오조케라이트를 포함하는 자연경화형 조소 조성물

08-02-2019 дата публикации
Номер:
KR0101946216B1
Принадлежит: 김지선, 성백연, 김지선, 성백연
Контакты:
Номер заявки: 01-18-102038340
Дата заявки: 12-11-2018

[1]

The present invention refers to resin compositions including model number taunted action techniques, more specifically the resin component comprising, during welding with hand or method for executing user work or may be, shaped cast certain a rice does not dissolving in water and in the air, plastic number article solidifies as a native curable ridicule composition remain metals and Sn-SB.

[2]

[3]

The present invention refers to various model, character, like the frame number taunted composition as well, the model number can be small number chamber to without clay and clay, solidifies after fixed period having properties, resin component taunted compositions including metals and Sn-SB. Conventional "plastic clay" of the present invention composition called substrate.

[4]

[5]

Used art education of children or, for small clay used in various model number generally deforms the user desired form and number a plastic hand high pressure liquid coolant, as well as retaining a constant time is complete the drying characterized past solidifies in profile. Examples of the clay, the ends of the smell, inorganic material of high specific gravity in the case of adaptation not hereinafter transport and plasticity of smell for thermally processing has, in addition to a drying process of smell in water in the fast time to work and the evaporable symptomatic therapies, such as the surface of the plastic door number point the pin is easily fractured shock absorber member.

[6]

[7]

Said inorganic clay such as starch such as door number point alternative patent registration number 1018158 call number using the weight to have a natural polymer or derivatives thereof to reduce the high pressure liquid coolant artificially clay, hand well without cleaning, surprisingly improved drum forms as lightweight, soft surface compared to inorganic clay clay has been developed. However natural polymers is large relative to the clay and arranged in an irregular but still heavy inorganic clay can, according to the dry clay is preferably cleavable severe shock absorber member and may be different from the billboard in various types and much reduced tendency, and the color of the colored clay during drying and maintains the door pin is point number generator.

[8]

[9]

In order to improve the above-mentioned traditional hollow minuteness nine point of clay door number, polyvinyl alcohol, gelling number and water so as to act as lightweight clay is loose number corrosion disclosed. By using the weight of the lightweight clay can in non-hollow microspheres in charging number of clay is prepared by mixing the clay complexity greatly improve the working drum forms. In addition, water-soluble polymer using polyvinyl alcohol which are excellent in flexibility of clay and, by evaporation of the moisture by the degree to which a surface cracks that negligible small contraction of plastic have the disclosed. However, place hand in use attached to said lightweight clay, which has been modified by easily for thermally processing does not use lead hereinafter, desired form convex notch which maintains the elasticity is too large, that is free from an extended surface smoothness, readily detectable by external force which twig deformation such as durability that the number it became work work not stably remain in memory section.

[10]

[11]

If the polyvinyl alcohol resin and a patent registration number 0978692 the call number point said clay lightweight door, viscosity modifier number, lightweight and fire a lightweight molding material containing disclosure but, amount of moisture and drying speed control suffers deformation of the plastic door from durability was measured number.

[12]

[13]

In addition, a plasticizer such as phthalate and taunted compositions provide number of the existing method, harmful to human body and environment by using borate such as his.

[14]

[15]

특허등록 제1018158호 특허등록 제0978692호

[16]

The present invention refers to excellent workability model (model or model loading space) number number taunted composition intended for the action.

[17]

[18]

In particular, compound number taunted composition includes the first time due to time about more than we shall be, easily cracks Figure after cure and received in the shaft and a door number, a door of the present invention refers to said number to the external number intended for the novel ridicule inflammatory effects.

[19]

[20]

In particular, the present invention refers to number phthalate plasticizer, borate, lead such as human body and environment not environment-friendly material detrimental substances taunted composition intended for the marble number.

[21]

[22]

In particular, the first connector or acidification is passed in long term storage, and smell unpleasant odor is the old door shaft and a bond number, the present invention refers to said door number point number taunted composition intended for the solved.

[23]

[24]

The present invention refers to water 10 - 40% by weight, resin 10 - 40% by weight, 30 - 60% by weight starch starch, CMC 1 - 20 weight % and 5 - 15% by weight including a lock system [khey light natural curable ridicule composition, said resin including polyethylene vinyl acetate and polyvinyl alcohol, natural curable ridicule composition number substrate.

[25]

[26]

In particular, resin of polyethylene vinyl acetate 1 parts by weight of said polyvinyl alcohol is 0. 01 - 0. 1 Parts by weight of a mixture ratio can be used.

[27]

[28]

In particular, said starch is a potato starch, corn starch, starch and wheat coloring agents which can be either.

[29]

[30]

In particular, lock system further mixing by weight of wax, said wax mixture of 5 - 15% by weight can be used as lock system the overall content.

[31]

[32]

In particular, the present invention refers to 1 - 5% by weight greater than can be using it teased.

[33]

[34]

In particular, emulsion number as neutral fatty acid triglyceride, organic acid mono fatty alkyl, glycerin fatty acid ester, a polyoxyethylene fatty acid ester, propylene glycol fatty acid ester, pharmaceuticals and cosmetic emulsion further comprises one or more 1 - 5 weight % for emulsion number can be any number.

[35]

[36]

In particular, 1 - 5% by weight collagen further added for skin moisturizing effect

[37]

2000.

[38]

[39]

Composition of the present invention is a plasticizer such as phthalate and conventional door number taunted was component number, borate or the like without harmful component formed in the human body are firstly disclosed.

[40]

[41]

In addition, composition of the present invention having model number (nozzle) operation time conventional laughed taunted composition cures rapidly fixing point number is symptomatic, model number triarylaminosilane model number point can be small door cracks after the second metal.

[42]

[43]

In addition, by including a cosmetic composition of the present invention [khey light and it teased taunted lock system component, a plurality of skin moisturizing effect can be achieved.

[44]

[45]

In addition, compositions of the present invention further includes a CMC by ridicule, tactile [ccon profit [ccon under profit of the mirror effect can be achieved.

[46]

[47]

1A to 1c in the embodiment 4 is also a process for making photographs of a tweezer shape taunted composition are disclosed. Figure 3 and 4 and in the embodiment 5 comparison example 2 each sample measuring microscope photograph also are disclosed.

[48]

The present invention refers to water 10 - 40% by weight, resin 10 - 40% by weight, 30 - 60% by weight starch, CMC 1 - 20 weight % and 5 - 15% by weight including a lock system [khey light natural curable ridicule composition, said resin including polyethylene vinyl acetate and polyvinyl alcohol, natural curable ridicule composition number substrate.

[49]

[50]

In the present invention main unit is polyethylene vinyl acetate resin, polyvinyl alcohol to force relatively small amount, e.g., polyethylene vinyl acetate 1 parts by weight of polyvinyl alcohol is 0. 01 - 0. 1 Parts by weight can be mixed. Preferably the starch composite resin and said 2 species rather than small, 10 - 40% by weight of the overall composition during the fabricating process, in particular, it can be used as 20 - 30% by weight, properties other than said content can be used as the required value.

[51]

[52]

Water is first mixed with said composite resin before the other components mixed with a bigger, said liver from a mixture state of resin is exposed it is water, water is 10 - 40% by weight of the overall composition in amounts during the fabricating process or middle distance below said composite resin are used preferably.

[53]

[54]

On the other hand, charging body (body) in the present invention by constructing as taunted billboard, characterized by the use of a starch. As well as fat include starch, which can mix both aqueous and oily ink color representation to free disclosed. In the present invention starch is a potato starch, corn starch, sweet potato starch, wheat starch such as starch and closed in and, mixing also pivotably. 30 - 60% By weight of the total composition is preferably total starch, preferably using the aforementioned resin component as the number rather than a small amount.

[55]

[56]

In addition, the present invention refers to CMC (carboxymethyl cellulose) 1 - 20% by weight can be further mixed, adding more composition has been placed in the CMC when equal to or less than.

[57]

[58]

A type of lock system mineral extracted from hydrocarbon wax are disclosed. Lock system for use in the present invention lock system [khey light obtained therefrom can be used for natural as well as lock system can be use. The compositions of the present invention lock system ridicule, semi-transparent resin component during operation a prevents mixes, planetary and water-base ink color representation that allow freedom for mixing hereinafter corn stalk, curing times heated and mixed in accordance with an amount ridicule composition, used for supplying power to the hands of the operator to the clay is without rub off. 5 - 15% By weight of the total composition the entire lock system Cu2Se.

[59]

[60]

In addition to the lock system [khey light other wax comprises further mixing, the mixture of 5 - 15% by weight of the overall composition said lock system [khey light and maintaining water the weight of the wax content is still preferably. Wax include vegetable wax, animal wax, mineral wax and petroleum wax is used as the alkali can be.

[61]

[62]

In addition, selective ingredient, lock system [khey light, 1 - 5% by weight of the starch and the resin mixture for scavenging can be adding it teased. emulsion number function with thin films formed after cure water melted or formed thin films used for the substrate and a rear substrate deformation. In addition, human sebum near component is very excellent skin moisturizing effect have, model number even after the hands of the operator without dry may have small effects.

[63]

[64]

In addition, resin emulsion number neutral fatty acid triglyceride as mixing water, organic acid mono fatty alkyl, glycerin fatty acid ester, a polyoxyethylene fatty acid ester, propylene glycol fatty acid ester, pharmaceuticals and cosmetic emulsion further comprises one or more 1 - 5 weight % for emulsion number can be any number.

[65]

[66]

In addition, the collagen can be 1 - 5% by weight adding increasing skin moisturizing effect.

[67]

[68]

Hereinafter incorporated in the present invention it relates further to a hole of the experiment.

[69]

[70]

Experiment example 1: taunted composition according to of the present invention mixing ratio hardness testing

[71]

[72]

Curing degree so that different respective samples for measuring its amount is the form of a plate into the vacuum zipper bag 1 minutes beyond the periphery of the Royal. It rigid beams irradiated from the object measuring method that measures the general properties as well as a numerical depressed pressure needle sclerometer. As a result below hardness such as numerical mistletoe.

[73]

[74]

ClassificationMixed resinwaterStarch (corn)[Khey light lock systemCMC Hardness (kg/mm2
In the embodiment 120 Kg20 Kg40 Kg6 Kg5 Kg12
In the embodiment 220 Kg20 Kg40 Kg7 Kg5 Kg11
In the embodiment 320 Kg20 Kg40 Kg8 Kg5 Kg8
In the embodiment 420 Kg20 Kg40 Kg9 Kg5 Kg6

[75]

4 ** Said mixed resin is a poly vinyl alcohol: polyethylene vinyl acetate=1:15 by mixing resin

[76]

** Said oxygen measuring hardness measuring 10 minutes after incubation

[77]

[78]

When you said in the embodiment 4 such as making sure that the lower hardness even quality for regenerating a significantly long curing times were. A small number of model number hand is treated in the embodiment 4 taunted composition 1a to 1c chamber also photograph also are disclosed.

[79]

[80]

Experiment example 2: taunted composition with conventional hardness comparison experiments

[81]

[82]

Experiments in example 1 in the embodiment 4 (=slow) on a high curing rate it best comparison example 1 to 3 hardness testing method are taunted prepared by the number by conventional techniques with his compositions. As a result table 2 such as disclosed.

[83]

[84]

ClassificationNumber comparison articleHardness (kg/mm2 )
Comparison example 1 (purchase number article)PVA + EVA + + water gypsum boards 40
Comparison example 2 (purchase number article)PA + BORAX + water + starch57
Comparison example 3 (purchase number article)PVA + water + paper powder62
In the embodiment 4Resin + + + + CMC [khey light starch water lock system6

[85]

Therefore relate to specific content ratio when compared purchase number ** article components that cannot confirm

[86]

[87]

In the embodiment 4 of example 1 to 3 in the embodiment 1 to 3 is not also be the case even if compared compared to numerical hardness selected from, for example made of cured product of the composition of the present invention method compared compared to a former state taunted that his car.

[88]

[89]

Experiment example 3: time according to hardness change measurement experiment

[90]

[91]

Evaluating the degree reference test method KS M 2252 infiltrate through quality change were measured. Experiments in example 3 by measuring a change in a intrusion according to a lapse of time, change the hardness of experiment identifying are disclosed. After intrusion when variation, i.e., hardness when taunted composition into a specific shape to the trellis coding of the shaped product of a post cure is produced during a long time that a shock absorber member easily broken up for big. In addition, after certain number of plastic small too rigid to have taken shape deformation of plastic are made impossible means other.

[92]

[93]

In the embodiment 4 sampleAlso intrusion
24 Hours8
48 Hours8
168 Hours8

[94]

** Measuring conditions: 25 °C, sample 100g, 5 seconds, intrusive depth unit 0. 1 Mm

[95]

[96]

In the embodiment 4 of sample is time 24, 48 time, but also the penetration of 168 hours is room changes, aromatic hydrocarbon polymer cured by keeping quality results in initial appearance without also shown.

[97]

[98]

On the other hand, in the case of comparison example 1 and comparison example 2 below table 4 and 5 showed changes such as intrusion.

[99]

[100]

Comparison example 1 sampleAlso intrusion
24 Hours42
48 Hours16
168 Hours3

[101]

[102]

Comparison example 2 sampleAlso intrusion
24 Hours14
48 Hours6
168 Hours-

[103]

[104]

Comparison example 1 are a sample time after 24, 48 time, maintaining hardness over time is dropped onto the substrate support 168, 168 of comparison example 2 was measured after 48 hours during the measurement sample is also intrusion en break the measuring 168 hours to speak.

[105]

[106]

Experiment example 4: starch types according to functional experiments

[107]

[108]

According to number and characteristic measures the quality article when the type of starch, mixed resin 19 weight %, 19% by weight water, starch 47 weight %, 10 weight % lock system [khey light, is mixed at the ratio of CMC 5% by weight, starch of the type corn starch, potato starch, sweet potato starch, rice starch, flour starch was subject to.

[109]

[110]

5 Requiring special skills inspector name of deceptive-sculpted to a functional test, transparency, flexibility was testing. With each 3 functional test through the lowest gastrodia root when results are evaluated criteria that the top 10 0 gastrodia root when the evaluation of the detected values was calculated averages have paper display panel. The result thereof is below such as table 6 his.

[111]

[112]

Classification-piecesTransparencyFlexible
Corn starch8. 73. 38. 2
Potato starch8. 58. 98. 0
Coloring agents8. 72. 18. 1
Rice starch6. 20. 58. 0
Flour5. 20. 88. 0

[113]

[114]

Results of this test-pieces in starch features are soybean was transparency. Corn starch as viewed best arrival but the overall result, just, degradable polymer film transparency in most transmission option. For example, corn starch is a delicate ridicule, transparent number article is needed situation may be degradable polymer film instead of using corn starch according to seasonal storage unit along raw material situation has been that it is starch can be used.

[115]

[116]

Experiment example 5: [khey light and it teased containing mixed diffusion experiments due to lock system

[117]

[118]

The experiment 20 kg in blended resin, water 18 kg, 40 kg corn starch, 9 kg lock system [khey light, CMC 6 kg, it teased additionally to sample (in the embodiment 5) are made of lanolin 3 kg, containing the shortest distance measured microscope to mix materials due to lock system [khey light and it teased degree. On the other hand, the present invention mixed resin 20 kg equipment, water 18 kg, 40 kg corn starch sample (comparison example 4) test for him.

[119]

[120]

Figure 3 and 4 and in the embodiment 5 comparison example 2 also each representing the microscope measuring photograph (magnified 300) as, in the case of the present invention in the embodiment 5 prepared by the number by has been well were much mixing can be identified by electron.

[121]

[122]



[123]

The present invention relates to a naturally curing type modeling composition and, more specifically, relates to a naturally curing type modeling composition including water, starch, CMC, and ozokerite as well as synthetic resin of polyvinyl alcohol and polyethylene vinyl acetate. Thus, the present invention is capable of preventing a model from cracking when being cured.<br>COPYRIGHT KIPO 2019<br>



10 - 40% By weight water, polyethylene vinyl acetate and vinyl alcohol aqueous mixed resin 10 - 40% by weight, 30 - 60% by weight starch, CMC 1 - 20 weight % and 5 - 15% by weight comprising a lock system [khey light, 1 - 5% by weight natural curable ridicule composition further including lanolin or collagen.

According to Claim 1, 1 parts by weight of said polyvinyl alcohol is polyethylene vinyl acetate resin blend 0. 01 - 0. 1 Parts by weight of mixed ratio characterized natural curable ridicule composition.

According to Claim 1, lock system wax further mixing by weight, 5 - 15% by weight mixture of wax lock system [khey light and the overall content characterized in native curable ridicule composition.

According to Claim 1, emulsion number as neutral fatty acid triglyceride, organic acid mono fatty alkyl, glycerin fatty acid ester, a polyoxyethylene fatty acid ester, propylene glycol fatty acid ester, 1 - 5% by weight one or more pharmaceuticals and cosmetic emulsion number number for emulsion characterized in further including a native curable ridicule composition.

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