신규한 유기발광 화합물 및 이를 포함하는 유기 발광 소자
The present invention refers to novel organic light-emitting device including organic light-emitting device relates to search for compound and, more particularly, low-voltage drive and efficiency characteristics of a fluorescent host when used as adjuvants for use in electroluminescent devices including an electron transporting organic compound and are disclosed. (Organic light emitting diode, OLED) using a magnetic layer of a mixed organic light emitting surface of the light transmissive, thin large viewing angle as compared to a liquid crystal display, can be reflected and, fast response time have a steering wheel pull - color (full-a color) display or a lighting applications to expected disclosed. The means by which electrical energy using organic material generally organic light emitting phenomenon to light installed on the pipe body. Organic light emitting phenomena between an anode and a cathode and a solvent including conventional organic light emitting devices has a meshed structure. The organic compound layer is formed of organic light-emitting material in order to enhance stability and different multilayered structure of which is in many cases, e.g. hole injection layer, hole transport layer, light emitting layer, metal-containing fullerene, or similar with an can be. Such an organic light-emitting device structure a voltage between two electrodes on the liquid crystal in the solution with holes, and the process is organic electronics is cathode, electrons are injected and when meeting the OLEDs (exciton) is formed, is equal to 1000 ppm when a light again falls into the ground state. Such an organic light emitting device is a self-luminous, high brightness, high efficiency, low driving voltage, wider viewing angles, high contrast, high response in the presence of having known. Packed in materials used in the organic light emitting layer to other persons, light-emitting material and a charge transporting material, such as a hole injection material, hole transporting material, an electron transport material, electron injection in order to remove can be classification. Said material comprises molecular weight-classification according to polymer type and molecular weight can be, light emitting mechanism of the former along singlet [...] fluorescent material and derived from electron triplet [...] derived from phosphorescent material can be classification. On the other hand, when only one substance as a luminescent material, an intermolecular interaction by isolating means is moved in the long wavelength emission wavelength can fall out of the maximum thickness of the light emitting electric door number is reduced to comparison, increased safety device through one or more energy transitions in order to increase the host as a luminescent material for a luminescent dopant system - can. Energy band gap and pressure are formed in the light emitting layer host than small dopant small mixing, transported to a high efficiency light generated in a light emitting layer dopant into at 1000 ppm are disclosed. The, wavelength of dopant wavelength moves as host, depending on the type of dopant using a desired light in a wavelength can be achieved. This luminous layer host compounds as prior art Patent Registration Notification number 10 - 1092006 call (2011. 12. 09) To both ends of the anthracene structure including an electron transporting light emitting [...] alcohol substituent phenyl combined with techniques described and, Public Patent Notification number 10 - 2006 - 0113954 call (2006. 11. 03) Mixture of blue light emission in response to light emitting [...] including asymmetric techniques disclosed. However, said conventional technique for use light emitting layer formed on the various class of compounds number becoming trillion, cladding wafer level package and stable despite the driving light emitting layer material having the need for development of organic light emitting devices are provided which continuously being requested. Patent Registration Notification number 10 - 1092006 call (2011. 12. 09) Public Patent Notification number 10 - 2006 - 0113954 call (2006. 11. 03) Thus, the present invention accomplish the first technical and number is of organic light-emitting light emitting layer can be used, low voltage driving and efficiency characteristics of a compound number [...] organic light-emitting device are disclosed. The present invention is organic light emitting compound including said second number is technical and accomplish [...] number are disclosed. The present invention refers to said first techniques in order to achieve a specific number, or organic light-emitting compound represented by [formula B] to [formula A] number [...] substrate. [Formula A] [Formula B] In said [formula A] and [formula B], A1, A2, and mutually the same or different from each E and F hereinafter, a substituted or unsubstituted aromatic hydrocarbon of 6 to 50 carbon atoms independently of each other a ring, or a substituted or unsubstituted aromatic heterocyclic and C12 2 to 40; Said A1 and two adjacent carbon atoms in an aromatic ring, an aromatic ring in said A2 in the R1 and R2 substituents connected to said two adjacent carbon atoms by forming each fused ring to form an annular carbon atoms and 5; Each said connector L1 to L4 and to the insulating layer hereinafter, are each independently a single bond, a substituted or unsubstituted 1 to 60 C12 alkylene, C12 justice neel the [khey which it will know [leyn 2 to 60 substituted or unsubstituted, a substituted or unsubstituted alkynyl in range of 2 to 60 C12, C12 claw alkyl [leyn justice at the time of a substituted or unsubstituted 3 to 60, 60 to a substituted or unsubstituted heterocyclic inhibitors of C12 2 hour claw alkyl [leyn, 6 to 60 it will be biting, [leyn of C12 substituted or unsubstituted or a substituted or unsubstituted heterocyclic inhibitors of C12 it will be biting, [leyn 2 to 60 in selected; the M N a-R3 , CR4 R5 , SiR6 R7 , GeR8 R9 , O, S, Se selected among resistant; Said substituent R1 To R9 , Each identical to one another and to Ar4 Ar1 or different hereinafter, are each independently a hydrogen, deuterium, a substituted or unsubstituted alkyl 1 to 30 C12, C12 50 6 to a substituted or unsubstituted aryl, a substituted or unsubstituted 2 to 30 between the light-emitting of C12, C12 to a substituted or unsubstituted alkynyl of 2 to 20, a substituted or unsubstituted cycloalkyl group of 3 to 30 C12, 5 to 30 between the light-emitting C12 substituted or unsubstituted cycloalkyl, substituted or unsubstituted heteroaryl group of C12 2 to 50, 2 to 30 C12 heterocyclic inhibitors of a substituted or unsubstituted cycloalkyl, substituted or unsubstituted alkoxy group 1 to 30 C12, C12 [...] 6 to 30 of a substituted or unsubstituted, a substituted or unsubstituted alkyl [...] C12 1 to 30, 5 to 30 carbon atoms substituted [...][...] of substituted or unsubstituted, 1 to 30 hydroxybutyrolactone C12 substituted or unsubstituted alkyl, a substituted or unsubstituted 5 to 30 [...] of C12, C12 1 to 30 substituted or unsubstituted alkyl silyl group, a substituted or unsubstituted 5 to 30 [...] of C12, C12 1 30 germanium to a substituted or unsubstituted alkyl, a substituted or unsubstituted 1 to 30 C12 germanium it will be biting of cyano group, nitro, catalyst in a halogen is selected from, Said R1 and R2 are each connected alicyclic, aromatic polycyclic forms a ring can be a single ring aromatic compound, formed said alicyclic, aromatic single ring aromatic polycyclic ring carbon atoms N, O, P, Si, S, Ge, Se, Te can be substitutionally replaced one or more heteroatoms selected from among; 1 To 3 is an integer to each said s1 s4, each connector L1 to L4 are each the same or more 2 these each and or different hereinafter, Said x is integer number of 1 or 2, and the same or different from each y and z hereinafter, positive numbers of 0 to 3 independently of each other, In adjacent two carbon atoms of said ring in said formula A formula Q1 * A2 by being coupled fused ring is formed, Said A1 in adjacent two carbon atoms of said ring in said formula B formula Q2 * by being coupled fused ring is formed, said A2 in adjacent two carbon atoms of said ring structure Q1 * form fused ring by being coupled; Said 'a' in 'substituted or unsubstituted substituted' is deuterium, cyano group, a halogen, hydroxy, nitro, alkyl of 1 to 24 carbon atoms, 1 to 24 carbon atoms halogenated alkyl, of 1 to 24 carbon atoms between the light-emitting, for 1 to 24 carbon atoms of alkynyl, hetero alkyl of 1 to 24 carbon atoms, 6 to 24 carbon atoms aryl, aryl-alkyl of 6 to 24 carbon atoms, aryl group or heterocyclic inhibitors of 2 to 24 carbon atoms 2 to 24 carbon atoms a variety of aryl-alkyl, alkoxy of 1 to 24 carbon atoms, 1 to 24 carbon atoms of alkyl-amino group, 1 to 24 carbon atoms of amino it will be biting, a variety of 1 to 24 carbon atoms amino it will be biting, 1 to 24 carbon atoms alkyl silyl group, of 1 to 24 carbon atoms [...], with biting jade time of 1 to 24 carbon atoms selected from the group consisting of at least one substituted 1 which means that the other. In addition the present invention refers to said second and in order to achieve a number, number 1 electrode; said number 1 number 2 electrode opposed to the electrode; and said number 1 and said number 2 electrode interposed between the organic layers, said organic layer including at least one organic compound 1 of the present invention, organic light emitting number [...] substrate. According to the present invention, hydrophilic organic solvent represented by [formula A] existing relative to wafer level package and has a excellent luminous efficiency, excellent stable number of the bath can be used. Figure 1 shows a schematic diagram of the organic light emitting device according to embodiments of the present invention also one are disclosed. Hereinafter, the present invention more detailed as follows. In each drawing of the present invention, structures of the present invention can be higher than the size of dimension is reduced by reducing the thread number or the virtualization of clarity and shown, feature configuration to define exposed to publicly known configurations not shown drawing since dispensed without substrate. Principles of the present invention preferred embodiment is connected to the publicly known for detailed description is the subject matter of invention specifically related function or configuration can be described if breach of haze decided to omit other. In addition, wherein the arbitrarily for facilitating description size and thickness of each configuration exhibited drawing representing, not limited to the present invention are not necessarily shown and, in addition drawing where the different layers in order by increasing a thickness and area unambiguously shown. In the drawing, for facilitating descriptions to, the thickness of several layers and the region shown exaggerated. Layer, film, region, such as when that plate parts which are "on", "directly on" as well as any other portion when intermediate when another portion comprises a unit. In addition, the entire specification, that "comprising" when any portion of any components, particularly the opposite substrate [...] number but without other components further can include other components which means that the other. In addition, the entire specification, "- on" means in which a multi-located above or below the object portion, positioned on the upper side with reference to the direction necessarily gravity epoxygenated fatty acids are not correct. The present invention refers to novel aromatic organic light emitting compound, compound [formula A] or [formula B] for a number [...] substrate. [Formula A] [Formula B] In said [formula A] and [formula B], A1, A2, and mutually the same or different from each E and F hereinafter, a substituted or unsubstituted aromatic hydrocarbon of 6 to 50 carbon atoms independently of each other a ring, or a substituted or unsubstituted aromatic heterocyclic and C12 2 to 40; Said A1 and two adjacent carbon atoms in an aromatic ring, an aromatic ring in said A2 in the R1 and R2 substituents connected to said two adjacent carbon atoms by forming each fused ring to form an annular carbon atoms and 5; Each said connector L1 to L4 and to the insulating layer hereinafter, are each independently a single bond, a substituted or unsubstituted 1 to 60 C12 alkylene, C12 justice neel the [khey which it will know [leyn 2 to 60 substituted or unsubstituted, a substituted or unsubstituted alkynyl in range of 2 to 60 C12, C12 claw alkyl [leyn justice at the time of a substituted or unsubstituted 3 to 60, 60 to a substituted or unsubstituted heterocyclic inhibitors of C12 2 hour claw alkyl [leyn, 6 to 60 it will be biting, [leyn of C12 substituted or unsubstituted or a substituted or unsubstituted heterocyclic inhibitors of C12 it will be biting, [leyn 2 to 60 in selected; the M N a-R3 , CR4 R5 , SiR6 R7 , GeR8 R9 , O, S, Se selected among resistant; Said substituent R1 To R9 , Each identical to one another and to Ar4 Ar1 or different hereinafter, are each independently a hydrogen, deuterium, a substituted or unsubstituted alkyl 1 to 30 C12, C12 50 6 to a substituted or unsubstituted aryl, a substituted or unsubstituted 2 to 30 between the light-emitting of C12, C12 to a substituted or unsubstituted alkynyl of 2 to 20, a substituted or unsubstituted cycloalkyl group of 3 to 30 C12, 5 to 30 between the light-emitting C12 substituted or unsubstituted cycloalkyl, substituted or unsubstituted heteroaryl group of C12 2 to 50, 2 to 30 C12 heterocyclic inhibitors of a substituted or unsubstituted cycloalkyl, substituted or unsubstituted alkoxy group 1 to 30 C12, C12 [...] 6 to 30 of a substituted or unsubstituted, a substituted or unsubstituted alkyl [...] C12 1 to 30, 5 to 30 carbon atoms substituted [...][...] of substituted or unsubstituted, 1 to 30 hydroxybutyrolactone C12 substituted or unsubstituted alkyl, a substituted or unsubstituted 5 to 30 [...] of C12, C12 1 to 30 substituted or unsubstituted alkyl silyl group, a substituted or unsubstituted 5 to 30 [...] of C12, C12 1 30 germanium to a substituted or unsubstituted alkyl, a substituted or unsubstituted 1 to 30 C12 germanium it will be biting of cyano group, nitro, catalyst in a halogen is selected from, Said R1 and R2 are each connected alicyclic, aromatic polycyclic forms a ring can be a single ring aromatic compound, formed said alicyclic, aromatic single ring aromatic polycyclic ring carbon atoms N, O, P, Si, S, Ge, Se, Te can be substitutionally replaced one or more heteroatoms selected from among; 1 To 3 is an integer to each said s1 s4, each connector L1 to L4 are each the same or more 2 these each and or different hereinafter, Said x is integer number of 1 or 2, and the same or different from each y and z hereinafter, positive numbers of 0 to 3 independently of each other, In adjacent two carbon atoms of said ring in said formula A formula Q1 * A2 by being coupled fused ring is formed, Said A1 in adjacent two carbon atoms of said ring in said formula B formula Q2 * by being coupled fused ring is formed, said A2 in adjacent two carbon atoms of said ring structure Q1 * form fused ring by being coupled; Said 'a' in 'substituted or unsubstituted substituted' is deuterium, cyano group, a halogen, hydroxy, nitro, alkyl of 1 to 24 carbon atoms, 1 to 24 carbon atoms halogenated alkyl, of 1 to 24 carbon atoms between the light-emitting, for 1 to 24 carbon atoms of alkynyl, hetero alkyl of 1 to 24 carbon atoms, 6 to 24 carbon atoms aryl, aryl-alkyl of 6 to 24 carbon atoms, aryl group or heterocyclic inhibitors of 2 to 24 carbon atoms 2 to 24 carbon atoms a variety of aryl-alkyl, alkoxy of 1 to 24 carbon atoms, 1 to 24 carbon atoms of alkyl-amino group, 1 to 24 carbon atoms of amino it will be biting, a variety of 1 to 24 carbon atoms amino it will be biting, 1 to 24 carbon atoms alkyl silyl group, of 1 to 24 carbon atoms [...], with biting jade time of 1 to 24 carbon atoms selected from the group consisting of at least one substituted 1 which means that the other. In addition, said "a substituted or unsubstituted alkyl C12 1 to 24", "6 to 24 C12 substituted or unsubstituted aryl" [...] range disposed on the side of the alkyl or, said 1 to 24 carbon atoms of 6 to 24 carbon atoms and alkyl carbon number range said substituent is substituted [...] each portion without any regard for a substituted or unsubstituted alkyl or aryl portion when portion which the arrangement meaning that the carbon number are disclosed. For example, butyl substituted carbon atoms substituted at the para-position of the phenyl carbon atoms to a corresponding aryl phosphate of butyl 4 6 must substrate. Aryl substituted compounds of the present invention used in number one hydrogen by volatile organic radicals derived from aromatic hydrocarbons due, when said trianthracene (fused) to an adjacent substituents which are fuse-substituent can be further formed. Specific examples [...] said phenyl, non-phenyl o -, m - non-phenyl, p - non-phenyl, [...] o -, m - [...], p - [...], me [phu, inside [thu reel, lung difficulty [thu reel, blood [ley neel, indenyl, five [ley neel and process for preparation thereof, draw or [phu 2, [leyn one vinyl, cryo imidazole, imidazole naphtha, aromatic group such as cited five column [theyn one process for preparation thereof, said one or more hydrogen atom of the aryl group deuterium atoms, halogen atom, hydroxy, nitro, cyano group, silyl group, amino group (- NH2 , - NH (R), - N (R ') (R "), R' and R" 1 to 10 carbon atoms and alkyl independently of each other, in this case a multi-"alkyl-amino group"), [...] amino, hydrazine to, [...], carboxyl group, a sulfonic acid group, phosphoric acid, alkyl of 1 to 24 carbon atoms, 1 to 24 carbon atoms halogenated alkyl, of 1 to 24 carbon atoms between the light-emitting, for 1 to 24 carbon atoms of alkynyl, hetero alkyl of 1 to 24 carbon atoms, 6 to 24 carbon atoms aryl, aryl-alkyl of 6 to 24 carbon atoms, aryl group or heterocyclic inhibitors of 2 to 24 carbon atoms can be substituted heterocyclic inhibitors of 2 to 24 carbon atoms [...]. N hetero aryl substituted compounds of the present invention use due, O, 1, 2 or 3 hetero atoms selected from of P or S, the remaining ring atoms being aromatic ring of 2 to 24 carbon may be used C12 means system, said fused rings (fused) to an can be formed. And said one or more hydrogen atoms substituted heteroaryl group when said [...] similar to pivotably. Specific examples used in the present invention due alkyl substituted methyl, ethyl, propyl, isobutyl, sec - butyl, tert - butyl, neopentyl, iso - amyl, hexyl or the like cited, when said at least one of said substituted alkyl hydrogen atoms atoms [...] similar to pivotably. Specific examples of the present invention compound used in due alkoxy substituted methoxy, ethoxy, propoxy, [...] [thil jade city, sec - butyl oxy, pen [thil jade city, iso - oh wheat jade city, such as ethylhexyloxy cited, said one or more hydrogen atoms substituted alkoxy when said [...] similar to pivotably. Specific examples of the present invention substituted compounds due thread reel using trimethylsilyl, tree [thil it will be recorded, phenyl thread reel tree, tree [...], the d maul [thok hour phenyl it will be recorded, the d phenyl methyl it will be recorded, silyl, the d phenyl vinyl it will be recorded, methyl the gap claw view [thil it will be recorded, such as the [phyu the reel it will be recorded dimethyl cited, wherein said one or more hydrogen atoms substituted [...] similar to when said pivotably. The compound of the present invention said formula A or formula B in said formula A, Q1 is connected to ring when said Ar2 including connector L2 is a formula A2 A2 has a structural features into engagement with the ring must, in addition formula B formula Q2 in A1 is connected to the ring, the ring including an Ar2 must frame including said A2 A2 formula Q1 is coupled to a ring connector L2 has structural characteristics. In said formula A or formula B A1, A2, and the same or different from each E and F hereinafter, a substituted or unsubstituted aromatic hydrocarbon of 6 to 50 carbon atoms independently of each other can be a ring. Such as said, in formula A or formula B A1, A2, and the same or different from each E and F hereinafter, independently of each other a substituted or unsubstituted aromatic hydrocarbon ring 6 to 50 C12 numbers, a substituted or unsubstituted aromatic hydrocarbon ring of 6 to 50 said C12 and hereinafter the same or different, [formula 10] to [formula 21] independently of each other can be selected from any one. [Formula 10] [formula 11] [formula 12] [Formula 13] [formula 14] [formula 15] [Formula 16] [formula 17] [formula 18] [Formula 20] [formula 21] [formula 19] [Formula 10] [formula 21] "- *" in said substituent R is said to1 And R2 Which is connected to a carbon including 5 formed to define a torus, or a binding site for forming said means including 5 in formula Q1 and Q2 and an annular M, Said [formula 10] to [formula 21] A1 A2 corresponding to formula Q1 or Q2 formula while ring or annulus is aromatic hydrocarbon ring is among these adjacent two carbon atoms bind to Q1 or Q2 ** of formula of formula said bind to form a condensed ring by being coupled; [Formula 10] said R1 and R2 is equal to said R defined in aforementioned to [formula 21], M is an integer 1 to 8 and, m is 2 or more R or R is 2 or more each be the same or different each other. In addition said formula A and formula B L1 to L4 in each single bond or linking group, in [formula 1] to [formula 8] below selected resistant, to 1 or 2 and each s1 s4, Wednesday 1 x is 2000. [Formula 1] [formula 2] [formula 3] [formula 4] [Formula 5] [formula 6] [formula 7] [formula 8] Said linking group can be an aromatic ring carbon seats is coupled in hydrogen or deuterium. In addition said Ar1 to Ar4 are hydrogen, deuterium, a substituted or unsubstituted alkyl 1 to 30 C12, C12 50 6 to a substituted or unsubstituted aryl, a substituted or unsubstituted cycloalkyl group of 3 to 30 C12, 2 to 50 of C12 substituted or unsubstituted heteroaryl group, a substituted or unsubstituted alkoxy group selected among 1 to 30 C12, [formula A] and [formula B] 1 and each of said x and y, and z Wednesday 0 is, in this case more specifically said Ar2 C12 6 to 50 is a substituted or unsubstituted aryl, or a substituted or unsubstituted heterocyclic inhibitors of C12 [...] be 2 to 50. In addition in the present invention said formula A or formula B said R1 and R2 substituents each independently of each other and in the same or different from the hereinafter, C12 [...] of 6 to 24 be substituted or unsubstituted. In this case R1 and R2 are each connected each substituent forms a ring thereof can not form ring are connected to each other or not. On the other hand, in the present invention compound of said formula A or formula B [formula 1] to [formula 138] to specific one example can be a the number represented by any one selected from the group consisting not. Formula 1 formula 2<><><>formula 3 Formula 5 formula 4<><><>formula 6 Formula 7<><><>formula 8 formula 9 Formula 10><<><>formula 12 formula 11 Formula 13><><formula 15><formula 14 Formula 16><><><formula 17 formula 18 Formula 19><><formula 21><formula 20 Formula 22><><formula 24><formula 23 Formula 25<><formula 26><>formula 27 Formula 28>><formula 30><<formula 29 Formula 31<><formula 32><>formula 33 Formula 35><><><formula 34 formula 36 Formula 37<><formula 38><>formula 39 Formula 41><>><<formula 40 formula 42 Formula 43<><><>formula 45 formula 44 Formula 47<><>formula 48><formula 46 Formula 49<><><formula 51>formula 50 Formula 54>><<><formula 52 formula 53 Formula 55<><><>formula 57 formula 56 Formula 58<><formula 59><>formula 60 Formula 61<><><formula 63>formula 62 Formula 64<><formula 65><>formula 66 Formula 67<><formula 68><>formula 69 Formula 70<><><formula 72>formula 71 Formula 73<><formula 74><>formula 75 Formula 76<><><formula 78>formula 77 Formula 79<><><formula 81>formula 80 Formula 82<><formula 83><>formula 84 Formula 85<><formula 86><>formula 87 Formula 88<><formula 89><>formula 90 Formula 91<><formula 92><>formula 93 Formula 94<><><>formula 96 formula 95 Formula 97<><formula 98><>formula 99 Formula 100><><formula 101<>formula 102 Formula 104><><formula 105><formula 103 Formula 106<><formula 107><>formula 108 Formula 110 formula 109<><><>formula 111 Formula 112<><><formula 114>formula 113 Formula 115<><formula 116><>formula 117 Formula 118<><><>formula 120 formula 119 Formula 121<><formula 122><>formula 123 Formula 124><<><>formula 125 formula 126 Formula 127<><formula 128><>formula 129 Formula 130<><formula 131><>formula 132 Formula 133<><><formula 135>formula 134 Formula 136<><formula 137><>formula 138 In addition, the present invention refers to number 1 electrode; said number 1 number 2 electrode opposed to the electrode; and said number 1 and said number 2 electrode interposed between organic layer; and, at least one of said organic layer including said compound 1 in the present invention, organic light emitting number [...] substrate. In the present invention "(organic layer) comprising at least one compound 1" implies, "(organic layer) of the present invention category belonging to 1 one compound or said compound comprising a compound of at least one different belonging to category 2 can be" can be interpreted as. The, said of the present invention compounds organic layer hole injection layer, hole transporting layer, a hole injection function and hole transport used as functional layer, light emitting layer, an electron transport layer, the metal layer and at least one can. In addition the present invention refers to said number 1 electrode interposed between the electrode and said number 2 formed at light emitting seed layer, in this case host luminescent layer made of said dopant, said formula A or formula B host compound can be used. In this case said light emitting layer dopant material using specific examples pyrene compound, deuterium substituted pyrene compound, arylamine, deuterium substituted arylamine, vinyl-based compound, deuterium substituted vinyl-based compound, pyrrole-based compound, deuterium substituted pyrrole-based compound, [...] compound, deuterium substituted [...] compound, cover neck of compounds, compounds of chrysanthemum cultivar deuterium substitution, steel [...] compound, deuterium substitution steel [...] compound, star bust orgin compounds, deuterium substitution star bust orgin compounds, oxadiazole-based compound, deuterium substituted oxadiazole-based compound, coumarin (coumarine), as to the deuterium substituted coumarin (coumarine) be, the present invention refers to the non-number one without substrate. When said light emitting layer is host and dopant, typically about 100 parts by weight of host the content of dopant from about 0. 01 To about 20 parts by weight of can be is selected from the range, limited to are not correct. In addition, in the present invention said hole injection layer, hole transport layer, a hole injection function and hole transport used as functional layer, light emitting layer, the deposition process with an alkali metal-containing fullerene and selected from at least one layer can be formed by processes or solution. Wherein said light is deposited on the material used for the material for forming the heated in vacuum or low pressure state thin film is formed by a method such as evaporation through components, said solvent solution for forming each layer of the material used for the same material is mixed with an inkjet printing, roll-to-roll coating, screen printing, spray coating, dip coating, thin film formation method such as spin coating method through means other. In addition in the present invention first and second of said flat panel display device; flexible display device; monochrome or white for plane light source device; and monochrome or white flexible for illumination device; selected from one device can be used. As of the present invention embodiments, an organic luminous layer between said hole (HTL, Hole Transport Layer) is additionally stacked on said anode, said cathode further an organic luminous layer between said metal-containing fullerene (ETL, Electron Transport Layer) can be stacked disclosed. Said low ionization potential materials include [...] hole electron-donating molecules be used, mainly triphenyl amine the basic framework of a diamine, triamine or tetra amine derivatives which are used, e.g., N, N'- bis (3 - methylphenyl) - N, N' - diphenyl - [1, 1 - biphenyl] - 4, 4 '- diamine (TPD) or N, N' - di (naphthalene - 1 - yl) - N, N' - d phenyl [peyn_ci (a non-NPD) can be use. The lower portion of the hole injection layer (HIL, Hole Injecting Layer) said [...] hole which additionally further deposit, said hole injection material art also typically used can be one in which the number not particularly using, e.g. a star burst type amines TCTA CuPc (copperphthalocyanine) (4, 4 ', 4 "- tri (N-a carbazolyl) triphenyl-a amine), m a-MTDATA (4, 4', 4" - tris - (3 provided methylphenylphenyl amino) triphenylamine) can be use. In addition, said metal-containing fullerene material include e.g. oxadiazole derivative PBD, BMD, Alq BND or3 Can be use. On the other hand, top is provided with a cathode from said electronic transporting bed that allow for improving power efficiency for electronic injection hereinafter ultimately further to be able to function with an (EIL, Electron Injecting Layer), said material also typically used in the art with an grudge without using the special number can be, e.g., LiF, NaCl, CsF, Li2 O, BaO using substance such as can be. Organic light emitting through broadcast receiver 1 also described hereinafter of the present invention. Figure 1 shows a cross-section indicating the structure of the organic light emitting device of the present invention also are disclosed. The present invention according to acts as an anode (20), hole (40), an organic luminous layer (50), alkali metal-containing fullerene (60) and a cathode (80) which, if necessary hole injection (30) and with an (70) can be further comprises, and 1 or 2 more than that of the intermediate layer in addition also be disclosed. The organic light emitting diode manufacturing method of the present invention with reference to the residual also 1 as follows. First substrate (10) for upper located one or more anode (20) and form. Wherein the substrate (10) is provided for use in conventional organic EL substrate of which transparency, surface smoothness, handling water-resistant organic substrate or transparent plastic substrate preferably selectively. And, indium tin oxide (ITO) anode electrode for title search using a polymer electrolyte clear, zinc indium oxide (IZO), tin oxide (SnO2 ), Zinc oxide (ZnO) etc.. Said anode (20) electrode hole injection layer material to vacuum thermal deposition, or spin coating to hole injection layer (30) formed on the substrate. Then said hole injection layer (30) by vacuum thermal deposition or spin coating on top of the transport layer material hole (40) formed on the substrate. Then, said hole (40) on top of an organic luminous layer (50) said laminated an organic luminous layer (50) (not shown) hole obstruction layer selectively on top of vacuum deposition method, or spin coating method can be as thin film. Said timing relay having the organic function layer cathode hole obstruction layer through holes of life is reduced efficiency HOMO (Highest Occupied Molecular Orbital) level by using very low material preventing such door number could be bonded each other. At this time, a hole transport material are specially used but one number higher ionization potential should have electronic transport capacity 802.11a packets while having light-emitting compound which typically BAlq, BCP, can be TPBI is used as the alkali. This hole from harmful alkali metal-containing fullerene (60) vacuum deposition method, or spin coating method after deposited with an (70) is formed with an said (70) on top of a metal layer cathode vacuum thermal deposition by cathode (80) electrode layer 4 on a substrate the organic EL element. A silicon carbide single crystal for forming cathodes in a excitation (Li), magnesium (Mg), aluminum (Al), aluminum - lithium (Al provided Li), calcium (Ca), magnesium (Mg provided In) indium -, magnesium - (Mg a-Ag) can be the use, in order to obtain the ITO front element, IZO using transmissive cathode can be used. In addition, the embodiments of the present invention, said light emitting layer has a thickness preferably in 50 to 2,000 Å, in addition said light emitting layer of the present invention said host with a dopant formed with a host compound can be used. The, said dopant compound to be a [formula D1] or [formula D2]. the light-emitting layer further comprises a dopant material can be various. [Formula D1] [formula D2] On during said [formula D1] [formula D2], A is 5 to 50 C12 substituted or unsubstituted aryl, a substituted or unsubstituted heterogeneous nuclear reactor and O, N or S 3 to 50 carbon atoms having a variety of aryl group, a substituted or unsubstituted carbon atoms of 6 to 60 it will be biting, [leyn not, O and a substituted or unsubstituted heterogeneous nuclear reactor, 3 to 50 carbon atoms having at least one selected from N or S can be any of a variety of it will be biting, [leyn. More specifically, it will be biting, [leyn A is not a substituted or unsubstituted carbon atoms of 6 to 60, or single bond and, preferably anthracene, fine alkylene, phenanthrene, [...], cryo-oligomerization, naphtacenediones, 500, triphenylene, perylene, pentacene may be either, more particularly, said A is represented by the formula A10 to either formula A1 may be a substituent described. [Formula A1] [formula A2] [formula A3] [Formula A4] [formula A5] [formula A6] [Formula A7] [formula A8] [formula A9] [Formula A10] Wherein said Z of [formula A3]1 To Z2 Is hydrogen, deuterium atoms, 1 to 60 C12 substituted or unsubstituted alkyl, a substituted or unsubstituted 2 to 60 between the light-emitting of C12, C12 to a substituted or unsubstituted alkynyl of 2 to 60, 60 to C12 alkoxy group substituted or unsubstituted 1, 1 to 60 mote unyielding spirit (alkylthio) C12 substituted or unsubstituted alkyl, substituted or unsubstituted cycloalkyl group of 3 to 60 C12, C12 6 60 to a substituted or unsubstituted aryl, a substituted or unsubstituted 5 to 60 [...] of C12, a substituted or unsubstituted 5 to 60 [...] of C12, C12 2 to 60 of a substituted or unsubstituted heteroaryl group, a substituted or unsubstituted (alkyl) of 1 to 60 C12 amino, di (substituted or unsubstituted 1 to 60 C12 alkyl) amino group, or (C12 6 60 to a substituted or unsubstituted aryl) amino, di (substituted or unsubstituted aryl of 6 to 60 C12) 1 selected from the group consisting of at least one amino group, Z1 To Z2 Which are equal to each other or different from each hereinafter, may form a fused ring with adjacent. In addition said during [formula D1], Said X1 X and2 Are each independently a substituted or unsubstituted carbon atoms of 6 to 30 may be a single bond and not it will be biting, [leyn, X1 X and2 Can be coupled each other, Said Y1 And Y2 Not 6 to 24 carbon atoms each independently a substituted or unsubstituted aryl, a substituted or unsubstituted heteroaryl group of 2 to 24 C12, C12 1 24 to a substituted or unsubstituted alkyl, a substituted or unsubstituted heterocyclic inhibitors of 24 1 to C12 alkyl group, a substituted or unsubstituted 3 to 24 of C12 cycloalkyl, a substituted or unsubstituted alkoxy group 1 to 24 C12, cyano group, a halogen, a substituted or unsubstituted [...] C12 of 6 to 24, 1 to 40 C12 alkyl substituted or unsubstituted silyl group, a substituted or unsubstituted [...] C12 of 6 to 30, germanium, phosphorus, boron, at least one selected from the group consisting of deuterium and hydrogen 1, Y1 To Y2 Which are equal to each other or different from each hereinafter, adjacent with aliphatic, aromatic, aliphatic heterocyclic or aromatic hetero polymer can be a condensation forms a ring. Said l, m each integer number of 1 to 20, n is an integer 1 to 4. In addition said during [formula D2], Cy A substituted or unsubstituted cycloalkyl of 3 to 8 and is C12, b is the integer number of 1 to 4, b is 2 or more fused cycloalkanes each form may be, in addition, the substituted each deuterium or alkyl can be substituted, be the same or different each other. In addition said BA single bond or - [C (R5 ) (R6 )]p - And, the p is an integer 1 to 3, 2 or more R p is 2 or more5 And R6 Are identical to each other or different from and hereinafter; Said R1 , R2 , R3, R5 And R6 Independently of each other, hydrogen, deuterium, halogen atom, hydroxyl groups, cyano group, nitro, amino, amino [...], hydrazine, hydra zone, carboxylic luck practical technique or salt thereof, sulfonic labor pains or salt thereof, phosphoric acid or salt thereof, 1 to 60 C12 substituted or unsubstituted alkyl, a substituted or unsubstituted 2 to 60 between the light-emitting of C12, C12 to a substituted or unsubstituted alkynyl of 2 to 60, 1 to 60 C12 substituted or unsubstituted alkoxy group, a substituted or unsubstituted alkyl of 1 to 60 mote unyielding spirit C12 (alkylthio), a substituted or unsubstituted cycloalkyl group of 3 to 60 C12, C12 6 60 to a substituted or unsubstituted aryl, a substituted or unsubstituted 5 to 60 [...] of C12, a substituted or unsubstituted 5 to 60 [...] of C12, C12 substituted or unsubstituted heteroaryl group of 2 to 60, C12 (alkyl) 1 to 60 of a substituted or unsubstituted amino, di (substituted or unsubstituted 1 to 60 C12 alkyl) amino, or (6 to 60 C12 substituted or unsubstituted aryl) amino, di (substituted or unsubstituted 6 to 60 C12 aryl) amino group, a substituted or unsubstituted alkyl silyl group 1 to 40 C12, a substituted or unsubstituted 6 to 30 [...] of C12, germanium, phosphorus, boron can be selected from, A is the integer number of 1 to 4, a is 2 or more R 2 or more3 Hereinafter the same or different from each other and, R3 When a plurality, each R3 The fused form may be, n is an integer 1 to 4. In addition, [formula D1] and [formula D2] A of said coupled to the [substituent 52] to [substituent 1] to an amine represented by the formula selected from the group consisting either display but, the defined are not correct. [Substituent 1] [substituent 2] [substituent 3] [4 Substituted] [5 substituted] [6 substituted] [Substituent 7] [substituent 8] [9 substituted] [Substituent 10] [substituent 11] [12 substituents] [Substituent 13] [14 substituted] [substituent 15] [Substituent 16] [17 substituted] [substituent 18] [Substituent 19] [20 substituted] [substituent 21] [Substituent 22] [23 substituted] [substituent 24] [Substituent 25] [26 substituted] [substituent 27] [Substituent 28] [29 substituted] [substituent 30] [Substituent 31] [32 substituted] [substituent 33] [Substituent 34] [35 substituted] [substituent 36] [Substituent 37] [substituent 38] [39 substituents] [Substituent 40] [41 substituted] [substituent 42] [Substituent 43] [substituent 44] [45 substituted] [Substituent 46] [47 substituted] [substituent 48] [Substituent 49] [50 substituted] [substituent 51] [Substituent 52] Said substituents independently or in R are identical to each other, hydrogen, deuterium, halogen atom, hydroxyl groups, cyano group, nitro, amino, amino [...], hydrazine, hydra zone, carboxylic luck practical technique or salt thereof, sulfonic labor pains or salt thereof, phosphoric acid or salt thereof, 1 to 60 C12 substituted or unsubstituted alkyl, a substituted or unsubstituted 2 to 60 C12 of the light-emitting, C12 to a substituted or unsubstituted alkynyl of 2 to 60, 60 to C12 alkoxy group substituted or unsubstituted 1, 1 to 60 mote unyielding spirit (alkylthio) C12 substituted or unsubstituted alkyl, substituted or unsubstituted cycloalkyl group of 3 to 60 C12, C12 6 60 to a substituted or unsubstituted aryl, a substituted or unsubstituted 5 to 60 [...] of C12, C12 [...] of a substituted or unsubstituted 5 to 60, 2 to 60 of C12 substituted or unsubstituted heteroaryl group, a substituted or unsubstituted (alkyl) of 1 to 60 C12 amino, di (substituted or unsubstituted 1 to 60 C12 alkyl) amino, or (6 to 60 C12 substituted or unsubstituted aryl) amino, di (substituted or unsubstituted 6 to 60 C12 aryl) amino group, a substituted or unsubstituted alkyl silyl group 1 to 40 C12, a substituted or unsubstituted 6 to 30 [...] of C12, germanium, phosphorus, boron can be selected, which can be substituted 1 to 12 each in two, each substituents can form a fused ring with adjacent. Hereinafter, the present invention for example preferred embodiment more detailed as follows. However, the present invention is more specifically to account for these in the embodiment, of the present invention is not one that the party industry to range the person with skill in the art will-case number. (In the embodiment) Synthesis example 1: synthesis of formula 1 Synthesis example 1 - (1): synthesis of [intermediates 1 a-a] A compound according to 1, [intermediates 1 provided a] and copiers. 1><Reactive 1 A-a><intermediates Methyl 5 - bromo - 2 - 500 ml reactor [...] eye coordinate of the benzoate (25. 0G, 73mmol), 4 - dibenzo the [phyu column step theory it buys (18. 7G, 88mmol), tetrakis (triphenyl phosphine) palladium (1. 7G, 0. 15Mmol), potassium purification (20. 2 G, 146. 7Mmol) and toluene into 125 ml, 125 ml tetrahydrofuran mixable, been painted with 50 ml water. Reactor 10 have been stirring time temperature temperature 80 into the road. The end point of the reaction temperature of ethyl acetate at room temperature reaction period particularly as organic layer was separated. The organic layer after separating column 1 a-a cream as well as intermediates are obtained. (75. 0G, 60. 1%) Synthesis example 1 - (2): synthesis of intermediates 1 a-b A compound according to 2 1 a-b intermediates and copiers: 2><Reactive 1 A-a 1 a-b intermediates><><intermediates 500 Ml reactor 1 provided a>[...]<intermediates (17. 0G, 45mmol), sodium hydroxide (2. 14G, 54mmol), 170 ml ethanol and reflux stirring time was placed in the 48. , Thin film chromatography was cooled down to room temperature after confirmation to the completion. 2 - Cooled enemy normal hydrochloric acid solution, 30 minutes stirring was generated acidifying the solids after filtering. Dichloro methane and 1 a-b is recrystallised with normal><intermediates are obtained. (14. 5G, 88. 6%) Synthesis example 1 - (3): synthesis of intermediates 1 a-c A compound according to intermediates 1 a-c 3 and copiers: 3><Reactive 1 A-b intermediates 1 a-c>><<intermediates 250 Ml reactor>[...]<intermediates 1 a-b (14. 5G, 39mmol), methanesulphonic acid 145 ml stirring time was 3 to 80 into and out of the elevated road. [...] been cooled to room temperature after confirmation to the completion. After stirring 30 minutes was 150 ml [...] reaction solution comprises a enemy slowly. The resulting solids after the water and methanol are flushable><intermediates 1 a-c are obtained. (11. 50G, 83. 4%) Synthesis example 1 - (4): synthesis of intermediates 1 a-d A compound according to intermediates 1 a-d 4 and copiers: 4><Reactive 1 A-c 1 a-d><intermediates><intermediates 1L [...] reactor><intermediates 1 a-c (11. 5G, 33mmol>, dichloro methane into 300 ml was stirred at ordinary temperature. Bromine (3. 4 Ml, 66mmol) dichloro methane dilution to the enemy [...] to 50 ml, 8 time was stirring at room temperature. After completion of the reaction the reaction vessel 100 ml acetone with concave-gate. The resulting solids after the acetone wash me. Solid which is recrystallised<1 a-d are obtained>mono chlorobenzene to intermediates. (11. 0G, 78%) Synthesis example 1 - (5): synthesis of intermediates 1 a-e A compound according to intermediates 1 a-e 5 and copiers: 5><Reactive 1 A-d><intermediates 1 a-e><intermediates 250 Ml [...] reactor 2 - bromo biphenyl (8. 4G, 0. 036Mol) and nitrogen atmosphere was placed in 110 ml tetrahydrofuran mixable -78 road cooling. Cooled reaction solution roh the butyl lithium which it rolls up (19. 3 Ml, 0. 031Mol) enemy-gate the same temperatures. 2 Reaction solution comprises a stirring time after 1 a-d><intermediates (11. 0G, 0. 026Mol) was stirred at room temperature into a little at a time. The TLC confirmed that the reaction terminated reaction solution changes color. H2O 50 ml ethyl acetate extracted from the reactive ends and placed in the water. After separating organic layer concentrated to 1 a-e>knight reel is recrystallised<degassed acetoacetoxy-functional intermediates are obtained. (12. 2G, 81. 5%) Synthesis example 1 - (6): synthesis of intermediates 1 a-f A compound according to intermediates 1 a-f 6 and copiers: 6><Reactive 1 A-e 1 a-f><intermediates><intermediates 250 Ml reactor 1 a-e>[...]<intermediates (12. 0G, 0. 021Mol) 120 ml with acetic acid, 2 ml sulfate and 5 placed in the reflux time was stirring. Solid once created [...] was cooled down to room temperature after confirmation to the completion. The resulting solids after the H2O, methanol good for a repulsion mono chlorobenzene to by silica gel filtration, after cooling the concentrated at room temperature 1 a-f><intermediates are obtained. (10. 7G, 90%> Synthesis example 1 - (7): synthesis of formula 1 A compound according to formula 1 configurated 7: 7><Reactive Formula 1 1 a-f><><intermediates 500 Ml reactor>[...]<intermediates 1 a-f (10. 0G, 0. 017Mol), phenyl boronic acid (4. 8G, 0. 039Mol), tetrakis triphenyl phosphine palladium (0. 8G, 0. 001Mol), purification of potassium (9. 56G, 0. 069Mol), 120 ml toluene, ethanol 60 ml, 45 ml water and placed in the reflux stirring time-gate 2. After completion of reaction was cooled at room temperature. Reaction solution comprises a concentrated methanol after melting and subsequent recrystallization to dichloro methane to toluene decodes a hot filter. Positive number dichloro methane and formula 1 acetone after separating column is recrystallised<>stingy. (9. 9G, 99%) MS (MALDI-a TOF): m/z 558. 2 [M+ ] Synthesis example 2: synthesis of formula 21 Synthesis example 2 - (1): synthesis of intermediates 2 a-a A compound according to 8, intermediates 2 a-a and copiers: 8><Reactive 2 A-a><intermediates 2L [...] reactor my [phu mask it buys 1 - hydroxy 2 - (50g, 266mmol), 1000 ml methanol, 100 and 100 ml was placed in the sulfuric acid reflux stirring time. TLC was cooling to room temperature after confirmation to the completion. After cream solution is extracted from the dichloro methane into methane. Organic layer pattern to anhydrous magnesium alkylsulfate after filtration, is recrystallised><intermediates 2 a-a cream after heptane to are obtained. (39G, 72. 6%) Synthesis example 2 - (2): synthesis of intermediates 2 a-b A compound according to 2 a-b intermediates 9 and copiers: 9><Reactive 2 A-b intermediates>><<intermediates 2 a-a 1L [...] reactor 2 provided a><intermediates (39. 0G, 193mmol), 390 ml acetic acid-gate into stirring at ordinary temperature. 80 Ml acetic acid brominated (11. 8 Ml, 231mmol) dilution was enemy to a reactive solution. Reaction solution comprises 5 at room temperature stirring time-gate. After completion of reaction resulting solids have filtering, heptane slurry after><intermediates 2 a-b are obtained. (50G, 90%) Synthesis example 2 - (3): synthesis of intermediates 2 a-c A compound according to intermediates 2 a-c 10 and copiers: 10><Reactive 2 A-b intermediates 2 a-c>><<intermediates 2L<>[...] reactor 2 a-b intermediates (50g, 178mmol) dichloro methane and with concave up. Nitrogen atmosphere pyridine (28. 1G, 356mmol) 20 minutes into the reaction solution was stirred at room temperature. 0 Reaction solution comprises a road after cooling under nitrogen atmosphere triple nick base oro methane opinion gun id anhydro-synchronized (65. 24G, 231mmol) enemy a-gate. 3 TLC after confirming the completion time to stirring, 20 ml 10 minutes stirring into water and-gate. After<intermediates 2 a-c are obtained>cream reaction solution comprises a column are separated from each other. (45G, 61%) Synthesis example 2 - (4): synthesis of intermediates 2 a-d A compound according to intermediates 2 a-d 11 and copiers: 11><Reactive 2 A-c><intermediates 2 a-d><intermediates 1L [...] reactor><intermediates 2 a-c (45. 0G, 0. 109Mol), 4 - dibenzo [...] (25. 4G, 0. 120Mol), tetrakis (triphenyl phosphine) palladium (2. 5G, 0. 22Mmol), potassium purification (30. 1 G, 0. 218Mol) and placed in 300 ml toluene, 130 ml ethanol, been painted with 90 ml water. Reactor temperature then 5 have been stirring time temperature road 80. The end point of the reaction temperature of ethyl acetate at room temperature reaction period particularly as organic layer was separated. The organic layer after column chromatography separated<intermediates 2 a-d>cream are obtained. (22. 0G, 46. 1%) Synthesis example 2 - (5): synthesis of intermediates 2 a-e 12 A compound according intermediates 2 a-e and copiers: 12><Reactive <Intermediates 2 a-d>><intermediates 2 a-e 1L [...] reactor><intermediates 2 a-d (22. 0, 0. 051Mol), sodium hydroxide (2. 65G, 0. 066Mol) frame and reflux stirring time was 48. After the reaction was cooled down to room temperature. 2 - Cooled enemy normal hydrochloric acid solution, 30 minutes stirring was generated acidifying the solids after filtering. Dichloro methane and 2 a-e is recrystallised with normal><intermediates are obtained. (17. 6G, 82. 7%) Synthesis example 2 - (6): synthesis of intermediates 2 a-f A compound according to intermediates 2 a-f 13 and copiers: 13><Reactive 2 A-f 2 a-e><intermediates><intermediates 500 Ml reactor>[...]<intermediates 2 a-e (17. 6G, 0. 042Mol), stirring time was 3 to 170 ml methanesulphonic acid 80 into and out of the elevated road. [...] been cooled to room temperature after confirmation to the completion. After stirring 30 minutes was 150 ml [...] reaction solution comprises a enemy slowly. The resulting solids after the water and methanol good for me. Filtering the solids was mono chlorobenzene for 1 to 3 silica gel pad. After heating concentrated acetone filtrate is recrystallised><intermediates 2 a-f are obtained. (12G, 71%) Synthesis example 2 - (7): synthesis of intermediates 2 a-g A compound according to intermediates 2 a-g 14 and copiers: 14><Reactive <Intermediates 2 a-f 2 a-g>><intermediates 1L [...] reactor><intermediates 2 a-f (12. 0G, 0. 030Mol) dichloro methane to 360 ml to the fire. During stirring at room temperature bromine (3. 1 Ml, 0. 06Mol) 40 ml dichloro methane to the enemy a dilution-gate. It does, 12 100 ml methanol at room temperature stirring time after completion of the reaction the resulting solids into filtered methanol good for me. 1, 2 - Dichloro benzene and acetone is recrystallised><intermediates 2 a-g are obtained. (10. 3G, 71. 7%) Synthesis example 2 - (8): synthesis of intermediates 2 a-h A compound according to intermediates 2 a-h 15 and copiers: 15><Reactive 2 A-g><intermediates 2 a-h><intermediates Said synthesis example 1 - (5) instead of 1 a-d><intermediates in the range of 0.1 and the number [...]><intermediates 2 a-g, using the same method<intermediates 2 a-h>stingy. (10. 0 G, 73. 4%) Synthesis example 2 - (9): synthesis of intermediates 2 a-i A compound according to intermediates 2 a-i 16 and copiers: 16><Reactive 2 A-h><intermediates 2 a-i><intermediates Said synthesis example 1 - (6) instead of 1 a-e><intermediates in the range of 0.1 and 2 a-h>[...]<intermediates the number, using the same method 2 provided i><intermediates are obtained. (6. 3 G, 64. 8%) Synthesis example 2 - (10): synthesis of formula 21 A compound according to formula 21 17 and copiers: 17><Reactive 2 A-i><><intermediates formula 21 Said synthesis example 1 - (7) 1 a-f 2 a-i>><intermediates in the range of 0.1 and the number [...]<intermediates instead, using the same method formula 21<>stingy. (6. 0G, 98%) MS (MALDI-a TOF): m/z 608. 21 [M+ ] Synthesis example 3: synthesis of formula 34 Synthesis example 3 - (1): synthesis of intermediates 3 a-a A compound according to 18, intermediates 3 a-a and copiers: 18><Reactive ><Intermediates 3 a-a 2L [...] reactor same compound 4 - bromo (100. 0G, 0. 405Mol), ethynyl tree [...] (47. 7G, 0. 486Mol), dichloro [1, 1' - bis ([...]) ferrocene] palladium (9. 92G, 0. 012Mol), copper iodide (2. 31G, 0. 012Mol), triphenyl phosphine (10. 6G, 0. 040Mol), reflux stirring in nitrogen atmosphere triethylamine 700 ml was placed in the 5 time. After completion of reaction was 500 ml heptane and cooling reaction end is placed. This [thu and silica gel pad filtration was minced and seasoned 2000. Cream or><intermediates 3 a-a are obtained. (130G, 84%) Synthesis example 3 - (2): synthesis of intermediates 3 a-b A compound according to 19, intermediates 3 a-b and copiers: 19><Reactive 3 A-b intermediates>><<intermediates 3 a-a 2L [...] reactor><intermediates 3 a-a (130g, 0. 492Mol), potassium carbonate (101. 9G, 0. 738Mol), methanol 650 ml, 650 ml tetrahydrofuran mixable and 2 placed in the stirring time was at room temperature. After completion of the reaction was reacted terminate into 500 ml heptane. Filtering the reaction solution comprises water and ethyl acetate extracted from the filtrate. Separating the organic layer followed by filtration in the form of anhydrous magnesium alkylsulfate<intermediates 3 a-b>cream or oil processing are obtained. (82G, 84%) Synthesis example 3 - (3): synthesis of intermediates 3 a-c A compound according to 20, intermediates 3 a-c and copiers: 20><Reactive 3 A-c 3 a-b intermediates>><<intermediates 2L [...] reactor 2 - bromo biphenyl (66. 0G, 0. 283Mol),><intermediates 3 a-b (65. 3G, 0. 340Mol), [1, 1' - bis ([...]) ferrocene] decrypts with palladium (6. 94G, 0. 008Mol), copper iodide (1. 62G, 0. 008Mol), triphenyl phosphine (7. 4G, 0. 028Mol), reflux stirring in nitrogen atmosphere triethylamine 500 ml was placed in the 5 time. After completion of reaction was placed 400 ml heptane and cooling reaction end. This [thu and silica gel pad filtration was minced and seasoned 2000. Resulting solids contained in the pressure-reducing concentrated filtrate><intermediates 3 a-c are obtained. (80G, 82%) Synthesis example 3 - (4): synthesis of intermediates 3 a-d A compound according to 21, intermediates 3 a-d and copiers: 21><Reactive <Intermediates 3 a-c 3 a-d>><intermediates 2L [...] reactor><intermediates 3 a-c (80. 0G, 0. 232Mol) dichloro methane into the nitrogen atmosphere was reconstituted with a 960 ml -78 road cooling. One ammonium child five [tin cooled solution (278. 4 Ml, 0. 279Mol) enemy-gate 12 and a stirring time at room temperature. Saturated aqueous solution sodium gap five opinion pay [thu after completion of the reaction with concave-gate. Dichloro methane and water separating organic layer extracted was cream. The circle><intermediates 3 a-d determined methanol are obtained. (67G, 61. 3%) Synthesis example 3 - (5): synthesis of intermediates 3 a-e A compound according to 22, intermediates 3 a-e and copiers: 22><Reactive <Intermediates 3 a-d>><intermediates 3 a-e 500 Ml reactor>[...]<intermediates 3 a-d (54. 8G, 0. 117Mol) 150 ml was placed under nitrogen atmosphere after melting and cooling 2 [...] -78 road. Cooled solution 1. 6 Mole roh the butyl loom which it rolls up (62. 4 Ml, 0. 1Mol) enemy same temperatures and a stirring time-gate 1. 9 - [Ley rice field flow five (15. 0G, 0. 083Mol) stirring at room temperature for 1 to 3 and 8 to 50 ml tetrahydrofuran mixable enemy time-gate. Ethyl acetate extracted from the water after completion of the reaction. Separating the organic layer in the form of cream or oil processing anhydride followed by filtration to magnesium alkylsulfate><intermediates 3 a-e are obtained. (33. 2G, 76%) Synthesis example 3 - (6): synthesis of intermediates 3 a-f A compound according to 23, intermediates 3 a-f and copiers: 23><Reactive <Intermediates 3 a-e>><intermediates 3 a-f 1L [...] reactor><intermediates 3 a-e (33. 3G, 0. 063Mol) 330 ml with acetic acid, sulfuric acid and reflux stirring time was 3 ml into 3. [...] was cooled down to room temperature after confirmation to the completion. The resulting solids after the H2O,<intermediates 3 a-f are obtained>mode so that good for methanol. (28. 6G,>88% Synthesis example 3 - (7): synthesis of intermediates 3 a-g A compound according to 24, intermediates 3 a-g and copiers: 24><Reactive <Intermediates 3 a-f 3 a-g>><intermediates 1L [...] reactor><intermediates 3 a-f (20. 0G, 0. 039Mol) placed on a 200 ml dichloro methane ofhis anger. During stirring at room temperature bromine (6 ml, 0. 118Mol) 40 ml dichloro methane to the enemy a dilution-gate. It does, 12 100 ml methanol at room temperature stirring time after completion of the reaction the resulting solids into filtered methanol good for me. Material is 1, 2 - dichloro benzene and acetone is recrystallised><intermediates 3 a-g are obtained. (16G, 60%) Synthesis example 3 - (8): synthesis of formula 34 A compound according to 25, a configurated formula 34: 25><Reactive Formula 34>><<intermediates 3 a-g Said synthesis example 1 - (7) 1 a-f><intermediates in a number in the range of 0.1 and the [...]><intermediates 3 a-g instead, using the same method formula 34<>stingy. (5. 2 G, 98. 6%) MS (MALDI-a TOF): m/z 658. 23 [M+ ] Synthesis example 4: synthesis of formula 52 Synthesis example 4 - (1): synthesis of intermediates 4 a-a A compound according to 26, intermediates 4 a-a and copiers: 26><Reactive ><Intermediates 4 a-a Same compound 1 - bromo [...] 500 ml reactor (20. 0G, 0. 081Mmol), bis (blood or cola earth) diboron (26. 7G, 0. 105Mol), [1, 1' - bis ([...]) ferrocene] decrypts with palladium (1. 3G, 0. 002Mol), potassium acetate (19. 9G, 0. 202Mol), 1, 4 - dioxane and placed in 200 ml 10 reflux stirring time-gate. After completion of reaction was filtering 2000 light pad. The pressure-reducing concentrated filtrate dichloro methane and heptane to have after separating column is recrystallised><intermediates 4 a-a are obtained. (17. 0G, 70%) Synthesis example 4 - (2): synthesis of 4 a-b intermediates A compound according to 27, 4 a-b intermediates and copiers: 27><Reactive 4 A-b intermediates>><<intermediates 4 a-a Said synthesis example 1 - (1) instead of 4 - dibenzo [...] in a number in the range of 0.1 and the [...]><intermediates 4 a-a, 4 a-b intermediates using same method<>stingy. (13. 1G, 68. 9%) Synthesis example 4 - (3): synthesis of intermediates 4 a-c A compound according to 28, intermediates 4 a-c and copiers: 28><Reactive 4 A-b intermediates 4 a-c><><intermediates Said synthesis example 1 - (2) instead of 4 a-b intermediates in<intermediates 1 provided a number in the range of 0.1 and a><>[...] a, using the same method<intermediates 4 a-c>stingy. (11. 0G, 87%) Synthesis example 4 - (4): synthesis of intermediates 4 a-d A compound according to 29, intermediates 4 a-d and copiers: 29><Reactive <Intermediates 4 a-c>><intermediates 4 a-d Said synthesis example 1 - (3) instead of 1 a-b intermediates in<><>[...] a number in the range of 0.1 and the intermediates 4 a-c, using the same method<intermediates 4 a-d>stingy (11. 0G, 87%) Synthesis example 4 - (5): synthesis of intermediates 4 a-e A compound according to 30, intermediates 4 a-e and copiers: 30><Reactive <Intermediates 4 a-d>><intermediates 4 a-e Said synthesis example 1 - (4) instead of 1 a-c><intermediates in the range of 0.1 and the number [...]><intermediates 4 a-d, using the same method<intermediates 4 a-e>stingy (6. 7G, 60. 7%) Synthesis example 4 - (6): synthesis of intermediates 4 a-f A compound according to 31, intermediates 4 a-f and copiers: 31><Reactive <Intermediates 4 a-e>><intermediates 4 a-f Said synthesis example 1 - (5) instead of 1 a-d><intermediates in the range of 0.1 and the number [...]><intermediates 4 a-e, using the same method<intermediates 4 a-f>stingy (5. 2G, 55%) Synthesis example 4 - (7): synthesis of intermediates 4 a-g A compound according to intermediates 4 a-g 32 and copiers: 32><Reactive <Intermediates 4 a-f>><intermediates 4 a-g Said synthesis example 1 - (6) instead of 1 a-e><intermediates in the range of 0.1 and the number [...]><intermediates 4 a-f, using the same method a><intermediates 4 a-g are obtained. (4. 3G, 85. 3%) Synthesis example 4 - (8): synthesis of formula 52 A compound according to formula 52 33 and copiers: 33><Reactive Formula 52>><<intermediates 4 a-g Said synthesis example 1 - (7) instead of 1 a-f><intermediates in the range of 0.1 and the number [...]><intermediates 4 a-g, using the same method formula 52<>stingy. (2. 5G, 34%) MS (MALDI-a TOF): m/z 558. 2 [M+ ] Synthesis example 5: synthesis of formula 83 Synthesis example 5 - (1): synthesis of intermediates 5 a-a A compound according to 34, intermediates 5 a-a and copiers: 34><Reactive 5 A-a><intermediates 1L round bottom [phul [su pen jade hour aniline 2 - reactor (25. 0, 0. 135Mol) and hydrochloric acid in 30 ml, 150 ml water and cool the stirring time was placed in the road 0 1. Sodium age tree [thu same temperatures (11. 2G, 0. 162Mol) enemy 1 75 ml aqueous solution reaction solution after stirring time-gate. Potassium iodide (44. 8G, 0. 270Mol) enemy 75 ml aqueous solution when a temperature of the reaction solution 5 degree not enemy attention beyond the and-gate. 5 Stirring at room temperature it does as a favor, reaction time after completion of water extracted from the ethyl acetate washed the aqueous solution sodium gap five opinion pay [thu. The organic layer after separating the positive number><intermediates 5 a-a cream separation column are obtained. (22. 6G, 56. 5%) Synthesis example 5 - (2): synthesis of 5 a-b intermediates A compound according to 35, 5 a-b intermediates and copiers: 35><Reactive 1 A-d<><intermediates 5 provided a>><intermediates 5 a-b intermediates Said synthesis example 1 - (5) instead of 2 - bromo biphenyl in a number in the range of 0.1 [...]><intermediates 5 a-a and a, using the same method 5 a-b intermediates<>stingy. (19. 6G, 70. 4%) Synthesis example 5 - (3): synthesis of intermediates 5 a-c A compound according to 36, intermediates 5 a-c and copiers: 36><Reactive 5 A-b intermediates 5 a-c>><<intermediates Said synthesis example 1 - (6) instead of in the range of 0.1 5 a-b intermediates><><intermediates 1 a-e and the [...] number, using the same method<intermediates 5 a-c>stingy. (14. 2 G, 74. 7%) Synthesis example 5 - (4): synthesis of formula 83 A compound according to 37, a configurated formula 83: 37><Reactive 5 A-c formula 83>><<intermediates Said synthesis example 1 - (7) 1 a-f><intermediates in a number in the range of 0.1 and 5 a-c instead of the [...]><intermediates, using the same method formula 83<>stingy. (2. 4 G, 28%) MS (MALDI-a TOF): m/z 574. 19 [M+ ] Synthesis example 6: synthesis of formula 104 Synthesis example 6 - (1): synthesis of intermediates 6 a-a A compound according to 38, intermediates 6 a-a and copiers: 38><Reactive ><Intermediates 6 a-a 2L [...] reactor 4 - dibenzo [...] (85. 0G, 0. 401Mol), bismuth (III) nitrate [...] (99. 2G, 0. 200Mol), nitrogen atmosphere into 400 ml toluene 70 road 3 stirring time-gate. After completion of reaction was filtering cooling resulting solids at room temperature. The toluene wash is carried out after 6 provided a><intermediates are obtained. (61. 5G, 72%) Synthesis example 6 - (2): synthesis of intermediates 6 a-b A compound according to the intermediates 6 a-b 39 and copiers: 39><Reactive 6 A-b intermediates>><<intermediates 6 a-a 2L [...] reactor ethyl acetate monohydrate (202. 9G, 1. 794Mol) on dimethylformamide amide 500 ml to the fire. Potassium hydroxide (67. 10G, 1. 196Mol), inside anger between potassium (38. 95G, 0. 598Mol) and dimethylformamide was stirred into 200 ml amide into at ordinary temperature. ><Intermediates 6 a-a reactive solution (127. 5G, 0. 737Mol) 50 whereupon the oxidation film is in the stirring time-gate 72. Reaction after completion of an aqueous sodium hydroxide (25%) and reflux stirring into 200 ml-gate. 3 Have room temperature stirring time after cooling, [...] acetate extracted from the water. Separating the organic layer concentrated column chromatography separation to have positive number<intermediates 6 a-b yes degassed defendant>are obtained. (20. 0G, 16%) Synthesis example 6 - (3): synthesis of intermediates 6 a-c A compound according to the intermediates 6 a-c 40 and copiers: 40><Reactive 6 A-b intermediates 6 a-c>><<intermediates 2L [...] reactor><intermediates 6 a-b (20. 0G, 0. 096Mol), 600 ml ethanol, an aqueous potassium hydroxide (142. 26G, 2. 53Mol) 170 ml into time-gate 12 and reflux stirring. On completion of the reaction was cooled at room temperature. 6 Normal hydrochloric acid reactive solution after 20 minutes stirring into 400 ml and acidifying the resulting solids have been filtered. 6 A-c><intermediates into ethanol wash is carried out after the solids are obtained. (17. 0G, 88. 5%) Synthesis example 6 - (4): synthesis of intermediates 6 a-d A compound according to the intermediates 6 a-d 41 and copiers: 41><Reactive <Intermediates 6 a-c>><intermediates 6 a-d 2L [...] reactor><intermediates 6 a-c (17. 0G, 0. 075Mol), 15 ml sulfate [neh with a reflux stirring time-gate 72. After completion of reaction at room temperature after cooling ethyl acetate extracted from the water. Separating the organic layer with an aqueous solution sodium bicarbonate wash me. The organic layer into excess methanol during cream resulting solids contained in><intermediates 6 a-d are obtained. (14. 0G, 77. 6%) Synthesis example 6 - (5): synthesis of intermediates 6 a-e A compound according to the intermediates 6 a-e 42 and copiers: 42><Reactive <Intermediates 6 a-d>><intermediates 6 a-e 5 - Said synthetic example (1) in the range of 0.1 and 2 - pen jade hour aniline intermediates 6 a-d>[...]<instead in the number, using the same method<intermediates 6 a-e>stingy. (9. 1G, 48%) Synthesis example 6 - (6): synthesis of intermediates 6 a-f A compound according to the intermediates 6 a-f 43 and copiers: 43><Reactive 6 A-e><intermediates<intermediates 4 provided a><>intermediates 6 a-f Said synthesis example 4 - (2) - 2 - methyl 5 - bromo<intermediates 6 a-e in the range of 0.1 and the relative coordinate of the benzoate instead child>[...] the number, using the same method><intermediates 6 a-f are obtained. (5. 3 G, 52. 3%) Synthesis example 6 - (7): synthesis of intermediates 6 a-g A compound according to the intermediates 6 a-g 44 and copiers: 44><Reactive <Intermediates 6 a-f 6 a-g> > <intermediates Said synthesis example 1 - (2) instead of in the range of 0.1<intermediates 6 a-f>><intermediates 1 provided a number and the [...], using the same method><intermediates 6 a-g are obtained. (4. 5G, 88. 1%) Synthesis example 6 - (8): synthesis of intermediates 6 a-h A compound according to the intermediates 6 a-h 45 and copiers: 45><Reactive ><Intermediates 6 a-h><intermediates 6 a-g Said synthesis example 1 - (3) instead of 1 a-b intermediates 6 a-g><><intermediates in the range of 0.1 and the [...] number, using the same method><intermediates 6 a-h are obtained. (3. 8G, 88. 8%) Synthesis example 6 - (9): synthesis of intermediates 6 a-i A compound according to the intermediates 6 a-i 46 and copiers: 46><Reactive 6 A-h><intermediates 6 a-i><intermediates Said synthesis example 1 - (4) instead of 1 a-c><intermediates in a number in the range of 0.1 and the [...]><intermediates 6 a-h, using the same method<intermediates 6 a-i>(3g, 55%) are obtained Synthesis example 6 - (10): synthesis of intermediates 6 a-j A compound according to the intermediates 6 a-j 47 and copiers: 47><Reactive <Intermediates 6 a-i>><intermediates 6 a-j Said synthesis example 1 - (5) instead of 1 a-d><intermediates in the range of 0.1 and the number [...]><intermediates 6 a-i, using the same method><intermediates 6 a-j are obtained. (2. 5G, 64%) Synthesis example 6 - (10): synthesis of intermediates 6 a-k A compound according to the intermediates 6 a-k 48 and copiers: 48><Reactive 6 A-j><intermediates 6 a-k><intermediates Said synthesis example 1 - (6) instead of in the range of 0.1<intermediates 6 a-j>><intermediates 1 a-e and the [...] number, using the same method><intermediates 6 a-k are obtained. (2. 2G, 90. 4%) Synthesis example 6 - (11): synthesis of formula 104 A compound according to formula 104 configurated 49: 49><Reactive <Intermediates 6 a-k><>formula 104 500 Ml reactor [...]<intermediates 6 a-k>(10. 0G, 0. 015), 2 - Naphthalene [...] (5. 16G, 0. 030Mol), kissing tree phenyl gun spin palladium tetra (0. 706G, 0. 001Mol), potassium purification (8. 45G, 0. 061Mol), 45 ml toluene, dioxan 45 ml, 18 ml 2 reflux stirring into water and time-gate. After completion of reaction was cooled at room temperature. Reaction solution comprises a concentrated methanol after melting and subsequent recrystallization to dichloro methane to toluene decodes a hot filter. Positive number dichloro methane and is recrystallised<formula 104 separating column after acetone>stingy. (8. 6G, 77%) MS (MALDI-a TOF): m/z 748. 24 [M+ ] Synthesis example 7: synthesis of formula 115 Synthesis example 7 - (1): synthesis of intermediates 7 a-a A compound according to 50, intermediates 7 a-a and copiers: 50><Reactive 7 Provided a><intermediates 2L [...] reactor 4 - dibenzo [...] (85. 0G, 0. 401Mol), bismuth (III) nitrate [...] (99. 2G, 0. 200Mol), nitrogen atmosphere into 400 ml toluene 70 road 3 stirring time-gate. After completion of reaction was filtering cooling resulting solids at room temperature. After the toluene><intermediates 7 provided a main major portions are obtained. (61. 5G, 72%) Synthesis example 7 - (2): synthesis of 7 a-b intermediates A compound 51 7 a-b intermediates according and copiers: 51><Reactive 7 Provided a 7 a-b intermediates>><<intermediates 2L [...] reactor ethyl acetate monohydrate (202. 9G, 1. 794Mol) on dimethylformamide amide 500 ml to the fire. Potassium hydroxide (67. 10G, 1. 196Mol), inside anger between potassium (38. 95G, 0. 598Mol) into 200 ml and dimethylformamide amide-gate into stirring at ordinary temperature. 7 Provided a reactive solution><intermediates (127. 5G, 0. 737Mol) 50 whereupon the oxidation film is in the stirring time-gate 72. Reaction after completion of an aqueous sodium hydroxide (25%) and reflux stirring into 200 ml-gate. 3 Have room temperature stirring time after cooling, [...] acetate extracted from the water. Separating the organic layer concentrated positive number 7 a-b intermediates have column separating the degassed<>are obtained. (20. 0G, 16%) Synthesis example 7 - (3): synthesis of intermediates 7 a-c A compound according to intermediates 7 a-c 52 and copiers: 52><Reactive 7 A-b intermediates 7 a-c>><<intermediates 2L [...] reactor><intermediates 7 a-b (20. 0G, 0. 096Mol), 600 ml ethanol, an aqueous potassium hydroxide (142. 26G, 2. 53Mol) 170 ml into time-gate 12 and reflux stirring. On completion of the reaction was cooled at room temperature. 6 Normal hydrochloric acid have a reactive solution into 400 ml and acidifying, after filtering the resulting solids was 20 minutes stirring. After 7 a-c are obtained><intermediates into ethanol wash is carried out. (17. 0G, 88. 5%) Synthesis example 7 - (4): synthesis of intermediates 7 a-d A compound according to intermediates 7 a-d 53 and copiers: 53><Reactive <Intermediates 7 a-c>><intermediates 7 a-d 2L [...] reactor><intermediates 7 a-c (17. 0G, 0. 075Mol), 15 ml sulfate [neh with a reflux stirring time-gate 72. After completion of reaction at room temperature after cooling ethyl acetate extracted from the water. Separating the organic layer with an aqueous solution sodium bicarbonate wash me. Resulting solids contained in excess cream during methanol into><intermediates 7 a-d are obtained. (14. 0G, 77. 6%) Synthesis example 7 - (5): synthesis of intermediates 7 a-e A compound according to intermediates 7 a-e 54 and copiers: 54><Reactive 7 A-e>><intermediates<intermediates 7 a-d 5 - Said synthetic example (1) in the range of 0.1 and 2 - 7 a-d in the phosphorus substitution which will not be a pen jade city<intermediates>[...] the number, using the same method<intermediates 7 a-e>stingy. (9. 1G, 48%) Synthesis example 7 - (6): synthesis of intermediates 7 a-f A compound according to intermediates 7 a-f 55 and copiers: 55><Reactive 7 A-e><intermediates<intermediates 4 provided a>><intermediates 7 a-f Said synthesis example 1 - (1) 5 - bromo - 2 - methyl benzoates><intermediates 7 a-e instead of the relative coordinate of the child, instead of 4 - the [phyu column step theory it buys a number in the range of 0.1 and the [...]><intermediates 4 a-a dibenzoylmethane, using the same method><intermediates 7 a-f are obtained. (5. 3 G, 52. 3%) Synthesis example 7 - (7): synthesis of intermediates 7 a-g A compound according to intermediates 7 a-g 56 and copiers: 56><Reactive 7 A-f > <intermediates 7 a-g><intermediates Said synthesis example 1 - (2) instead of in the range of 0.1><intermediates 1 provided a number [...]><intermediates 7 a-f and a, 7 a-g are obtained><intermediates using the same method. (4. 5G, 88. 1%) Example 7 - synthesis (8): synthesis of intermediates 7 a-h A compound according to intermediates 7 a-h 57 and copiers: 57><Reactive 7 A-g><intermediates 7 a-h><intermediates Said synthesis example 1 - (3) instead of 1 a-b intermediates 7 a-g><><intermediates in the range of 0.1 and the [...] number, using the same method 7 a-h><intermediates are obtained. (3. 8G, 88. 8%) Synthesis example 7 - (9): synthesis of intermediates 7 a-i A compound according to intermediates 7 provided i 58 and copiers: 58><Reactive 7 A-h><intermediates 7 provided i><intermediates Said synthesis example 1 - (4) instead of 1 a-c><intermediates in the range of 0.1 and the number [...]><intermediates 7 a-h, using the same method 7 provided i><intermediates are obtained. (3. 0G, 55%) Synthesis example 7 - (10): synthesis of intermediates 7 a-j A compound according to intermediates 7 a-j 59 and copiers: 59><Reactive 7 Provided i><intermediates 7 a-j><intermediates Said synthesis example 1 - (5) instead of 1 a-d><intermediates in the range of 0.1 and the number [...]><intermediates 7 a-i, using the same method><intermediates 7 a-j are obtained (2. 5G, 64%) Synthesis example 7 - (10): synthesis of intermediates 7 a-k A compound according to intermediates 7 a-k 60 and copiers: 60><Reactive 7 A-j><intermediates 7 a-k><intermediates Said synthesis example 1 - (6) instead of 1 a-e><intermediates in the range of 0.1 and the number [...]><intermediates 7 a-j, using the same method 7 a-k><intermediates are obtained. (2. 2G, 90. 4%) Synthesis example 7 - (11): synthesis of formula 115 A compound according to formula 115 61 and copiers: 61><Reactive 7 A-k><formula 115><intermediates 500 Ml reactor 7 a-k>[...]<intermediates (10. 0G, 0. 015Mol), indole (3. 9G, 0. 033Mol), tree - 2 - tertiary butyl [...][...] (1. 4G, 0. 002Mol), phosphonium (0. 887G, 0. 003Mol), sodium it shakes off, department [thok side (8. 45G, 0. 061Mol), reflux stirring 50 ml xylene and 2 into time-gate. After completion of reaction was cooling. After recrystallization from methanol concentrated toluene-gate a hot filter. Dichloro methane and is recrystallised<>formula 115 positive number separating column after acetone are obtained. (8. 9G, 81. 5%) MS (MALDI-a TOF): m/z 726. 23 [M+ ] In the embodiment 1 to 7: number of organic light-emitting bath 2 Mm × 2mm ITO glass sized to cathode-gate after cleaning. Said ITO glass is mounted on the vacuum chamber base pressure 1 × 10-7 On DNTPD torr is to expose said ITO (700 Å), α-a NPD (300 Å) chemical vapor deposition compounds according the present invention and a bright 1 order after a (97:3) mixing forming film (250 Å) and then, after electron transport layer and a 1:1 ratio 300 Å [formula E-a 1] [formula E-a 2], a [formula E-a 1] 5 Å electron injection layer, Al (1000 Å) order number was high pressure liquid coolant is organic light emitting film. The Eu 0 said organic light-emitting device. 4 MA in a long time. [α-a NPD] [BD1] [formula E-a 1] [formula E-a 2] Comparison example 1 Said in the embodiment 1 to 7 instead of using the same heating conditions as used in host compounds in addition to small number it does, agent, said organic light emitting device light emitting characteristic is 0. 4 MA in a long time. The structure of the as follows. In the embodiment 1 to 7 and, in accordance with comparison example 1 number prepared by the organic light emitting elements, voltage, current density, Q. E, [table 1] have shown to result color coordinate measuring means. In the compounds according to the present invention said table 1 as comparison example 1 using the compound of the prior art than efficiency (Q. E) show excellent properties can be high and low voltage driving, the organic light emitting device applied likely indicates a disclosed. The present invention refers to a compound [formula B] and including an electron transporting layer are disclosed. [Formula B] [Formula B] said cyclic group A1 to A3, Q1 and Q2, R1 and R2, L1 to L4 formula, to Ar4 Ar1, E and F efined is a detailed description of the invention. [Formula B] to compound. [Formula B] In said [formula B], A1, A2, and mutually the same or different from each E and F hereinafter, a substituted or unsubstituted aromatic hydrocarbon of 6 to 50 carbon atoms independently of each other and a ring; said A1 and two adjacent carbon atoms in an aromatic ring, said A2 R1 and R2 substituents in adjacent two carbon atom of the aromatic ring in said annular carbon atoms and 5 by forming each connected to form a fused ring; and each said connector L1 and L2 to the insulating layer hereinafter, are each independently a single bond, a substituted or unsubstituted 6 to 60 it will be biting, [leyn of C12 in selected; said M is O, S selected from among resistant; said substituent R1 And R2 To the insulating layer and each hereinafter, are each independently a hydrogen, deuterium, 1 to 30 C12 substituted or unsubstituted alkyl, substituted or unsubstituted cycloalkyl group of 3 to 30 C12, C12 6 to 24 a substituted or unsubstituted aryl, a substituted or unsubstituted aryl group is selected from among a variety of C12 2 to 50, said R1 Or R2 It is an allyl substituents of 6 to 24 carbon atoms substituted when deuterium, for halogen, alkyl of 1 to 24 carbon atoms, 1 to 24 carbon atoms halogenated alkyl, 1 to 24 carbon atoms is selected from among alkyl silyl group, said R1 and R2 are each connected alicyclic, aromatic polycyclic forms a ring can be a single ring aromatic compound, said Ar1 hydrogen, deuterium, 1 to 30 C12 substituted or unsubstituted alkyl, a substituted or unsubstituted 6 to 50 C12 aryl, substituted or unsubstituted cycloalkyl group of 3 to 30 C12, selected among a variety of substituted or unsubstituted 2 to 50 C12 aryl group, a substituted or unsubstituted 6 to 50 said Ar2 is C12 aryl, or a substituted or unsubstituted heterocyclic inhibitors of 2 to 50 C12 alkoxy group, said s1 and s2 1 to 3 each is an integer, each connector L1 and L2 are each the same or more 2 these each and or different hereinafter, each said x and y and z is 0 and 1, said formula B in adjacent two carbon atoms of said ring said A1 in the formula Q2 * by being coupled to form a fused ring, said A2 in adjacent two carbon atoms of said ring structure Q1 * form fused ring by being coupled; said 'a' in 'substituted or unsubstituted substituted' is deuterium, for halogen, alkyl of 1 to 24 carbon atoms, 1 to 24 carbon atoms halogenated alkyl, 6 to 24 carbon atoms aryl, aryl-alkyl of 7 to 24 carbon atoms, 1 to 24 carbon atoms alkyl silyl group, 6 to 24 carbon atoms selected from the group consisting of one or more substituted [...] 1 which means that the other. According to Claim 1, said A1, A2, a substituted or unsubstituted aromatic hydrocarbon ring of 6 to 50 in E and F C12 and the same or different from the hereinafter, independently of each other selected from [formula 10] to [formula 21] cost characterized compound. [Formula 10] [formula 11] [formula 12] [Formula 13] [formula 14] [formula 15] [Formula 16] [formula 17] [formula 18] [Formula 20] [formula 21] [formula 19] [Formula 10] [formula 21] "- *" in said substituent R is said to1 And R2 Which is connected to a carbon including 5 formed to define a torus, or a binding site for forming said means including 5 in formula Q1 and Q2 and an annular M, said [formula 10] to [formula 21] A1 A2 corresponding to formula Q1 or Q2 formula while ring or annulus is aromatic hydrocarbon ring is among these adjacent two carbon atoms bind to Q1 or Q2 ** of formula of formula said bind to form a condensed ring by being coupled; said R R1 and R2 in the [formula 10] to [formula 21] is equal to defined according to Claim 1, and m is an integer 1 to 8, m is 2 or more R or R is 2 or more each be the same or different each other. According to Claim 1, L1 and L2 are each single bond or linking group in said formula B, [formula 1] below, [formula 2], [formula 4], [formula 6], selected from among resistant [formula 7], s1 s2 1 or 2 and characterized in each compound. [Formula 1] [formula 2] [formula 4] [Formula 6] [formula 7] Said linking group can be an aromatic ring carbon seats is coupled in hydrogen or deuterium. According to Claim 1, said substituent R1 and R2 in the same each other or different from each said formula B hereinafter independently, a substituted or unsubstituted aryl characterized in 6 to 24 carbon compounds. According to Claim 1, represented by said [formula 28] to [formula 32], [formula 76] to [formula 79], [formula 81], [formula 91], [formula 92], [formula 96], [formula 103] to [formula 117], [formula 120] to [formula 123], [formula 127] to [formula 129], [formula 134] to [formula 138] selected from the group consisting compounds characterized in that any one can be used. Formula 28>><formula 30><<formula 29 Formula 31>><><<formula 32 formula 76 Formula 77<><><formula 79>formula 78 Formula 91><><formula 81><formula 92 Formula 104><>><<formula 96 formula 103 Formula 105<><formula 106><>formula 107 Formula 108<><><>formula 110 formula 109 Formula 111<><formula 112><>formula 113 Formula 114<><formula 115><>formula 116 Formula 117<><formula 120><>formula 121 Formula 122><><formula 127><formula 123 Formula 128<><formula 129><>formula 134 Formula 135<><formula 136><>formula 137 Formula 138<> Number 1 electrode; said number 1 number 2 electrode opposed to the electrode; and said number 1 and said number 2 electrode interposed between organic layer; and, both formed at said at least one compound selected from number 1 to number 5 anti anti terms including 1, organic light-emitting device. According to Claim 6, said organic layer hole injection layer, hole transporting layer, a hole injection function and hole transport used as functional layer, light emitting layer, an electron transport layer, the metal layer and including at least one characterized in organic light emitting devices. According to Claim 7, said number 1 interposed between the light emitting layer and the organic layer and said number 2 electrode, said light-emitting layer host wherein said dopant, said compounds are characterized host are used as organic light emitting devices. According to Claim 7, each layer selected from said at least one layer formed by deposition process or solution characterized in organic light emitting devices According to Claim 6, said first and second flat panel display device; flexible display device; monochrome or white for plane light source device; and, monochrome or white flexible for illumination device; characterized selected from one device used in organic light emitting devices. Voltage Current density(MA/cm2) Q. E (%) CIEx CIEy Comparison example 1[BH1] 4. 1 10 5. 2 0. 143 0. 150 In the embodiment 1[Formula 1] 3. 5 10 5. 9 0. 135 0. 140 In the embodiment 2[Formula 21] 3. 7 10 7. 7 0. 137 0. 146 In the embodiment 3[Formula 34] 3. 8 10 8. 6 0. 135 0. 146 In the embodiment 4[Formula 52] 3. 3 10 7. 5 0. 140 0. 148 In the embodiment 5[Formula 83] 3. 7 10 7. 2 0. 135 0. 143 In the embodiment 6[Formula 104] 3. 6 10 8 0. 137 0. 141 In the embodiment 7[Formula 115] 3. 8 10 6. 7 0. 132 0. 148
