparency of molded body activity and, strength, heat resistance, and impact resistance is preferably class and an area. Said metallocene compound (b) as such or combined alone may be the..

In the present invention the (b) metallocene compound using hydrocarbon prior to use dilution hydrogen by halogenated hydrocarbons or. may be.

Then metallocene (a) for forming an organic aluminum oxyhydroxide-compounds (c) and ionization ionic compounds which are. also disclosed to (d).

Use in the present invention an organic aluminum oxyhydroxide-compounds (c) an aluminoxane or a of the publicly known [...] 2-78687 call (USP 4990640 corresponding, EP 360492B) benzene is illustrated insoluble organic aluminum oxyhydroxide preferably even-compounds.

Aluminoxane of the following method, for instance, which produced at, conventional is recovery in the shape of a solution hydrocarbon solvent.

(1) an organoaluminum compound such trialkyl can for adsorbing containing compound or decisions are salts which contain (e.g.: magnesium chloride hydrate, copper sulfate hydrate, aluminum sulfate hydrate, nickel sulfate hydrate or chloride hydrate cesium number 1) aromatic hydrocarbon solvent added to suspension can adsorption an organoaluminum compound reacting water determined or, aromatic hydrocarbon solvent as the solution then retrieves the an aluminoxane.

(2) water, ice, water vapor benzene, toluene, ethyl ether or tetrahydrofuran mixable such trialkyl medium directly an organoaluminum compound such translations and during, as solvent solution aromatic hydrocarbon system can then retrieves the an aluminoxane.

(3) dimethyl tin oxide or dibutyl tin oxide such as a tin oxide decane, benzene or toluene such trialkyl in hydrocarbon media reacting an organoaluminum compound such..

Ionization oxalate-based ionic compound (d) examples of Lewis acid, oxalate-based ionic compound, borane compound and: borane compound. These ionization ionic compounds which are 502036/1989 and patent application disclosure 501950/1989 International, call and 3-207703 [...] call 3-179005 [...][...] 3-207704 call, and USP 5,321,106 disclosed is call or the like.

Ionization oxalate-based ionic compound (d) a Lewis acid can be used as examples of type BR₃ is a fullerene derivative is denoted by chemical (wherein R each same or which differ from each other in, fluorine, methyl or trifluoromethyl such as preferred that is phenyl or fluorine atom randomly choosing may be). Magnetron roboblock trifluoride examples of such compounds, triphenylboron, tris (4-fluorophenyl) boron, tris (3, 5-difluorophenyl) boron, tris (4-fluoromethyl phenyl) boron and tris (pentafluorophenyl) boron :.

Ionization oxalate-based ionic compound (d), which can be used as an ionization ion compound is made up of and the anion cation compound is salts. (B) metallocene compound the anionic compound is water-said react with a cationic (b) compounds forming the ion pair on, . provides a stabilized transition metal cation species (seed). Examples of anion such organic boron compound anion, organoaluminum compound anions, and organic arsenicals as to the aromatic hydrocarbon anion. Anion relatively remarkably bulky, transition metal cationic species which is stable over a it is preferable that the. Examples of cationic said metal cations, organic metal cations, cationic hafnium carbonate, cationic [...] tropinone, oxo hafnium cationic, sulfonium cationic, phosphonium cation and ammonium cationic as to the aromatic hydrocarbon. Cationic [...] tree more specifically, tree butyl ammonium cationic, N, N-dimethyl ammonium cationic, Perot [...] : cationic.

Among them, anionic compounds containing boron compound as preferred are those compounds which the alloy has a matrix that, examples include trialkyl substituted ammonium salt, N, [...] -N, can be mentionned [...] and d alkyl ammonium salt.

ALPO said trialkyl substituted examples tri-ethyl ammonium tetra (phenyl) boron, tree profile ammonium tetra (phenyl) boron, tree (n-butyl) ammonium tetra (phenyl) boron and trimethylamine ammonium tetra (p-tolyl) boron as to the aromatic hydrocarbon.

Said N, [...] -N N examples, [...] -dimethyl N a notifies a user (phenyl).

Examples d alkyl ammonium salt said di (n-propyl) ammonium tetra (pentafluorophenyl) boron and [...] as to the aromatic hydrocarbon (phenyl) boron.

[...] comprise trialkylamines e.g. [...] said triazine (phenyl) boron, tree (methyl phenyl) (phenyl) boron and pos [...] pos [...] (dimethyl-phenyl) (phenyl) boron can be mentionned lamp.

[...] as ionic compounds which are in addition (pentafluorophenyl) borate, N, (pentafluorophenyl) borate and multi maul -N [...][...] (pentafluorophenyl) borate, use can be made of, lamp.

Said ionization oxalate-based ionic compound (d), which can be used as an examples of borane compound

Decaborane (14);

Bis [tree (n-butyl) ammonium] [...] and bis [tree (n-butyl) ammonium] [...] such salt anion;

Tree (n-butyl) ammonium bis (use of Saccharomyces cerevisiae [...]) [...] (III) and bis [tree (n-butyl) ammonium] bis (use of Saccharomyces cerevisiae [...]) nickel rate (III) of metals, such as borane anion salt.

Said ionization oxalate-based ionic compound (d), which can be used as an examples of borane compound knife

4- it plays but step column cover (14) and 1, 3-dicarboxylic it plays but step column (13) such as anionic salt;

Tree (n-butyl) ammonium bis ([...][...] -1, 3-dicarboxylic) [...] (III) and (n-butyl) ammonium bis (-7, 8-dicarboxylic [...][...]) [...] light (III) of metals, such as knife borane anion salts, and so forth can be mentionned.

Ionic compounds which are patterned to said hump combination on the paper 2 alone (d), use can be made of,.

(A) in the present invention a metalocene catalysed using the necessary in addition to component (e) organic aluminum compound a further may contain..

As needed (e) which is used as an organic aluminum compound after that, for instance, (5) is represented by organoaluminum compound.

(R⁶)_n AlX_3-n (5)

(Wherein R⁶ carbon atoms 1 ∼ 15, preferably carbon atoms 1 ∼ 4 of PAG, X represent halogen or hydrogen atom, n is the 1 ∼ 3.)

1 ∼ 15 carbon atoms hydrogen for example alkyl hydrocarbons. Chroman cycle alkyl or aryl group. Examples of such methyl, ethyl, n-propyl, isopropyl and notifies a user this cow department[...].

Examples of organoaluminum compound:

Trimethyl aluminum, aluminum, tree isopropyl aluminum, tri-n-butyl aluminum, tree isobutyl aluminum, tri-sec-butyl such as aluminum trialkyl aluminium;

Isocyanate type such [...] (i-C₄ H₉)_X Al_y (C₅ H₁₀)_Z alkenylaluminum represented by

(Wherein x, y, z and each stove, z≥ 2x randomly choosing);

Molecular weight distribution, an MFR diisobutyl aluminum chloride such as d alkyl aluminum halide;

Diisobutylene such as of different grown epitaxial d alkyl aluminum hydride;

Dimethyl aluminum methoxide such as d alkyl aluminum alkoxide;

d ethyl aluminumlung stipendiary sided alkyl aluminum such as to the aromatic hydrocarbon biting oxide.

Ethylene, aromatic vinyl compound necessary carbon atoms of 3 ∼ 20 α-olefin of formula and continuous batch mispairing of preferably thin spot and void, despite in which method. Where a continuously copolymerization said, said metallocene used as the concentration has an (a).

The concentration of (b) metallocene compound situtype polymerization polymerization, conventional (duty elastomer applications) 0.00005 ∼ 1.0 mmol/L, preferably in the range of from 0.0001 ∼ 0.5mmol/L.

The (c) organic aluminum oxyhydroxide-compounds, (b) metallocene compound in-polymerization in metal transition in the organic aluminium oxy compound in non aluminum atom (Al/transition metal) is 0.1 ∼ 10,000, preferably is used in quantities ranging from 1 ∼ 5,000.

Ionization ionic compounds which are the (d), (b) metallocene compound in polymerization ion ions molar ratio of (d) compound (ionization oxalate-based ionic compound (d)/ metallocene compound (b)) is 1.0 ∼ 20, preferably is used in quantities ranging from 1 ∼ 10.

The (e) said organoaluminum compound, organoaluminum compound (e) typically concentration of 0 ∼ 5mmol/L (duty elastomer applications), preferably about. are used in a quantity of 0 ∼ 2mmol/L range.

Ethylene/aromatic vinyl compound random said for the preparation of a copolymer a public reaction temperature -30 ∼ 250 °C, preferably 0 ∼ 200 °C, conventional pressure 0 ∼ 80kg/cm² (gauge pressure), preferably 0 ∼ 50kg/cm² (gauge pressure), the portable telephone sends under conditions of.

Such as a temperature and the like and the polymeric catalyst concentration, the reaction times are of to accomplish different but according to the reaction condition, said reaction time (average residence time when the sum public continuous) conventional time ∼ 3 ingredient 5, preferably is time ∼ 1.5 ingredient 10.

Ethylene/aromatic vinyl compound in for the production of random copolymers, ethylene, aromatic vinyl compound and optionally said α-olefins of 3 ∼ 20 carbon atoms a particular composition copolymers, an amount can be obtained is supplied to aperture polymerization. In public said, such as hydrogen can be by using molecular weight controlling agent.

Ethylene, aromatic vinyl compound of 3 ∼ 20 carbon atoms and optionally said lower copolymerized such as α-olefins, α-olefin/aromatic vinyl compound random copolymer typically as polymer solutions containing the same are obtained. Of the existing method method the polymerization to form the solution, ethylene/aromatic vinyl compound random copolymer obtain.

In the present invention, α-olefin/aromatic vinyl random copolymer grafted monomer (the is signal from the "graft monomer") is the unsaturated carboxylic acid or derivatives. Said unsaturated carboxylic examples acrylic acid, methacrylic acid, maleic, fumaric acid and can be mentionned the cone it buys lighter. Unsaturated carboxylic derivatives examples of unsaturated carboxylic anhydride, ester, amide, polyimide and a metal salt can be mentionned. These examples of maleic anhydride, itaconic anhydride, methyl acrylate, methyl methacrylate, ethyl acrylate, ethyl methacrylate, butyl acrylate, butyl methacrylate, [...] , prepare the, monomethyl maleate, [...] , monomethyl fumarate, dimethyl fumarate, mono [...] , [...] , acrylamide, methacrylamide, maleic mono amide, maleic diamide, maleic N-ethyl amide, maleic N, d ethyl amide -N, maleic N-monobutyl amide, maleic N, d butyl amide -N, fumaric acid mono amide, fumaric acid diamide, fumaric acid N-ethyl amide, fumaric acid N, d ethyl amide -N, fumaric acid N-monobutyl amide, fumaric acid N, d butyl amide -N, sodium acrylate, sodium methacrylate, potassium acrylate and potassium methacrylate, and the like :. Grafted monomer contains in, preferably using of the maleic anhydride.

Α-olefin/aromatic vinyl compound random copolymer and other graft monomer inputted, retrieves/displays graft copolymerized, various publicly known method, use can be made of,. E.g. α-olefin/aromatic vinyl compound random copolymer and other under the solvent of or absence of the water-soluble Xylan graft monomer, radical initiator or, in the alternative, with graft copolymerization is heated at a high temperature without, the portable telephone sends. In graft copolymerized, styrene another payload such as vinyl monomers is preferably even when the within total.

Graft amount (graft ratio) 0.01 ∼ 30 weight % having a part or wholly grafted modified α-olefin/aromatic vinyl random for the preparation of a copolymer to, having grafted high initially a graft modified α-olefin/aromatic vinyl random for the preparation of a copolymer and is subsequently graft modified α-olefin/aromatic vinyl random copolymer non-denatured α-olefin/aromatic vinyl compound random copolymer by adding a method of manipulating the rate of graft is industrial production is used preferably in terms of. The amount graft wherein copolymers grafted respect to 100g. ratio of monomer copolymerized graft copolymers. For example, copolymers grafted monomer copolymerized grafted to the 1g 100g when an acceleration force is present, graft the amount defined by the 1 weight %. According to method is, concentration of monomer graft in the formula preferably can be appropriately adjusted. Is copolymers prepared by method "some graft modified α-olefin/aromatic vinyl compound random copolymer" represented by a. Initially course predetermined amount of graft monomer α-olefin/aromatic vinyl compound random copolymer added to preferably conducted graft copolymerized. The production cost is cheap copolymer method is "wholly grafted modified α-olefin/aromatic vinyl compound random copolymer" as a display.

The adhesive resin composition of the present invention in addition to modified copolymer said ethylene / α-olefin copolymer and/or ethylene/vinyl acetate copolymer particles may further include..

Ethylene / α-olefin copolymer as the addition of modified copolymer, oxide layer and an amorphous silicon melting point adhesive resin composition of the present invention is can be having improved formability is, in addition can be is [...] in retort container. In addition for the polyolefin is the composition can be.

Ethylene/vinyl acetate copolymer modified copolymer or modified copolymer and ethylene / α-olefin copolymer as the addition of, oxide layer and an amorphous silicon melting point adhesive resin composition of the present invention is can be having improved formability is, [...] in retort container in addition can be having improved adhesion.

In view hereof, entire adhesive resin compositions, of the present invention graft monomers are graft monomer graft amount (weight ratio) is 0.01 ∼ 30 weight %, in particular 0.05 ∼ 10 weight % range an amount α-olefin/aromatic vinyl random copolymer is grafted to the preferably. Graft wherein the amount to 100g entire adhesive resin composition exhibits graft monomer in weight.

Ethylene / α-olefin copolymer

The present invention ethylene / α-olefin copolymer may comprise ethylene and α-olefins in addition 45 ∼ 95mol % content of ethylene is economical to manufacture, durable in sum, preferably α-olefm polymer that has a 45 ∼ 90mol % α.-olefin copolymer.

Ethylene / α-olefin copolymer melt flow rate (ASTM D 1238, conditions: E) 0.1 ∼ 50g/10 ingredient conventional, preferably 0.3 ∼ 30 g/10 ingredient, 0.850 ∼ 0.900 g/cm3 typically density, preferably 0.850 ∼ 0.890 g/cm3, and crystallinity (X ray diffraction crossroad measuring) 30% hereinafter a common, preferably has a 25% hereinafter.

Ethylene / α-olefin copolymer forming α-olefin for using α-olefin is of 3 ∼ 20 carbon atoms, their examples propylene, 1-butene, 1-hexene, 4-methyl-1-pentene, 1-octene, 1-hexadecene, 1-octadecene tetra can be mentionned it counted octahydro 1-and. Is α-olefin alone or. are used in combination with on the paper 2.

Ethylene / α-olefin copolymer typically has melting point (ASTM D3418) 100 °C hereinafter.

Ethylene/vinyl acetate copolymer

The present invention ethylene/vinyl acetate copolymer a vinyl acetate content 5 ∼ 40 weight %, preferably has 10 ∼ 35 weight %. In addition of polyol component is ethylene/vinyl acetate copolymer a melt flow rate (ASTM D 1238, conditions: E) 0.1 ∼ 50g/10 ingredient conventional, preferably 0.3 ∼ 30 g/10 75/25 to 35.

The adhesive resin composition of the present invention graft modified α-olefin/aromatic vinyl compound random copolymer, ethylene / α-olefin copolymer and ethylene/vinyl acetate copolymer in addition ethylene polymer, propylene polymer, water modified of these polymers, thickener lamp. particles may further include.

Ethylene polymer

Ethylene the present invention are either a homopolymer of ethylene polymer 90 ∼ 100 mol % content of ethylene or, preferably 95 ∼ 100 mol % α-olefm polymer that has a and a minor amount of this α-with is copolymer.

Ethylene polymer a melt flow rate (ASTM D 1238, conditions: E) 0.1 ∼ 50g/10 ingredient conventional, preferably 0.3 ∼ 30 g/10 ingredient, and density 0.900 ∼ 0.980 g/cm3 typically, has preferably 0.920 ∼ 0.970 g/cm3.

Ethylene polymer formation for using α-olefin carbon atoms of 3 ∼ 20 α-olefin is, their examples propylene, 1-butene, 1-hexene, 4-methyl-1-pentene, 1-octene, 1-hexadecene, 1-octadecene tetra can be mentionned it counted octahydro 1-and. Is α-olefin alone or on the paper 2 can utilize combinations of.

Ethylene polymer modified with unsaturated carboxylic acid or derivatives. may be. Examples of unsaturated carboxylic acid and its derivative equal to said weight, and is economical. In order to produce the modified ethylene polymer, various publicly known method, use can be made of,.

Ethylene polymer-adhesive when added to resin composition, the composition can be is.

Propylene polymer

Propylene propylene polymer for use in the present invention are either a homopolymer of 55 ∼ 100 mol % content of propylene or, preferably 80 ∼ 100 mol % polypropylene and having is copolymer with-α.

Propylene polymer a melt flow rate (ASTM D 1238, conditions: E) 0.1 ∼ 50g/10 ingredient conventional, preferably 0.3 ∼ 30 g/10 ingredient, melting and conventional (Tm) 110 ∼ 165 °C, preferably has 120 ∼ 165 °C.

Propylene polymer formation for using 4 ∼ 20 α-olefin carbon atoms of α-olefin is, their examples 1-butene, 1-hexene, 4-methyl-1-pentene, 1-octene, 1-hexadecene, 1-octadecene tetra can be mentionned it counted octahydro 1-and. Is polyolefin is a-α, alone or in combination on the paper 2, use can be made of,.

Propylene polymer modified with unsaturated carboxylic acid or derivatives. may be. Examples of unsaturated carboxylic acid and its derivative equal to said weight, and is economical. In order to produce the modified propylene polymer, various publicly known method, use can be made of,.

Propylene polymer is when added to the adhesive resin composition, the composition can be is.

Thickener

The addition of composition adhesive resin thickener melt viscosity the composition high temperature to the lane width or adjusting the adhering characteristics and improves wet tensile properties. Is preferably used is reduced in the excessive fluidity in thickener hydrogenation cycloaliphatic examples, rosin, modified rosin, is rosin ester, aliphatic petroleum resins, cycloaliphatic petroleum resins, aromatic petroleum resins, copolymer plant and aromatic components, petroleum resins, low molecular weight polystyrene resin, isoprene resin, an alkylphenol resin, can be mentionned is and the resin which is burnt -coumarin and pen resin. Reestablishment of is, alone or in combination at least one 2, use can be made of,.

Mixing ratio

As the main components as the present invention adhesion-resin composition graft modified α-olefin/aromatic vinyl co-polymers containing union , graft modified α-olefin/aromatic vinyl compound random copolymer 1 ∼ 100 parts by weight, preferably 1 ∼ 80 parts by weight, more preferably 10 ∼ 80 parts by weight and ductility polymer 0 ∼ 99 parts by weight, preferably 20 ∼ 99 parts by weight, more preferably 20 ∼ 90 is constituted of parts by weight (stage modified copolymer and ductility and a polymer the mol, in total of acetone recognition unit recognizes weight 100).

Flexible polymer encrypts the information for example, the, ethylene / α-olefin copolymer, ethylene/vinyl acetate copolymer or mixtures thereof is.

Adhesive resin composition of the present invention preferred aspects modified copolymer 10 ∼ 80 parts by weight and ethylene / α-olefin copolymer and/or ethylene/vinyl acetate copolymer 20 ∼ 90 parts by weight (stage a copolymer thereof, in total of acetone recognition unit recognizes weight the 100) and good air tightness by maintaining the composition.

A specific example of the composition:

Modified copolymer 10 ∼ 80 parts by weight, preferably 30 ∼ 80 parts by weight, and ethylene / α-olefin copolymer 20 ∼ 90 parts by weight, preferably 20 ∼ 70 parts by weight (stage a copolymer thereof, in total of acetone recognition unit recognizes weight the 100) and good air tightness by maintaining the composition;

Modified copolymer 10 ∼ 80 parts by weight, preferably 30 ∼ 80 parts by weight, and ethylene/vinyl acetate copolymer 20 ∼ 90 parts by weight, preferably 20 ∼ 70 parts by weight (stage a copolymer thereof, in total of acetone recognition unit recognizes weight the 100) and good air tightness by maintaining the composition;

Modified copolymer 10 ∼ 80 parts by weight, preferably 30 ∼ 80 parts by weight, and ethylene / α-olefin copolymer 5 ∼ 60 parts by weight, preferably 10 ∼ 50 parts by weight, and ethylene/vinyl acetate copolymer 5 ∼ 40 parts by weight, preferably 10 ∼ 30 parts by weight (stage a copolymer thereof, in total of acetone recognition unit recognizes weight the 100) and good air tightness by maintaining the can be mentionned composition.

Modified copolymer, ethylene / α-olefin copolymer and ethylene/vinyl acetate copolymer in addition to ethylene polymer, propylene polymer, water modified of these polymers, thickener lamp. may be added to the composition composition adhesive resin of the present invention.

Ethylene polymer or modified method using the composition, when, the amount of modified or ethylene polymer modified copolymer, ethylene / α-olefin copolymer and ethylene/vinyl acetate copolymer 100 mol, in total of the parts by weight, 0.1 ∼ 50 parts by weight, preferably ranging from 1 ∼ 30 parts by weight.

Propylene polymer or modified method using the composition, when, the amount of modified or propylene polymer modified copolymer, ethylene / α-olefin copolymer and ethylene/vinyl acetate copolymer 100 mol, in total of the parts by weight, 0.1 ∼ 50 parts by weight, preferably ranging from 1 ∼ 30 parts by weight.

The event of the use of thickener, thickeners the amount modified copolymer, ethylene / α-olefin copolymer and ethylene/vinyl acetate copolymer 100 mol, in total of the parts by weight, 0.5 ∼ 25 parts by weight, preferably ranging from 5 ∼ 15 parts by weight.

As said, the adhesive resin composition of the present invention major component the graft modified α-olefin/aromatic vinyl which random copolymer in which the, entire the adhesive resin composition conventional graft amount (ratio) 0.01 ∼ 30 weight % preferably 0.05 ∼ 10 weight %, the MFR 0.2 ∼ 40 g/10 ingredient 0.1 ∼ 50 g/10 ingredient preferably, crystallization degree has 35% hereinafter.

The adhesive resin composition of the present invention graft modified α-olefin/aromatic vinyl compound random copolymer loads LPG and has at least, or ethylene / α-olefin copolymer and/or ethylene/vinyl acetate copolymer further includes. The composition various publicly known method, e.g. said [...] component, V type blender, ribbon blender, such as are mixed with a dumbbell type blender, the mixture is shortened extruder, / S09/Markov to a min, 0.12, semi kneading melted charge such as mixer gate of the memory cell, the same has an or granulating [...] doped region is to be formed. method.

Adhesive resin composition of the present invention, of an acrylonitrile-butadiene-styrene, weather stabilizer, pigment, dye and internal sacrifice another payload such as various purpose of the invention the present additives in within such a range that causes no damage to the can add.

Polyester resin the adhesive resin composition of the present invention, polycarbonate resin, of a saponified olefin/vinyl acetate copolymer and for the polyolefin has insulating. Hence the composition for use as adhesive agent between these resins can be to achieve a good utilization of the. Said adhesive resin composition polycarbonate or polyester layer a layer of a saponified ethylene/vinyl recovering order junction the total layer when used, an excellent gas stack generating X-hopper coating, and a impermeable, the hot fill or applied the Colloidic [...] in retort container does not occur.

Next described a and a layered product by the present invention.

The laminate of the present invention (I) polyester resin layer or polycarbonate resin layer, and an adhesive layer which is made of resin composition adhesive (II) said a saponified olefin/vinyl acetate copolymer (III) 151 are composed.

(I) layer laminate extensibility and by the present invention a polyester resin or polycarbonate resin selected from two 1 is a layer formed of resins.

Dihydroxy polyester resins derived from dihydroxy compound units and having an at and dicarboxylic acid derived from dicarboxylic acids is composed is polyester. Dihydroxy compounds ethylene glycol, propylene glycol, 1, 4-butanediol, ethylene glycol, and hexamethylenediamine Neo [...] aliphatic glycol; glycol cycloaliphatic such [...] cycle; id rock hour harmony water under D strain of an aromatic bisphenol; they selects from a mixture of. Dicarboxylic the luck thread it buys terephthalic acid, isophthalic acid and a 2, 6-naphthalene pyridinedicarboxylic strain of an aromatic dicarboxylic acid; oxalic, succinic, adipic acid, sebacic acid and the fortune car D car luck thread it buys aliphatic dicarboxylic acid such as; hexahydro terephthalic acid such as cycloaliphatic dicarboxylic acid; they selects from a mixture of. Indicating thermoplastic is a modified polyester resin within such a range that, on guiding 3 such as carboxylic acid or triol polyhydric hydroxy compound or multivalent carboxylic acid in a minor amount. may be modified. Thermoplastic polyester examples polyethylene terephthalate, polybutylene terephthalate and polyethylene isophthalate/terephthalate copolymer can be mentionned.

Poly [...][...] or phosgene compound dihydroxy resin is produced polycarbonate and is [...].

Hydroquinone examples id rock hour harmony scandal under D , hardness, 4, 4 '- id rock hour D phenyl methane under D , 4, 4' - id rock hour D phenyl ethane under D , 4, 4 '- id rock hour D phenyl under D -n-butane, 4, 4' - [...] , 4, 4 '- id rock hour D phenyl phenyl methane under D , 4, 4' - id rock hour D phenyl under D -2, 2-propane (bisphenol A), 4, 4 '-dihydroxy -3, 3' , -dimethyl diphenyl -2, 2-propane, 4, 4 '-dihydroxy -3, 3' - d phenyl D phenyl -2, 2-propane, 4, 4 '- with id rock hour D claw under D D phenyl -2, 2-propane, 4, 4' - id rock hour D phenyl under Dcrow pentane cycle -1, 1-, 4, 4 '- id rock hour D phenyl under D hexane chroman cycle -1, 1-, 4, 4' - id rock hour D phenyl methyl phenyl methane under D , 4, 4 '- id rock hour D phenyl ethyl phenyl methane under D , 4, 4' - id rock hour D phenyl under D -2, 2, 2-trichloro -1, 1-ethane, 2, 2 '- id rock hour D phenyl under D , 2, 6-dihydroxynaphthalene, 4, 4' - id rock hour D phenyl ether under D , 4, 4 '-dihydroxy -3, 3' -dichloro d phenyl ether and 4, 4'-dihydroxy -2, 5-can be mentionned [...]. Is selected from them, 4, 4'- id rock hour D phenyl under D -2, 2-propane (bisphenol A) is preferably, the made by using the same polycarbonate is good mechanical properties. over and transparency.

Adhesive layer laminate extensibility and by the present invention (II) to form a, .are to use a liquid adhesive resin said of the present invention.

By the present invention (III) layer laminate extensibility and the a layer of a saponified olefin/vinyl acetate copolymer formed from. layer. Wherein a saponified olefin/vinyl acetate copolymer using 15 ∼ 60 mol % olefin content and that the copolymer has a, preferably 25 ∼ 50 mol % having olefin/vinyl acetate copolymer which a layer of a saponified film fabricated thereby to reduce a layer of a saponified copolymer, sword degree film has at least 90% preferably 50% or more. Olefin content is said range, a layer of a saponified copolymer and from substantially of pinholes, which has good moldability and, excellent stretchable, has water resistance and gas my permeability. sword degree a length different from each 50%, an excellent gas copolymer thereof has my permeability.

Examples of olefin a chemical side group is copolymerized with vinyl acetate, include ethylene, propylene, 1-butene, 1-hexene, 4-methyl-1-pentene, 1-octene, 1-hexadecene, 1-octadecene tetra can be mentionned it counted octahydro 1-and. Is selected from them, ethylene mechanical strength and preferably in terms of.

Polyester resin laminate of the present invention or polycarbonate resin, adhesive resin composition and a layer of a saponified olefin/vinyl acetate copolymer separating squeezer (separate extruder) and so the density and, same supply die layer structure 3, adhesive resin composition layer is this interlayer adjacent their root to co-extruding method % by weight to produce the title (pneumatic the method which it will dance), or preferentially polyester resin or a saponified olefin/vinyl acetate copolymer and [...] formed 150, has the features of method for melt extruded composition adhesive resin satisfying a full (sandwich laminate method) can be produced by.

Is selected from them, preferably pneumatic in strength ingrredient the method which it will dance. Using die plate the method which it will dance pneumatic T-method using die and circular is inflation method. As die plate, each black box using realizes and only quarter style , use can be made of, any water exhibits. The inflation method, publicly known dies, use can be made of, any water exhibits.

A thickness of each layer laminated body and decides the appropriately thereby in use. , And a stacked body is film or sheet therefrom when used as, polyester unit has a sliding unit (I) or a polyvinylidene fluoride about 0.02 ∼ 5 millimeter [...] (I), (II) adhesive layer about 0.01 ∼ 1 millimeter, a layer of a saponified ethylene/vinyl acetate copolymer (III) having a thickness of about 0.01 ∼ 1 millimeter it is preferred that a.

Each outside a layer laminate of the present invention (I) is formed in a laminate with fluoropolymer film (e.g. : (I) / (II) / (III) / (II) / (I)), or polyol [...] further provides in a laminate (e.g.: poly propylene layer / (II) / (III) / (II) / (I) or polyethylene layer / (II) / (III) / (II) / (I)) .may be ear.

Effect of the invention

The adhesive resin composition of the present invention ., an excellent thermal resistance and adhesion. Hence the composition [...] polyester unit has a sliding unit (I) or a polyvinylidene fluoride (I) and a layer of a saponified olefin/vinyl acetate copolymer (III) for splicing for use as adhesive agent when the mother pipe having a, (I) and layer is capable of strongly bonding the (III) layer, layer (I) the (III) layer and the hot fill or in retort container even conditions temperature, high [...] can be preventing Colloidic. Is actually used in addition speckles and is at higher temperatures and are pleasing to the adhesive strength can be retained even room temperature.

Layer (I), layer (II) and (III) layer consisting of an oxygen laminate of the present invention such represents the of low permeability, gas [...] in retort container. materials the hot fill or packaging.

The present invention to. specifically, to embodiment. The present invention however this embodiment to exemplify limited not.

In in the embodiment a, crystallinity and density which is marked as a chemical method was are determined by averaging the.

Sample manufacturing

Composition 10 in 180 °C to hot press is heated minutes, then cooling press (for water) to and rapidly cooling the sample have been prepared.

Crystallinity

An optical output peak of the in said X-ray diffraction crossroad it was determined that crystallization degree.

Density

In said 23 °C density in an optical output peak of the save by azimuth measurement density gradient tube.

Manufacturing 1

For the production of random copolymers of ethylene/styrene

Agitators in the cooling pipe and attached 1 is purged with the second nitrogen reaction apparatus glass liters, toluene was is charged into the 35 milliliter and styrene 645 milliliter. Then ethylene with stirring, in a saturated solution is supplied to an engine, for baked pancakes. 35 °C temperature of-based then at elevated temperatures and, methyl 2001 (Tosoh Aquzo K. K. Number, 10 weight % toluene solution) 4.5 mmol, (t-butyl amide) dimethyl (tetramethyl-η⁵- to crow pen hit D Neel cycle) thread column titanium D claw id (0.01 mmol toluene solution) 0.045 mmol has added. Ethylene with then successively time rate liters per -100 N the surface plate while supplying the in 40 °C was polymerizing 60 minutes. Polymerization and after that, isobutyl alcohol 250 milliliter 10 milliliter and hydrochloric 80 °C the mixture is added in 30 minutes stirring section. Isobutyl alcohol containing a reaction solution are separation with the atmosphere which it will peel 250 milliliter water transferred with oil stratum aqueous solution and, after washing the burn to place them into separated the layer. 3 methanol in oil stratum then using an isotropic polymer by adding liters visitor is checked through a. 130 °C in a polymer 12 time vacuum drying of ethylene/styrene random copolymer (to is displayed in "ESC1") a obtained. In ESC1 obtained, which the molar ratio of ethylene to styrene (ethylene/styrene) the 90/10 power is fed, the 135 °C decalines among ESC1 extreme viscosity is measured was 2.1 dl/g.

ESC1 of grafted

1 is purged with the second nitrogen pot pressurized glass liters, was 190 milliliter and ESC1 30 g is charged into the toluene. While agitating the mixture is 140 °C adaptation at elevated temperatures. Relation to the other container to, maleic anhydride 40 milliliter is toluene 6.9g d queue wheat ladling oxide and 5.3g dissolved in the solution have been produced. The solution into an 3.5, over a period of time at a constant speed after the addition is dripped in pot pressurized, pressurized mixture type cauldron 30 minutes stirring section. Dripping during added, until 160 °C temperature situtype polymerization, was gradually temperatures. After reaction, was cooled to 70 °C based temperature of. Then 1 methanol reactive solution using an isotropic polymer by adding liters visitor is checked through a. A polymer in which washes the acetone 1 L in terms of the vacuum drying time 12 130 °C ESC1 of grafted-modified water (to is displayed in "MAH-ESC1") is obtained. In MAH-ESC1 obtained, of the maleic anhydride graft amount (graft ratio) was the 2.2 weight %. The 135 °C decalines among MAH-ESC1 extreme viscosity is measured was 2.0 dl/g.

Manufacturing 2

For the production of random copolymers of ethylene/styrene

Random copolymer of ethylene/styrene (to "ESC2" together with audience rating) a (t-butyl amide) dimethyl (tetramethyl-η⁵- to crow pen hit D Neel cycle) thread column titanium D claw id[...] by instead (indenyl) zirconium dichloride manufacturing except used in the range of 1 obtained by the same method. In ESC2 obtained, which the molar ratio of ethylene to styrene (ethylene/styrene) the 88/12 power is fed, the 135 °C decalines among ESC2 extreme viscosity is measured was 1.8 dl/g.

ESC2 of grafted

Graft degeneration instead ESC1 copolymers produced in said (ESC2) a graft-denaturalized using water (to is displayed in "MAH-ESC2") gives 1 manufacturing except for the host supplying the same method was carried out. In MAH-ESC2 obtained, of the maleic anhydride graft amount (graft ratio) was the 2.0 weight %. The 135 °C decalines among MAH-ESC2 extreme viscosity is measured was 1.8 dl/g.

In the embodiment 1

Manufacturing 1 alcohol to the glycolide monomer at MAH-ESC1, polycarbonate (brand names: Teijin Panlite L-1250, Teijin Kasei K. K. Number, by to come to "PC"), a layer of a saponified ethylene/vinyl acetate copolymer (MFR: 1.3 g/10 ingredient, density: 1.19 g/cm3, weight of EPDM having an ethylene content: 32 mol %, brand names; Kuraray Eval EP-F, Kuraray Co. , Ltd number, by outputting the to "EVOH") and polyethylene (brand names: Ultozex 2021L, Mitsui Chemicals, Inc. , Number, to "PE" together with audience rating) Y = under conditions been produced with at layer sheet 5.

Structure of sheet: PE/ESC1-EVOH/MAH/ESC1 PC/MAH-

Thickness of each layer (micro m): 80/50/50/50/80

Extruder:

To extrudate having 40 millimeter diameter, 280 °C (for PC)

Extrudate having to 30 millimeter diameter, 250 °C (for MAH-ESC1)

Extrudate having to 30 millimeter diameter, 210 °C (for EVOH)

To extrudate having 40 millimeter diameter, 230 °C (for PE)

5 layer sheet obtained at the T-peel, and a position thereof is PC layer burglar MAH-ESC1 layer and between inner products of (FPC, g/15 millimeter) and EVOH layer and between MAH-ESC1 layer burglar inner products of a temperature (FEVOH, g/15 millimeter) 80 °C or 23 °C, shedding rates it was determined that under conditions/min. 300 millimeter. In addition its seat a 131 °C in the invention also provides for a processing [...] in retort container 30 minutes. Then said T-peel test was performed in equal conditions. Described to result to the computer of the table 1.

Furthermore, MAH-ESC1, EVOH, polyethylene terephthalate (Mitsui pet K. K number J35 crystallisation promoter by adding obtaining, by outputting the to "Peru Time") and under conditions for using PE been produced with at layer sheet 5.

Structure of sheet: PE/ESC1-EVOH/MAH/MAH-ESC1/Peru Time

Thickness of each layer (micro m): 80/50/50/50/80

Extruder:

To extrudate having 40 millimeter diameter, 280 °C (for Peru Time)

Extrudate having to 30 millimeter diameter, 250 °C (for MAH-ESC1)

Extrudate having to 30 millimeter diameter, 210 °C (for EVOH)

To extrudate having 40 millimeter diameter, 230 °C (for PE)

Obtained at the 5 layer sheet between MAH-ESC1 layer and Peru Time of inner products of (EPFT, g/15 millimeter) and EVOH layer and layer burglar MAH-ESC1 layer burglar (FEVOH, g/15 millimeter) between inner products of a equal to said save under conditions. Described to result to the computer of the table 2.

In the embodiment 2

Instead MAH-ESC1, MAH-ESC1 40 parts by weight and ethylene/1-butene random copolymer (MFR: 3.6 g/10 ingredient, density: 0.89 g/cm3, weight of EPDM having an ethylene content: 85 mol %, crystallinity: 15%, to "EBR" together with audience rating) 60 parts by weight of mixture except used in the range of 5 layer sheet in the same method in the embodiment 1 have been prepared. Then equal to 5 layer sheet T-peel test in the embodiment 1, which table 1 and table 2 to described.

In the embodiment 3

Instead MAH-ESC1, MAH-ESC1 70 parts by weight and ethylene/vinyl acetate copolymer (MFR: 2.5 g/10 ingredient, vinyl acetate content: 25 mol %, to "EVA" together with audience rating) 30 parts by weight of mixture except used in the range of 5 layer sheet in the same method in the embodiment 1 have been prepared. Then equal to 5 layer sheet T-peel test in the embodiment 1, which table 1 and table 2 to described.

In the embodiment 4

Instead MAH-ESC1, MAH-ESC1 35 parts by weight, and EBR 45 mixture parts by weight of EVA 20 except used in the range of 5 layer sheet in the same method in the embodiment 1 have been prepared. Then equal to 5 layer sheet T-peel test in the embodiment 1, which table 1 and table 2 to described.

In the embodiment 5

Instead MAH-ESC1, MAH-ESC1 60 parts by weight, and EBR 15 EVA 20 parts by weight of mixture (i.e. composition 100 weight starting point MAH-ESC1 63.2 parts by weight, and EBR 15.8 EVA 21.0 parts by weight) in the embodiment 1 except for the host using the method in the same 5 been produced with at layer sheet. Then equal to 5 layer sheet T-peel test in the embodiment 1, which table described to 1.

In the embodiment 6

Manufacturing MAH-ESC1 instead produced in a 1, 2 alcohol to the glycolide monomer at MAH-ESC2 manufacturing paste using the same method in the embodiment 1 except for 5 in been produced with at layer sheet. Then equal to 5 layer sheet T-peel test in the embodiment 1, which table 1 and table 2 to described.

Compared example 1

Instead MAH-ESC1, polypropylene (MFR: 12 g/10 ingredient, density: 0.91 g/cm3) maleic anhydride 5 parts by weight of a graft-denaturalized the grafted polypropylene (to "MAH-PP" to come by) in the embodiment 1 except for the host using the method in the same 5 been produced with at layer sheet. Then equal to 5 layer sheet T-peel test in the embodiment 1, which table described to 1.

Compared example 2

Instead MAH-ESC1, polyethylene (MFR (190 °C): 2 g/10 ingredient, density: 0.92 g/cm3, butene content: 4 mol %) maleic anhydride 5 parts by weight of a graft-denaturalized obtained a second method, the expansion is grafted (to "MAH-PE" to come by) in the embodiment 1 except for the host using the method in the same 5 been produced with at layer sheet. Then equal to 5 layer sheet in the embodiment 1 and the resulting T-peel for testing for described to 1 in a table

Compared example 3

Instead MAH-ESC1, ethylene/styrene/1-polybutene copolymer (brand names: Crayton G 1652, Shell, Co. , Number, by outputting the to "SEBS") 5 parts by weight maleic anhydride a obtained a graft-denaturalized copolymers grafted (to "MAH-SEBS" to come by) in the embodiment 1 except for the host using the method in the same 5 been produced with at layer sheet. Then equal to 5 layer sheet T-peel test in the embodiment 1, which table described to 1.