МЕЗОПОРИСТЫЙ КАТАЛИЗАТОР НА ОСНОВЕ СМЕШАННОГО ОКСИДА, СОДЕРЖАЩИЙ КРЕМНИЙ

Изобретение относится к мезопористым катализаторам для получения бутадиена из этанола. Предложен мезопористый катализатор на основе смешанного оксида, содержащего кремний и по меньшей мере один металл M, выбранный из тантала, ниобия и их смесей, в котором массовое содержание металла M составляет от 0,1 и 20% от массы смешанного оксида, и кремний и металл М связаны ковалентной связью. Предложен также способ получения указанного катализатора и его применение для получения 1,3-бутадиена из этанола. Технический результат – снижение стоимости катализатора при сохранении его эффективности. 3 н. и 10 з.п. ф-лы, 4 табл., 9 пр., 1 ил.

Способ получения фотокатализатора на основе высокопористого наноструктурированного монолитного оксида алюминия, инкрустированного неагломерированными квантовыми точками, и способ синтеза квантовых точек Zn0,5Cd0,5S

Изобретение относится к химической промышленности, медицине, охране окружающей среды и может быть использовано при изготовлении фотокатализаторов для разложения токсичных органических веществ, загрязняющих воду и воздух. Сначала при 130°С готовят смесь прекурсоров Zn и Cd из их ацетатов в присутствии олеиновой кислоты в органическом растворителе. Отдельно при 135°С готовят раствор серы в органическом растворителе в инертной атмосфере. При приготовлении указанных растворов в качестве органического растворителя используют дибензиловый эфир. Затем к смеси прекурсоров Zn и Cd в инертной атмосфере при 280°С последовательно добавляют олеиламин и полученный раствор серы, перемешивают при 260°С, охлаждают, добавляют этанол для образования осадка, который переосаждают и диспергируют в циклогексане. После этого к дисперсии добавляют раствор NiCl2 в этаноле, продувают аргоном и освещают кварцевой лампой при перемешивании. Полученные квантовые точки Zn0,5Cd0,5S, допированные 10 мас.% никеля, осаждают ...

КАТАЛИЗАТОР ПРЕВРАЩЕНИЯ СИНТЕЗ-ГАЗА В СПИРТЫ

РОССИЙСКАЯ ФЕДЕРАЦИЯ (19) RU (11) (13) 2019 131 826 A (51) МПК B01J 23/89 (2006.01) ФЕДЕРАЛЬНАЯ СЛУЖБА ПО ИНТЕЛЛЕКТУАЛЬНОЙ СОБСТВЕННОСТИ (12) ЗАЯВКА НА ИЗОБРЕТЕНИЕ (21)(22) Заявка: 2019131826, 09.03.2018 (71) Заявитель(и): БАСФ СЕ (DE) Приоритет(ы): (30) Конвенционный приоритет: 10.03.2017 EP 17160382.2 (85) Дата начала рассмотрения заявки PCT на национальной фазе: 10.10.2019 (86) Заявка PCT: (87) Публикация заявки PCT: WO 2018/162709 (13.09.2018) R U (54) КАТАЛИЗАТОР ПРЕВРАЩЕНИЯ СИНТЕЗ-ГАЗА В СПИРТЫ (57) Формула изобретения 1. Катализатор превращения синтез-газа, причем указанный катализатор содержит первый каталитический компонент и второй каталитический компонент, где первый каталитический компонент содержит нанесенный на первую пористую оксидную подложку Rh, Mn, щелочной металл M и Fe, и где второй каталитический компонент содержит нанесенный на второй пористый оксидный материал-носитель Cu и переходный металл, отличный от Cu. 2. Катализатор по п. 1, где в первом каталитическом компоненте, молярное соотношение Rh, вычисленного как элементарный Rh, и Mn, вычисленного как элементарный Mn, находится в интервале от 0,1 до 10, предпочтительно в интервале от 1 до 8, более предпочтительно в интервале от 2 до 5; молярное соотношение Rh, вычисленного как элементарный Rh, и Fe, вычисленного как элементарный Fe, находится в интервале от 0,1 до 10, предпочтительно в интервале от 1 до 8, более предпочтительно в интервале от 2 до 5, и молярное соотношение Rh, вычисленного как элементарный Rh, и щелочного металла M, вычисленного как элементарный M, находится в интервале от 0,1 до 5, предпочтительно в интервале от 0,15 до 3, более предпочтительно в интервале от 0,25 до 2,5. 3. Катализатор по п. 1, где щелочной металл M, содержащийся в первом каталитическом компоненте, представляет собой один или более из Na, Li, K, Rb, Cs, Стр.: 1 A 2 0 1 9 1 3 1 8 2 6 A Адрес для переписки: 105064, Москва, а/я 88, "Патентные поверенные Квашнин, Сапельников и партнеры" 2 0 1 9 1 3 1 8 2 6 EP ...

Methanol process

A process is described for the synthesis of methanol comprising the steps of: (i) passing a first synthesis gas mixture comprising a make-up gas through a first synthesis reactor containing a cooled methanol synthesis catalyst to form a first product gas stream, (ii) recovering methanol from the first product gas stream thereby forming a first methanol- depleted gas mixture, (iii) combining the first methanol-depleted gas mixture with a loop recycle gas stream to form a second synthesis gas mixture, (iv) passing the second synthesis gas mixture through a second synthesis reactor containing a cooled methanol synthesis catalyst to form a second product gas stream, (v) recovering methanol from the second product gas stream thereby forming a second methanol-depleted gas mixture, and (vi) using at least part of the second methanol-depleted gas mixture as the loop recycle gas stream, wherein the first synthesis reactor has a higher heat transfer per cubic metre of catalyst than the second synthesis ...

SOLID, HETEROGENEOUS CATALYSTS AND METHODS OF USE

Solid mixed catalysts and methods for use in conversion of triglycerides and free fatty acids to biodiesel are described. A batch or continuous process may be used with the catalysts for transesterification of triglycerides with an alkyl alcohol to produce corresponding mono carboxylic acid esters and glycerol in high yields and purity. Similarly, alkyl and aryl carboxylic acids and free fatty acids are also converted to corresponding alkyl esters. The described catalysts are thermostable, long lasting, and highly active.

CU-BASED CATALYST, ITS PREPARATION PROCESS AND USE THEREOF

The present invention relates to a Cu-based catalyst, a preparation process thereof and its use as the dehydrogenation catalyst in producing a hydroxyketone compound such as acetoin. Said Cu-based catalyst contains copper, at least one auxiliary metal selected from metal of Group IIA, non-noble metal of Group VIII, metal of Group VIB, metal of Group VIIB, metal of Group IIB and lanthanide metal of periodic table of elements, and an alkali metal, and further contains at least one ketone additive selected from a ketone represented by formula (II) and a ketone represented by formula (II'). Said Cu-based catalyst shows a high the acetoin selectivity as the dehydrogenation catalyst for producing acetoin. R1 -C(=O)-CH(OH)-R2 (II) R1 -C(=O)-CH(=O)-R2 (II') In formulae (II) and (II'), each group is defined as in the description.

CATALYST FOR CARBON MONOXIDE CONVERSION AND METHOD OF CARBON MONOXIDE MODIFICATION WITH THE SAME

The invention provides a catalyst for carbon monoxide conversion, comprising from 10 to 90 % by mass of a copper oxide ingredient, from 5 to 50 % by mass of a zinc oxide ingredient and from 10 to 50 % by mass of an aluminum oxide ingredient, and having a specific surface area of from 100 to 300 m2/g, a carbon monoxide adsorption of from 20 to 80 µmol/g, and a copper oxide crystallite diameter of at most 200 angstroms, as a catalyst suitable for carbon monoxide conversion for fully reducing carbon monoxide in the hydrogen gas obtained through reforming of a starting hydrocarbon material, for the purpose of enabling stable long-term operation of a fuel cell which uses hydrogen gas as a fuel and which is frequently and repeatedly started and stopped.

Method for preparing silicon and/or germanium nanowires

The invention relates to a method for preparing a material made of silicon and/or germanium nanowires, comprising the steps of: i) placing a source of silicon and/or a source of germanium in contact with a catalyst comprising a binary metal sulfide or a multinary metal sulfide, said metal(s) being selected from among Sn, In, Bi, Sb, Ga, Ti, Cu, and Zn, by means of which silicon and/or germanium nanowires are obtained, ii) optionally recovering the silicon and/or germanium nanowires obtained in step (i); the catalyst and, optionally, the source of silicon and/or the source of germanium being heated before, during and/or after being placed in contact under temperature and pressure conditions that allow the growth of the silicon and/or germanium nanowires.

Multitubular reactor for liquid phase alcohol dehydrogenation and method for liquid phase alcohol dehydrogenation

The invention relates to a multitubular reactor for dehydrogenation of liquid phase alcohol dehydrogenation and a method of liquid phase alcohol dehydrogenation. Most of the alcohol dehydrogenation reaction is endothermic reaction, the reaction temperature is high and the equilibrium conversion rate is low.

КАТАЛИЗАТОР ДЛЯ СИНТЕЗА АРОМАТИЧЕСКИХ УГЛЕВОДОРОДОВ И СПОСОБ ЕГО ПОЛУЧЕНИЯ

FIELD: chemistry.SUBSTANCE: disclosed is a catalyst for synthesis of aromatic hydrocarbons, a method for production thereof and a method for synthesis of aromatic hydrocarbons directly from synthesis gas using said catalyst. Disclosed catalyst comprises particles of an acidic molecular sieve and particles of coprecipitated zinc oxide-aluminium, in which said particles of coprecipitated zinc oxide-aluminium additionally contain other metals; wherein said other metals include at least one metal selected from the group consisting of zirconium, copper, platinum, palladium and chromium; where said other metals are added to said particles of coprecipitated zinc oxide aluminium for modification by impregnation. Weight ratio of particles of acid molecular sieve to particles of coprecipitated complex zinc-aluminium oxide ranges from 2:1 to 1:2. Acid molecular sieve is an acidic molecular sieve ZSM-5. Particles of the coprecipitated composite zinc-aluminium oxide are obtained by forming an aqueous solution with a salt containing zinc and aluminium, and then co-precipitation of metal ions of the salt containing zinc and aluminium, using an aqueous solution of the precipitating agent to obtain a precipitate, after which said residue is held, washed, dried and calcined. Said metals are added to said particles of coprecipitated zinc oxide aluminium for modification by impregnation. Then, the particles of the coprecipitated zinc-aluminium oxide are mixed with the particles of the acidic molecular sieve ZSM-5.EFFECT: catalyst has relatively high selectivity with respect to aromatic hydrocarbons, particularly BTX, and stable operating characteristics.9 cl, 2 tbl, 27 ex РОССИЙСКАЯ ФЕДЕРАЦИЯ ФЕДЕРАЛЬНАЯ СЛУЖБА ПО ИНТЕЛЛЕКТУАЛЬНОЙ СОБСТВЕННОСТИ (12) (19) RU (11) (13) 2 732 247 C1 (51) МПК B01J 29/06 (2006.01) B01J 21/04 (2006.01) B01J 23/06 (2006.01) B01J 29/40 (2006.01) B01J 37/04 (2006.01) C07C 1/04 (2006.01) C07C 15/00 (2006.01) ОПИСАНИЕ ИЗОБРЕТЕНИЯ К ПАТЕНТУ (52) СПК B01J 29/40 ( ...

ВЫСОКОАКТИВНЫЕ ЧЕТВЕРТИЧНЫЕ МЕТАЛЛИЧЕСКИЕ МАТЕРИАЛЫ, ИСПОЛЬЗУЮЩИЕ СОЕДИНЕНИЯ КОРОТКОЦЕПОЧЕЧНОГО ЧЕТВЕРТИЧНОГО АЛКИЛАММОНИЯ

FIELD: chemistry. SUBSTANCE: invention relates to a mixed transition metal oxide and its use as a catalyst or precursor to a catalyst, such as a catalyst or precursor to a catalyst for the conversion of hydrocarbons or, more specifically, a catalyst or precursor to a hydro-treatment catalyst. The catalyst material is a mixed transition metal oxide having the formula: (M I a ) m (M IIb ) n (M III c ) o (M IV d ) p O e q , where M I is a metal or a mixture of metals selected from Group IB (IUPAC Group 11), Group IIB (IUPAC Group 12), Group VIIB (IUPAC Group 7), Group IIIA (IUPAC Group 13), Group IVA (IUPAC Group 14) and Group IVB (Group 4 IUPAC); M II is a metal or a mixture of metals selected from Group VIII (IUPAC Groups 8, 9, and 10); M III is a metal selected from Group VIB (IUPAC Group 6); M IV is a metal selected from Group VIB (IUPAC Group 6), which is different from M III . EFFECT: catalyst with a higher intrinsic activity per unit mass is obtained. 24 cl, 8 tbl, 8 ex, 2 dwg РОССИЙСКАЯ ФЕДЕРАЦИЯ (19) RU (11) (13) 2 746 318 C1 (51) МПК B01J 23/887 (2006.01) B01J 27/047 (2006.01) B01J 37/03 (2006.01) B01J 37/20 (2006.01) C10G 45/08 (2006.01) C10G 45/50 (2006.01) ФЕДЕРАЛЬНАЯ СЛУЖБА C10G 45/60 (2006.01) ПО ИНТЕЛЛЕКТУАЛЬНОЙ СОБСТВЕННОСТИ C10G 47/04 (2006.01) (12) ОПИСАНИЕ ИЗОБРЕТЕНИЯ К ПАТЕНТУ (52) СПК B01J 23/002 (2020.08); B01J 23/8873 (2020.08); B01J 23/8885 (2020.08); B01J 23/8892 (2020.08); C10G 45/08 (2020.08); C10G 45/50 (2020.08); C10G 45/60 (2020.08); C10G 47/04 (2020.08) (21)(22) Заявка: 2020122466, 20.12.2018 20.12.2018 R U (24) Дата начала отсчета срока действия патента: (72) Автор(ы): ОСМАН, Зара (US), ПАНЬ, Вэй (US) (73) Патентообладатель(и): ЮОП ЛЛК (US) Дата регистрации: 12.04.2021 20.12.2017 US 62/608,450 (45) Опубликовано: 12.04.2021 Бюл. № 11 (85) Дата начала рассмотрения заявки PCT на национальной фазе: 07.07.2020 2 7 4 6 3 1 8 (56) Список документов, цитированных в отчете о поиске: CN 101306374 A, 19.11.2008. WO 2004/073859 A1, 02.09.2004. US ...

GAS CLEAN-UP FOR ALKANE OXIDATIVE DEHYDROGENATION EFFLUENT

The invention relates to a process for the production of an alkene by alkane oxidative dehydrogenation, comprising: (a) subjecting a stream comprising an alkane to oxidative dehydrogenation conditions, comprising contacting the alkane with oxygen in the presence of a catalyst comprising a mixed metal oxide, resulting in a stream comprising alkene, unconverted alkane, water, carbon dioxide, unconverted oxygen, carbon monoxide and optionally an alkyne; (b) removing water from at least part of the stream comprising alkene, unconverted alkane, water, carbon dioxide, unconverted oxygen, carbon monoxide and optionally an alkyne resulting from step (a), resulting in a stream comprising alkene, unconverted alkane, carbon dioxide, unconverted oxygen, carbon monoxide and optionally alkyne; (c) removing unconverted oxygen, carbon monoxide and optionally alkyne from at least part of the stream comprising alkene, unconverted alkane, carbon dioxide, unconverted oxygen, carbon monoxide and optionally alkyne resulting from step (b), wherein carbon monoxide and optionally alkyne are oxidized into carbon dioxide, resulting in a stream comprising alkene, unconverted alkane and carbon dioxide; (d) optionally removing carbon dioxide from at least part of the stream comprising alkene, unconverted alkane and carbon dioxide resulting from step (c), resulting in a stream comprising alkene and unconverted alkane; (e) optionally separating at least part of the stream comprising alkene and unconverted alkane resulting from step (d), into a stream comprising alkene and a stream comprising unconverted alkane; (f) optionally recycling unconverted alkane from at least part of the stream comprising unconverted alkane resulting from step (e), to step (a).

METHOD OF PRODUCING METHANOL

CONVERSION OF ALCOHOLS TO HYDROCARBONS USING A DUAL CATALYST SYSTEM COMPRISING BASIC OXIDE ON MIXED OXIDE OR MESOPOROUS CARRIER AND ETCHED METAL LOADED ZEOLITE CATALYST

METHOD FOR PREPARING METAL COMPLEX CATALYST AND METAL COMPLEX CATALYST PREPARED THEREOF

ZnWO4 photocatalytic material with oxygen vacancy and preparation method thereof

The invention belongs to the field of novel photocatalytic materials, and particularly relates to a ZnWO4 photocatalytic material containing oxygen vacancy. According to the material, absorption exists in a near infrared region of an ultraviolet-visible light diffuse reflection spectrum, wherein the wavelength range of the near infrared region is 780-2500 nm. The invention further relates to a preparation method of the ZnWO4 photocatalytic material containing oxygen vacancy. Na2WO4 and soluble zinc salt are used as raw materials, ZnWO4 crystals are formed through a hydrothermal crystallization reaction and then roasted in the presence of hydrogen so as to achieve partial reduction of ZnWO4, and then the ZnWO4 photocatalytic material containing oxygen vacancy is obtained.

Methanol process

A process is described for the synthesis of methanol comprising the steps of: (i) passing a first synthesis gas mixture comprising a make-up gas through a first synthesis reactor containing a cooled methanol synthesis catalyst to form a first product gas stream, (ii) recovering methanol from the first product gas stream thereby forming a first methanol-depleted gas mixture, (iii) combining the first methanol-depleted gas mixture with a loop recycle gas stream to form a second synthesis gas mixture, (iv) passing the second synthesis gas mixture through a second synthesis reactor containing a cooled methanol synthesis catalyst to form a second product gas stream, (v) recovering methanol from the second product gas stream thereby forming a second methanol-depleted gas mixture, and (vi) using at least part of the second methanol-depleted gas mixture as the loop recycle gas stream, wherein the first synthesis reactor has a higher heat transfer per cubic meter of catalyst than the second synthesis ...

Hybrid catalysts comprising a mixed metal oxide component for production of C2 and C3 hydrocarbons

A hybrid catalyst including a metal oxide catalyst component comprising chromium, zinc, and at least one additional metal selected from the group consisting of iron and manganese, and a microporous catalyst component that is a molecular sieve having 8-MR pore openings. The at least one additional metal is present in an amount from 5.0 at % to 20.0 at %.

ВЫСОКОАКТИВНЫЕ ЧЕТВЕРТИЧНЫЕ МЕТАЛЛИЧЕСКИЕ МАТЕРИАЛЫ, ИСПОЛЬЗУЮЩИЕ СОЕДИНЕНИЯ ГАЛОГЕНИДА КОРОТКОЦЕПОЧЕЧНОГО ЧЕТВЕРТИЧНОГО АЛКИЛАММОНИЯ

FIELD: chemistry. SUBSTANCE: developed is a highly active trimetallic material containing mixed transition metal oxide and a method for production thereof. The material can be subjected to sulphidation producing metal sulphides used as a catalyst in a method for conversion, e.g., in hydrotreatment. Hydrotreatment can include hydrodenitrification, hydrodesulphurisation, hydrodemetallisation, hydrodesilication, hydrodearomatisation, hydroisomerisation, hydrorefining, hydrogenation purification, and hydrocracking. The material for producing a catalyst, containing a mixed transition metal oxide with the formula: (M I a ) m (M II b ) n (M III c ) o (M IV d ) p O e q , wherein M I constitutes a metal or mixture of metals selected from group IB (group 11 according to IUPAC), group IIB (group 12 according to IUPAC), group VIIB (group 7 according to IUPAC) and group IVB (group 4 according to IUPAC); M II constitutes a metal or mixture of metals selected from group VIII (groups 8, 9 and 10 according to IUPAC); M III constitutes a metal selected from group VIB (group 6 according to IUPAC); M IV constitutes a metal selected from group VIB (group 6 according to IUPAC), different from M III ; a, b, c, d and e constitute the valence state of M I , M II , M III , M IV , and O; m, n, o, p and q constitute the molar ratio of M I , M II , M III , M IV , and O, wherein m / (m + n) > 0 and m / (m + n) ≤ 1, wherein (m + n) / (o + p) ranges from 1/10 to 10/1, wherein o/p > 0 and 0 ≤ p/o ≤ 100, wherein q is greater than 0, and a, b, c, d, e, m, n, o, p and q satisfy the equation: a × m + b × n + c × o + d × p + e × q = 0, wherein the mixed transition metal oxide is characterised by an x-ray diffractogram containing a broad peak between the values of 2θ equal to 55° and 58°, with a full width at the half maximum level greater than 3° and at least one of the following: one or more sharp peaks between the values of 2θ equal to 5° and 11.5°, with a full width at the half maximum level ...

Kohlenmonoxid-selektive Oxidationskatalysatoren

Es können Partikel aus Mischoxiden von Cer, Zirkonium und Kupfer (CeZrCuOx) als Katalysatoren zubereitet und verwendet werden, um bevorzugt die Oxidation von CO in Abgasströmen zu katalysieren, die CO und NH3 enthalten. In einer Anwendung kann dieser CeZrCuOx-Katalysator in Kombination mit einem motornahen PGM-Katalysator, der die Bildung von NH3 in dem Abgas während eines kraftstoffreichen Betriebes begünstigt, und zumindest einem motorfernen NH3-SCR-Katalysator verwendet werden, der die Reduktion von NOx in dem Abgasstrom während eines kraftstoffarmen Betriebes mithilfe von NH3 als ein Reduktionsmittel katalysiert. Während eines kraftstoffreichen Motorbetriebes kann der Abgasstrom unterstromig des PGM-Katalysators mit Sauerstoff dotiert werden und in Kontakt mit Partikeln des CeZrCuOx-Katalysators geleitet werden, sodass das restliche CO in dem Abgas ohne Oxidation oder eine andere Umwandlung des NH3 zu CO2 oxidiert werden kann.

Catalyst for synthesizing aromatic hydrocarbons and preparation method thereof

A catalyst for synthesizing aromatic hydrocarbons, a preparation method therefor, and a method for synthesizing aromatic hydrocarbons by using the catalyst. The catalyst comprises acidic molecular sieve particles and zinc-aluminum composite particles. The catalyst has relatively high selectivity to aromatic hydrocarbons, particularly BTX, stable performance, and a long single-pass life.

Methanol process

A process is described for the synthesis of methanol comprising the steps of: (i) passing a first synthesis gas mixture comprising a make-up gas through a first synthesis reactor containing a cooled methanol synthesis catalyst to form a first product gas stream, (ii) recovering methanol from the first product gas stream thereby forming a first methanol- depleted gas mixture, (iii) combining the first methanol-depleted gas mixture with a loop recycle gas stream to form a second synthesis gas mixture, (iv) passing the second synthesis gas mixture through a second synthesis reactor containing a cooled methanol synthesis catalyst to form a second product gas stream, (v) recovering methanol from the second product gas stream thereby forming a second methanol-depleted gas mixture, and (vi) using at least part of the second methanol-depleted gas mixture as the loop recycle gas stream, wherein the first synthesis reactor has a higher heat transfer per cubic metre of catalyst than the second synthesis ...

A CATALYST FOR CONVERTING SYNTHESIS GAS TO ALCOHOLS

A catalyst for converting a synthesis gas, said catalyst comprising a first catalyst component and a second catalyst component, wherein the first catalyst component comprises, supported on a first porous oxidic substrate, Rh, Mn, an alkali metal M and Fe, and wherein the second catalyst component comprises, supported on a second porous oxidic support material, Cu and a transition metal other than Cu.

METHOD FOR PREPARING CARBON-SUPPORTED PLATINUM-TRANSITION METAL ALLOY NANOPARTICLE CATALYST

Disclosed is a method for preparing a carbon-supported platinum-transition metal alloy nanoparticle catalyst using a stabilizer. According to the method, the transition metal on the nanoparticle surface and the stabilizer are simultaneously removed by treatment with acetic acid. Therefore, the method enables the preparation of a carbon-supported platinum-transition metal alloy nanoparticle catalyst in a simple and environmentally friendly manner compared to conventional methods. The carbon-supported platinum-transition metal alloy nanoparticle catalyst can be applied as a high-performance, highly durable fuel cell catalyst.

Patent RU2018105073A3

ВУ“? 2018105073`” АЗ Дата публикации: 31.12.2019 Форма № 18 ИЗПМ-2011 Федеральная служба по интеллектуальной собственности Федеральное государственное бюджетное учреждение ж 5 «Федеральный институт промышленной собственности» (ФИПС) ОТЧЕТ О ПОИСКЕ 1. . ИДЕНТИФИКАЦИЯ ЗАЯВКИ Регистрационный номер Дата подачи 2018105073/04(007702) 05.07.2016 РСТ/ЕР2016/065821 05.07.2016 Приоритет установлен по дате: [ ] подачи заявки [ ] поступления дополнительных материалов от к ранее поданной заявке № [ ] приоритета по первоначальной заявке № из которой данная заявка выделена [ ] подачи первоначальной заявки № из которой данная заявка выделена [ ] подачи ранее поданной заявки № [Х] подачи первой(ых) заявки(ок) в государстве-участнике Парижской конвенции (31) Номер первой(ых) заявки(ок) (32) Дата подачи первой(ых) заявки(ок) (33) Код страны 1. 1556664 13.07.2015 ЕК Название изобретения (полезной модели): [Х] - как заявлено; [ ] - уточненное (см. Примечания) МЕЗОПОРИСТЫЙ КАТАЛИЗАТОР НА ОСНОВЕ СМЕШАННОГО ОКСИДА, СОДЕРЖАЩИЙ КРЕМНИЙ Заявитель: ИФП ЭНЕРЖИ НУВЕЛЛЬ, ЕК, КОМПАНИ ЖЕНЕРАЛЬ ДЕЗ ЭТАБЛИССМАН МИШЛЕН, ЕК 2. ЕДИНСТВО ИЗОБРЕТЕНИЯ [Х] соблюдено [ ] не соблюдено. Пояснения: см. Примечания 3. ФОРМУЛА ИЗОБРЕТЕНИЯ: [Х] приняты во внимание все пункты (см. П см. Примечания [ ] приняты во внимание следующие пункты: р [ ] принята во внимание измененная формула изобретения (см. Примечания) 4. КЛАССИФИКАЦИЯ ОБЪЕКТА ИЗОБРЕТЕНИЯ (ПОЛЕЗНОЙ МОДЕЛИ) (Указываются индексы МПК и индикатор текущей версии) ВО1./ 37/03 (2006.01) ВО1. 37/08 (2006.01) ВО1.] 21/08 (2006.01) ВО1.] 23/20 (2006.01) С07С 1/20 (2006.01) 5. ОБЛАСТЬ ПОИСКА 5.1 Проверенный минимум документации РСТ (указывается индексами МПК) ВО11 37/03, ВО13 37/08, ВО11 21/08, ВО11 23/20, С07С 1/20 5.2 Другая проверенная документация в той мере, в какой она включена в поисковые подборки: 5.3 Электронные базы данных, использованные при поиске (название базы, и если, возможно, поисковые термины): Езрасепе, Соозе, РаЗеагсв, ЗСОРИЗ$, ОЗРТО, Уапдех, БД ...

CATALYST AND METHOD FOR CONVERTING CARBON-CONTAINING STREAM TO C2 TO C5 PARAFFINS USING IT

A process for preparing C2 to C5 paraffins includes introducing a feed stream comprising hydrogen gas and a carbon-containing gas into a reaction zone of a reactor, and converting the feed stream into a product stream comprising C2 to C5 paraffins in the reaction zone in the presence of a hybrid catalyst. The hybrid catalyst includes a metal oxide catalyst component and a microporous catalyst component. The metal oxide catalyst component satisfies: an atomic ratio of Cu/Zn from 0.01 to 3.00; an atomic ratio of Cr/Zn from 0.01 to 1.50; and percentage of (A1 + Cr) from greater than 0.0 at% to 50.0 at% based on a total amount of metal in the metal oxide catalyst component.

PROCESS FOR PRODUCING CHLOROTRIFLUOROETHYLENE

The present invention relates, at least in part, to a process for making chlorotrifluoroethylene (CFO-1113) from 1,2-dichloro-1,1,2-trifluoroethane (HCFC-123a). In certain aspects, the process includes dehydrochlorinating 1,2-dichloro-1,1,2-trifluoroethane (HCFC-123a) in the presence of a catalyst selected from the group consisting of (i) one or more metal halides; (ii) one or more halogenated metal oxides; (iii) one or more zero-valent metals or metal alloys; (iv) combinations thereof.

METHANOL PROCESS

A process is described for the synthesis of methanol comprising the steps of: (i) passing a first synthesis gas mixture comprising a make-up gas through a first synthesis reactor containing a cooled methanol synthesis catalyst to form a first product gas stream, (ii) recovering methanol from the first product gas stream thereby forming a first methanol- depleted gas mixture, (iii) combining the first methanol-depleted gas mixture with a loop recycle gas stream to form a second synthesis gas mixture, (iv) passing the second synthesis gas mixture through a second synthesis reactor containing a cooled methanol synthesis catalyst to form a second product gas stream, (v) recovering methanol from the second product gas stream thereby forming a second methanol-depleted gas mixture, and (vi) using at least part of the second methanol-depleted gas mixture as the loop recycle gas stream, wherein the first synthesis reactor has a higher heat transfer per cubic metre of catalyst than the second synthesis reactor, none of the loop recycle gas stream is fed to the first synthesis gas mixture and the recycle ratio of the loop recycle gas stream to form the second synthesis gas mixture is in the range 1.1 :1 to 6:1.

MESOPOROUS MIXED OXIDE CATALYST COMPRISING SILICON

CATALYST FOR CARBON MONOXIDE CONVERSION AND METHOD OF CARBON MONOXIDE MODIFICATION WITH THE SAME

본 발명은 수소 가스를 연료로 하는 연료 전지에 있어서, 빈번하게 기동·정지를 반복하는 연료 전지를 안정적으로 장기간 운전 가능하게 하기 때문에, 원료 탄화수소의 개질로 얻어지는 수소 가스 중의 일산화탄소를 충분히 저하시키는 일산화탄소 전환 반응에 적합한 촉매로서, 산화구리 성분이 10 내지 90 질량％, 산화아연 성분이 5 내지 50 질량％, 및 산화알루미늄 성분이 10 내지 50 질량％이고, 비표면적이 100 내지 300 ㎡/g, 일산화탄소 흡착량이 20 내지 80 μmol/g, 산화구리 결정자 직경이 200 Å 이하인 일산화탄소 전환용 촉매를 제공한다. The present invention relates to a fuel cell using hydrogen gas as a fuel and a fuel cell which repeatedly starts and stops frequently so that it can stably operate for a long period of time so that the carbon monoxide conversion A catalyst suitable for the reaction is a catalyst having a copper oxide content of 10 to 90 mass%, a zinc oxide content of 5 to 50 mass% and an aluminum oxide content of 10 to 50 mass%, a specific surface area of 100 to 300 m2 / g, Of 20 to 80 占 퐉 ol / g and a copper oxide crystallite diameter of 200 Å or less. 일산화탄소 전환용 촉매, 산화구리, 산화아연, 산화알루미늄, 홍아연광  A catalyst for converting carbon monoxide, copper oxide, zinc oxide, aluminum oxide,

GOLD-BASED CATALYST FOR OXIDATIVE ESTERIFICATION OF ALDEHYDES TO CARBOXYLIC ACID ESTERS

Gold-based catalyst for oxidative esterification of aldehydes to carboxylic acid esters The present invention relates to novel catalysts for oxidative esterification, by means of which, for example, (meth)acrolein can be converted to methyl (meth)acryiate. The catalysts of the invention are especially notable for high mechanical and chemical stability even over very long periods. This especially relates to an improvement in the catalyst service life, activity and selectivity over prior art 10 catalysts which lose activity and/or selectivity relatively quickly in continuous operation in media having even a small water content. (No drawing to be published) ...

Process of preparing catalyst; platinum-tin on zinc aluminate-calcium aluminate-zeolite catalyst for selective light alkane dehydrogenation

Disclosed are supported platinum-tin (Pt—Sn) based catalysts and methods of their use in selective light alkane dehydrogenation to corresponding alkenes and preparation. The supported catalysts contain a support of blended zeolite, in particular SAPO-34, zinc aluminate compound, and calcium aluminate, impregnated with Pt and Sn metal and a promoter that includes an alkali metal or compound thereof, an alkaline earth metal or compound thereof, or any combination thereof.

HIGHLY ACTIVE QUATERNARY METALLIC MATERIALS USING SHORT-CHAIN ALKYL QUATERNARY AMMONIUM COMPOUNDS

A highly active quaternary mixed transition metal oxide material has been developed. The material may be sulfided to generate metal sulfides which are used as catalyst in a conversion process such as hydroprocessing. The hydroprocessing may include hydrodenitrification, hydrodesulfurization, hydrodemetallation, hydrodesilication, hydrodearomatization, hydroisomerization, hydrotreating, hydrofining, and hydrocracking.

Method for preparing a carbon-supported, platinum-transition metal alloy nanoparticle fuel cell catalyst

Disclosed is a method for preparing a carbon-supported platinum-transition metal alloy nanoparticle catalyst using a stabilizer. According to the method, the transition metal on the nanoparticle surface and the stabilizer are simultaneously removed by treatment with acetic acid. Therefore, the method enables the preparation of a carbon-supported platinum-transition metal alloy nanoparticle catalyst in a simple and environmentally friendly manner compared to conventional methods. The carbon-supported platinum-transition metal alloy nanoparticle catalyst can be applied as a high-performance, highly durable fuel cell catalyst.

CONVERSION OF ALCOHOLS TO HYDROCARBONS USING A DUAL CATALYST SYSTEM COMPRISING BASIC OXIDE ON MIXED OXIDE OR MESOPOROUS CARRIER AND ETCHED METAL LOADED ZEOLITE CATALYST

A method for converting an alcohol to hydrocarbons comprises two serially placed catalysts. The fraction of aromatics is reduced to desired levels. The method comprises: a) contacting the alcohol with a first catalyst on a carrier, said carrier is selected from a mixed oxide and a mesoporous carrier, said first catalyst comprises at least one basic oxide and optionally at least one selected from the group consisting of metals and metal oxides, then b) contacting the resulting mixture from step a) with a second catalyst wherein said second catalyst is an etched metal loaded zeolite catalyst wherein the etched metal loaded zeolite catalyst is manufactured with a method comprising etching with subsequent loading of metal onto the catalyst, wherein the metal is in the form of nanoparticles, and wherein at least two different metals are loaded onto the etched zeolite catalyst. The hydrocarbons are recovered and used for instance for fuel including gasoline, kerosene, diesel, and jet propellant ...

HYDROGENOLYSIS CATALYSTS WITH HIGH ACID TOLERANCE

PROCESS FOR THE PREPARATION OF SILICON NANOWIRES AND/OR GERMANIUM

L'invention concerne un procédé de préparation d'un matériau à base de nanofils de silicium et/ou de germanium, comprenant les étapes de : i) mise en contact d'une source de silicium et/ou d'une source de germanium avec un catalyseur comprenant un sulfure de métal binaire ou un sulfure de métaux multinaire, le ou lesdits métaux étant choisis parmi Sn, In, Bi, Sb, Ga, Ti, Cu, et Zn, ce par quoi on obtient des nanofils de silicium et/ou de germanium, ii) éventuellement récupération des nanofils de silicium et/ou de germanium obtenus à l'étape (i) ; le catalyseur, et éventuellement la source de silicium et/ou la source de germanium, étant chauffé avant, pendant, et/ou après la mise en contact dans des conditions de température et de pression permettant la croissance des nanofils de silicium et/ou de germanium. The invention relates to a method for preparing a material based on silicon nanowires and / or germanium, comprising the steps of: i) contacting a source of silicon and / or a source of germanium with a catalyst comprising a binary metal sulfide or a multinary metal sulfide, the one or more metals being selected from Sn, In, Bi, Sb, Ga, Ti, Cu, and Zn, whereby silicon nanowires and / or or of germanium, ii) optionally recovery of the silicon and / or germanium nanowires obtained in step (i); the catalyst, and optionally the silicon source and / or the germanium source, being heated before, during, and / or after contacting under conditions of temperature and pressure permitting the growth of silicon nanowires and / or germanium.

Production method of transparent coating liquid for photocatalysis

METHOD USING METAL-ORGANIC FRAMEWORK COMPOSITIONS

Embodiments of the present disclosure include a metal-organic framework (MOF) composition comprising one or more metal ions, a plurality of organic ligands, and a solvent, wherein the one or more metal ions associate with the plurality of organic ligands sufficient to form a MOF with kag topology. Embodiments of the present disclosure further include a method of making a MOF composition comprising contacting one or more metal ions with a plurality of organic ligands in the presence of a solvent, sufficient to form a MOF with kag topology, wherein the solvent comprises water only. Embodiments of the present disclosure also describe a method of capturing chemical species from a fluid composition comprising contacting a MOF composition with kag topology and pore size of about 3.4 Å to 4.8 Å with a fluid composition comprising two or more chemical species and capturing one or more captured chemical species from the fluid composition.

Patent RU2019131826A3

ВУ“? 2019131826” АЗ Дата публикации: 18.06.2021 Форма № 18 ИЗПМ-2011 Федеральная служба по интеллектуальной собственности Федеральное государственное бюджетное учреждение ж 5 «Федеральный институт промышленной собственности» (ФИПС) ОТЧЕТ О ПОИСКЕ 1. . ИДЕНТИФИКАЦИЯ ЗАЯВКИ Регистрационный номер Дата подачи 2019131826/04(062624) 09.03.2018 РСТ/ЕР2018/055898 09.03.2018 Приоритет установлен по дате: [ ] подачи заявки [ ] поступления дополнительных материалов от к ранее поданной заявке № [ ] приоритета по первоначальной заявке № из которой данная заявка выделена [ ] подачи первоначальной заявки № из которой данная заявка выделена [ ] подачи ранее поданной заявки № [Х] подачи первой(ых) заявки(ок) в государстве-участнике Парижской конвенции (31) Номер первой(ых) заявки(ок) (32) Дата подачи первой(ых) заявки(ок) (33) Код страны 1. 17160382.2 10.03.2017 ЕР Название изобретения (полезной модели): [Х] - как заявлено; [ ] - уточненное (см. Примечания) КАТАЛИЗАТОР ПРЕВРАЩЕНИЯ СИНТЕЗ-ГАЗА В СПИРТЫ Заявитель: БАСФ СЕ, РЕ 2. ЕДИНСТВО ИЗОБРЕТЕНИЯ [Х] соблюдено [ ] не соблюдено. Пояснения: см. Примечания 3. ФОРМУЛА ИЗОБРЕТЕНИЯ: [Х] приняты во внимание все пункты (см. Примечания) [ ] приняты во внимание следующие пункты: [ ] принята во внимание измененная формула изобретения (см. Примечания) 4. КЛАССИФИКАЦИЯ ОБЪЕКТА ИЗОБРЕТЕНИЯ (ПОЛЕЗНОЙ МОДЕЛИ) (Указываются индексы МПК и индикатор текущей версии) ВО1. 23/859 (2006.01) ВО1.] 21/08 (2006.01) ВО1.] 37/02 (2006.01) ВО1.] 23/58 (2006.01) В01. 37/18 (2006.01) С07С 27/06 (2006.01) ВО1. 23/656 (2006.01) ВО1.] 37/08 (2006.01) С07С 29/156 (2006.01) 5. ОБЛАСТЬ ПОИСКА 5.1 Проверенный минимум документации РСТ (указывается индексами МПК) ВО1} 23/89, ВО13 21/08, ВО14 37/02, ВО11 23/58, ВО13 37/18, СО7С 27/06, ВО11 23/656, ВО13 37/08, СО7С 29/158 5.2 Другая проверенная документация в той мере, в какой она включена в поисковые подборки: 5.3 Электронные базы данных, использованные при поиске (название базы, и если, возможно, поисковые термины): ...

МЕЗОПОРИСТЫЙ КАТАЛИЗАТОР НА ОСНОВЕ СМЕШАННОГО ОКСИДА, СОДЕРЖАЩИЙ КРЕМНИЙ

РОССИЙСКАЯ ФЕДЕРАЦИЯ (19) RU (11) (13) 2018 105 073 A (51) МПК B01J 37/03 (2006.01) ФЕДЕРАЛЬНАЯ СЛУЖБА ПО ИНТЕЛЛЕКТУАЛЬНОЙ СОБСТВЕННОСТИ (12) ЗАЯВКА НА ИЗОБРЕТЕНИЕ (21)(22) Заявка: 2018105073, 05.07.2016 (71) Заявитель(и): ИФП ЭНЕРЖИ НУВЕЛЛЬ (FR), КОМПАНИ ЖЕНЕРАЛЬ ДЕЗ ЭТАБЛИССМАН МИШЛЕН (FR) Приоритет(ы): (30) Конвенционный приоритет: 13.07.2015 FR 1556664 (85) Дата начала рассмотрения заявки PCT на национальной фазе: 13.02.2018 (72) Автор(ы): КАДРАН Николя (FR), ШОМОННО Александра (FR), ЛАМБЕР Арнольд (FR) R U (43) Дата публикации заявки: 14.08.2019 Бюл. № 23 (86) Заявка PCT: (87) Публикация заявки PCT: WO 2017/009105 (19.01.2017) A Адрес для переписки: 129090, Москва, ул. Б. Спасская, 25, стр. 3, ООО "Юридическая фирма Городисский и Партнеры" R U (57) Формула изобретения 1. Мезопористый катализатор на основе смешанного оксида, содержащий кремний и по меньшей мере один металл M, выбранный из группы, состоящей из элементов групп 4 и 5 периодической системы элементов, и их смесей, причем массовое содержание металла M составляет от 0,1% до 20% от массы смешанного оксида, и указанный смешанный оксид получен в результате соединения атомов кислорода с по меньшей мере элементом кремний и элементом M. 2. Катализатор по п. 1, причем указанный металл M выбран из группы, состоящей из тантала, ниобия, циркония и их смесей. 3. Катализатор по одному из пп. 1, 2, содержащий металл M', причем указанный металл M' выбран из группы, состоящей из элементов групп 11 и 12 периодической системы элементов, и их смесей, и массовое содержание металла M' составляет от 0,1% до 20% от массы смешанного оксида. 4. Катализатор по п. 3, причем указанный металл M' выбран из группы, состоящей из серебра, меди, цинка и их смесей. 5. Катализатор по одному из пп. 1-4, причем указанный смешанный оксид является мезоструктурированным. 6. Катализатор по одному из пп. 1-5, причем смешанный оксид имеет удельную Стр.: 1 A 2 0 1 8 1 0 5 0 7 3 (54) МЕЗОПОРИСТЫЙ КАТАЛИЗАТОР НА ОСНОВЕ СМЕШАННОГО ОКСИДА, ...

Method

A method for activating a catalyst comprising: optionally drying the catalyst at a temperature of from 100 °C to 400 °C; treating the catalyst with a composition comprising HF at a temperature of from 100 °C to about 500 °C; treating the catalyst with a composition comprising an oxidant and optionally HF at a temperature of from about 100 °C to about 500 °C. The oxidant may be air, oxygen, chlorine, chlorine monofluoride or nitrogen trifluoride. The catalyst may be chromia and may also comprise zinc or zinc oxide. A method for activating a catalyst comprising: optionally drying the catalyst at a temperature of from 100 °C to 400 °C; treating the catalyst with a composition comprising HF at a temperature of from 500 °C to about 700 °C. The use of said activated catalyst in a fluorination or hydrofluorination reaction which may be performed on a halogenated hydrocarbon. The halogenated hydrocarbon may be 2-chloro-3,3,3-trifluoropropene (1233xf). A process for preparing a fluorinated hydrocarbon ...

CATALYST FOR CARBON MONOXIDE CONVERSION AND METHOD OF CARBONMONOXIDE MODIFICATION WITH THE SAME

A catalyst for the conversion of carbon monoxide which is suitable for a carbon monoxide conversion reaction in a fuel cell employing hydrogen gas as a fuel. For enabling the fuel cell in which start and stop are frequently r epeated to be stably operated for long, the catalyst can be used to sufficie ntly diminish the carbon monoxide contained in the hydrogen gas obtained by the reforming of a feed hydrocarbon. The catalyst comprises 10-90 mass% copp er oxide ingredient, 5-50 mass% zinc oxide ingredient, and 10-50 mass% alumi num oxide ingredient and has a specific surface area of 100-300 m2/g, carbon monoxide adsorption of 20-80 µmol/g, and copper oxide crystallite diameter of 200 Å or smaller.

Preparation method of carbon-supported platinum-transition metal alloy nanoparticle catalyst

Conversion of alcohols to hydrocarbons using a dual catalyst system comprising basic oxide on mixed oxide or mesoporous carrier and etched metal loaded zeolite catalyst

A method for converting an alcohol to hydrocarbons comprises two serially placed catalysts. The fraction of aromatics is reduced to desired levels. The method comprises: a) contacting the alcohol with a first catalyst on a carrier, said carrier is selected from a mixed oxide and a mesoporous carrier, said first catalyst comprises at least one basic oxide and optionally at least one selected from the group consisting of metals and metal oxides, then b) contacting the resulting mixture from step a) with a second catalyst wherein said second catalyst is an etched metal loaded zeolite catalyst wherein the etched metal loaded zeolite catalyst is manufactured with a method comprising etching with subsequent loading of metal onto the catalyst, wherein the metal is in the form of nanoparticles, and wherein at least two different metals are loaded onto the etched zeolite catalyst. The hydrocarbons are recovered and used for instance for fuel including gasoline, kerosene, diesel, and jet propellant ...

Gas clean-up for alkane oxidative dehydrogenation effluent

The invention relates to a process for the production of an alkene by alkane oxidative dehydrogenation, comprising: (a) subjecting a stream comprising an alkane to oxidative dehydrogenation conditions, comprising contacting the alkane with oxygen in the presence of a catalyst comprising a mixed metal oxide, resulting in a stream comprising alkene, unconverted alkane, water, carbon dioxide, unconverted oxygen, carbon monoxide and optionally an alkyne; (b) removing water from at least part of the stream comprising alkene, unconverted alkane, water, carbon dioxide, unconverted oxygen, carbon monoxide and optionally an alkyne resulting from step (a), resulting in a stream comprising alkene, unconverted alkane, carbon dioxide, unconverted oxygen, carbon monoxide and optionally alkyne; (c) removing unconverted oxygen, carbon monoxide and optionally alkyne from at least part of the stream comprising alkene, unconverted alkane, carbon dioxide, unconverted oxygen, carbon monoxide and optionally ...

Conversion of alcohols to hydrocarbons using a dual catalyst system comprising basic oxide on mixed oxide or mesoporous carrier and etched metal loaded zeolite catalyst

A method for converting an alcohol to hydrocarbons comprises two serially placed catalysts. The fraction of aromatics is reduced to desired levels. The method comprises: a) contacting the alcohol with a first catalyst on a carrier, said carrier is selected from a mixed oxide and a mesoporous carrier, said first catalyst comprises at least one basic oxide and optionally at least one selected from the group consisting of metals and metal oxides, then b) contacting the resulting mixture from step a) with a second catalyst wherein said second catalyst is an etched metal loaded zeolite catalyst wherein the etched metal loaded zeolite catalyst is manufactured with a method comprising etching with subsequent loading of metal onto the catalyst, wherein the metal is in the form of nanoparticles, and wherein at least two different metals are loaded onto the etched zeolite catalyst. The hydrocarbons are recovered and used for instance for fuel including gasoline, kerosene, diesel, and jet propellant ...

Catalyst for synthesizing aromatic hydrocarbons and preparation method thereof

Methanol process

Methanol synthesis process comprises the steps of passing make-up gas through a first synthesis reactor 20; recovering methanol from the formed product stream thereby forming a first methanoldepleted gas mixture; passing a combination of the first methanol-depleted gas mixture and a loop recycle gas through a second synthesis reactor 48; recovering methanol from the formed product stream thereby forming a second methanoldepleted gas mixture; using the second methanol-depleted gas mixture as the loop recycle gas; wherein both reactors contain a cooled methanol synthesis catalyst, the first synthesis reactor has a higher heat transfer per cubic meter of catalyst than the second synthesis reactor, none of the loop recycle gas stream is fed to the first synthesis gas mixture and the recycle ratio of the loop recycle gas stream to form the second synthesis gas mixture is in the range 1.1:1 to 6:1. The reactors are preferably tubular converters.

CATALYST FOR METHANOL SYNTHESIS AND PREPARATION METHOD THEREOF

The invention relates to a catalyst for methanol synthesis, which comprises the following components by mass fraction, 24% to 56% Cu, 16% to 40% Zn, 4.3% to 10.8% Al, and 0.5% to 3% halogen. The preparation method of catalyst proposed in the invention enables the formation of a strong interaction between the halogen and the active component, which structurally ensures high activity and high stability, and on this basis, it can significantly reduce the content of carbonyl compounds in methanol products, so that the content of impurity carbonyl compounds in crude methanol is less than 30ppm, which is much lower than the limit requirement for this impurity in MTO-grade methanol feedstock.

NATURAL 1,2-ALKANEDIOLS, COMPOSITIONS HAVING NATURAL 1,2-ALKANEDIOLS AND PROCESSES FOR MAKING THE SAME

A process is incorporated herein for the synthesis of bio-1,2-alkanediols, comprising: providing a bio-alkene having a carbon chain of about 5 to about 20 carbon atoms and a bio-1-alkene regioselectivity of at least about 80%, at least about 92% and/or at least about 95%; and converting the bio-alkene to a bio-1,2-alkanediol having a carbon chain length of about 5 to about 20 carbon atoms. Methods for treating catalysts which may be incorporated in the process for the synthesis of bio-1,2-alkanediols are also included herein. Such bio-1,2-alkanediols are used in compositions and products alone as antimicrobial materials, or with existing bio-compounds and/or antimicrobials, preservatives, alternative preservation systems and/or hurdle technology components. The bio-1,2-alkanediols incorporate a natural and bio-based pathway for antimicrobial effects in various compositions such as cosmetic, pharmaceutical, industrial and household products.

Methanol process

Natural 1,2-alkanediols, compositions having natural 1,2-alkanediols and processes for making the same

A process is incorporated herein for the synthesis of bio-1,2-alkanediols, comprising: providing a bio-alkene having a carbon chain of about 5 to about 20 carbon atoms and a bio-1-alkene regioselectivity of at least about 80%, at least about 92% and/or at least about 95%; and converting the bio-alkene to a bio-1,2-alkanediol having a carbon chain length of about 5 to about 20 carbon atoms. Methods for treating catalysts which may be incorporated in the process for the synthesis of bio-1,2-alkanediols are also included herein. Such bio-1,2-alkanediols are used in compositions and products alone as antimicrobial materials, or with existing bio-compounds and/or antimicrobials, preservatives, alternative preservation systems and/or hurdle technology components. The bio-1,2-alkanediols incorporate a natural and bio-based pathway for antimicrobial effects in various compositions such as cosmetic, pharmaceutical, industrial and household products.

알데하이드의 카르복실산 에스테르로의 산화적 에스테르화를 위한 금-기반 촉매

... 본 발명은 산화적 에스테르화를 위한 신규한 촉매에 관한 것이며, 이를 통해, 예를 들어, (메트)아크롤레인은 메틸 (메트)아크릴레이트로 전환될 수 있다. 본 발명에 따른 촉매는 매우 장기간에 걸친 높은 기계적 및 화학적 안정성을 특징으로 한다. 이는 특히 적은 물 함량을 가지는 매질에서도 연속적 작업시 상대적으로 빠르게 활성 및/또는 선택성을 상실하는 선행 기술로부터의 촉매와 비교하여 촉매의 사용 수명, 활성 및 선택성에서의 개선에 관한 것이다.

HYDROGENOLYSIS CATALYSTS WITH HIGH ACID TOLERANCE

EFFICIENT CATALYST FOR THE CONVERSION OF CO2 TO METHANOL

An efficient catalyst for the synthesis of methanol by catalytic hydrogenation of carbon dioxide is provided. A process for the preparation of the catalyst by self-combustion of a gel and a process for the synthesis of methanol by catalytic hydrogenation of carbon dioxide are also presented. The catalyst has the following formula (Cu)x(ZnO)y(ZrO2)z supported on mesoporous silica.

Gas clean-up for alkane oxidative dehydrogenation effluent

The invention relates to a process for the production of an alkene by alkane oxidative dehydrogenation, comprising: (a) subjecting a stream comprising an alkane to oxidative dehydrogenation conditions, comprising contacting the alkane with oxygen in the presence of a catalyst comprising a mixed metal oxide, resulting in a stream comprising alkene, unconverted alkane, water, carbon dioxide, unconverted oxygen, carbon monoxide and optionally an alkyne; (b) removing water from at least part of the stream comprising alkene, unconverted alkane, water, carbon dioxide, unconverted oxygen, carbon monoxide and optionally an alkyne resulting from step (a), resulting in a stream comprising alkene, unconverted alkane, carbon dioxide, unconverted oxygen, carbon monoxide and optionally alkyne; (c) removing unconverted oxygen, carbon monoxide and optionally alkyne from at least part of the stream comprising alkene, unconverted alkane, carbon dioxide, unconverted oxygen, carbon monoxide and optionally alkyne resulting from step (b), wherein carbon monoxide and optionally alkyne are oxidized into carbon dioxide, resulting in a stream comprising alkene, unconverted alkane and carbon dioxide; (d) optionally removing carbon dioxide from at least part of the stream comprising alkene, unconverted alkane and carbon dioxide resulting from step (c), resulting in a stream comprising alkene and unconverted alkane; (e) optionally separating at least part of the stream comprising alkene and unconverted alkane resulting from step (d), into a stream comprising alkene and a stream comprising unconverted alkane; (f) optionally recycling unconverted alkane from at least part of the stream comprising unconverted alkane resulting from step (e), to step (a).

MESOPOROUS MIXED OXIDE CATALYST COMPRISING SILICON

L'invention concerne un catalyseur oxyde mixte mésoporeux comprenant du silicium et au moins un métal M choisi dans le groupe constitué par les éléments des groupes 4 et 5 du tableau périodique et leurs mélanges, la masse de métal M étant comprise entre 0,1 et 20% de la masse de l'oxyde mixte. The invention relates to a mesoporous mixed oxide catalyst comprising silicon and at least one metal M selected from the group consisting of the elements of groups 4 and 5 of the periodic table and mixtures thereof, the mass of metal M being between 0.1 and 20% of the mass of the mixed oxide.

Metal complex catalysts for selective formation of cyclic carbonates and process for preparing cyclic carbonate using the same

catalisador à base de ouro para esterificação oxidativa de aldeídos a ésteres de ácido carboxílico

Hydrogenolysis catalysts with high acid tolerance

A catalyst includes a mixed metal oxide; an alumina; silica, and calcium, where the mixed metal oxide includes Cu and at least one of Mn, Zn, Ni, or Co. Such catalysts exhibit enhanced tolerance sulfur-containing compounds and free fatty acids.

AN ADDITIVE AND A CATALYST COMPOSITION COMPRISING THE ADDITIVE FOR FCC PROCESS

The present disclosure relates to an additive and a catalyst composition for a catalytic cracking process of vacuum gas oil for preparing cracked run naphtha having reduced liquid olefin content, and increased propylene and butylene yields in the LPG fraction. The process makes use of a catalyst composition which is a mixture of an FCC equilibrated catalyst and an additive comprising a zeolite, phosphorus and a combination of metal promoters. The process is successful in achieving high propylene and butylene yields in the LPG fraction along with a lower liquid olefin content and increased aromatic content with increase in RON unit in the resultant cracked run naphtha, as compared to that achieved using an FCC equilibrated catalyst alone. 1. An additive for a catalyst composition for a fluid catalytic cracking process comprising a zeolite impregnated with phosphorus in the range of 10 wt % to 15wt % with respect to the weight of said zeolite and a mixture of metal promoters comprising zirconium , molybdenum , nickel , cobalt , zinc and gallium , independently in the range of 0.1 wt % to 1.0 wt % with respect to the weight of said zeolite.2. The additive as claimed in claim 1 , wherein said phosphorous in said zeolite is 12 wt % with respect to the weight of said zeolite.3. The additive as claimed in claim 1 , wherein the precursor of phosphorus is at least one phosphorus compound selected from the group consisting of phosphoric acid claim 1 , phosphates claim 1 , phosphorous acid claim 1 , phosphites claim 1 , pyrophosphoric acid claim 1 , pyrophosphates claim 1 , polymeric phosphoric acid claim 1 , polyphosphates claim 1 , metaphosphoric acid and metaphosphates.4. The additive as claimed in claim 1 , wherein the amount of said metal promoters with respect to the weight of said zeolite are:a. 0.5 wt % zirconium;b. 0.5 wt % molybdenum;c. 0.5 wt % nickel;d. 0.5 wt % cobalt;e. 1 wt % zinc; andf. 1 wt % gallium.5. The additive as claimed in claim 1 , wherein the ...

클로로트리플루오로에틸렌 제조방법

... 본 발명은, 적어도 부분적으로, 1,2-디클로로-1,1,2-트리플루오로에탄(HCFC-123a)으로부터 클로로트리플루오로에틸렌(CFO-1113)을 제조하는 방법에 관한 것이다. 어떤 견지에서, 상기 방법은 (i) 하나 이상의 금속 할라이드; (ii) 하나 이상의 할로겐화된 금속 옥사이드; (iii) 하나 이상의 0가 금속 또는 금속 합금; (iv) 이들의 조합으로 이루어진 그룹으로부터 선택되는 촉매의 존재하에서 1,2-디클로로-1,1,2-트리플루오로에탄(HCFC-123a)을 탈염화수소화하는 것을 포함한다.

METHODS FOR GAS PHASE OXIDATIVE DESULPHURIZATION OF HYDROCARBONS USING CUZNAL CATALYSTS PROMOTED WITH VIB METAL OXIDES

Methanol process

FOR CONVERTIR UNA CORRIENT QUE CONTIENE CHBONO EN PARAFINAS C A C Y MÉTO-2 5 DO QUE UTILIZA EL CATALIZADOR

Un proceso para preparar parafinas C₂ a C₅ incluye introducir una corriente de alimentación que comprende gas hidrógeno y un gas que contiene carbono en una zona de reacción de un reactor, y convertir la corriente de alimentación en una corriente de producto que comprende parafinas C₂ a C₅ en la zona de reacción en presencia de un catalizador híbrido. El catalizador híbrido incluye un componente catalizador de óxido metálico y un componente catalizador microporoso. El componente catalizador de óxido metálico satisface: una relación atómica de Cu/Zn de 0,01 a 3,00; una relación atómica de Cr/Zn de 0,01 a 1,50; y un porcentaje de (Al + Cr) de más de 0,0% hasta a 50,0% hasta en función de una cantidad total de metal en el componente catalizador de óxido metálico.

PROCESS FOR PRODUCING CHLOROTRIFLUOROETHYLENE

The present invention relates, at least in part, to a process for making chlorotrifluoroethylene (CFO-1113) from 1,2-dichloro-1,1,2-trifluoroethane (HCFC-123a). In certain aspects, the process includes dehydrochlorinating 1,2-dichloro-1,1,2-trifluoroethane (HCFC-123a) in the presence of a catalyst selected from the group consisting of (i) one or more metal halides; (ii) one or more halogenated metal oxides; (iii) one or more zero-valent metals or metal alloys; (iv) combinations thereof. 1. A process for producing chlorotrifluoroethylene (CFO-1113) comprising:dehydrochlorinating 1,2-dichloro-1,1,2-trifluoroethane (HCFC-123a) in the presence of a catalyst selected from the group consisting of (i) one or more metal halides; (ii) one or more halogenated metal oxides; (iii) one or more zero-valent metals or metal alloys; (iv) combinations thereof to produce a reaction product comprising CFO-1113.2. The process of wherein the conversion of HCFC-123a is at least about 5 wt. %.3. The process of wherein a selectivity to chlorotrifluoroethylene is at least about 70 wt. %.4. The process of wherein said reaction product comprises less than about 10 wt. % of CFO-1112.5. The process of wherein the dehydrochlorinating step is conducted at a temperature greater than about 400° C.6. The process of wherein a substantial portion of the dehydrochlorinating step is carried out at a temperature of from about 480° C. to about 550° C.7. The process of wherein catalyst comprises a mono-valent metal halide claim 1 , a bi-valent metal halide claim 1 , a tri-valent metal halide claim 1 , or a combination thereof.8. The process of wherein catalyst comprises a mono-valent metal halide claim 1 , a bi-valent metal halide or a combination thereof.9. The process of wherein the catalyst comprises at least one metal halide wherein the component metal is selected from the group consisting of Cr claim 1 , Fe claim 1 , Mg claim 1 , Ca claim 1 , Ni claim 1 , Zn claim 1 , Pd claim 1 , Li claim 1 , Na claim ...

PROCESS FOR PRODUCING CHLOROTRIFLUOROETHYLENE

The present invention relates, at least in part, to a process for making chlorotrifluoroethylene (CFO-1113) from 1,2-dichloro-1,1,2-trifluoroethane (HCFC-123a). In certain aspects, the process includes dehydrochlorinating 1,2-dichloro-1,1,2-trifluoroethane (HCFC-123a) in the presence of a catalyst selected from the group consisting of (i) one or more metal halides; (ii) one or more halogenated metal oxides; (iii) one or more zero-valent metals or metal alloys; (iv) combinations thereof.

Catalyst for converting carbon-containing stream to C2 to C5 paraffins and method using the catalyst

A process for preparing C2to C5paraffins includes introducing a feed stream comprising hydrogen gas and a carbon-containing gas into a reaction zone of a reactor, and converting the feed stream into a product stream comprising C2to C5paraffins in the reaction zone in the presence of a hybrid catalyst. The hybrid catalyst includes a metal oxide catalyst component and a microporous catalyst component. The metal oxide catalyst component satisfies: an atomic ratio of Cu/Zn from 0.01 to 3.00; an atomic ratio of Cr/Zn from 0.01 to 1.50; and percentage of (Al+Cr) from greater than 0.0 at % to 50.0 at % based on a total amount of metal in the metal oxide catalyst component.

Verfahren zur selektiven Oxidation von Kohlenmonoxid und Verfahren zum Reinigen eines Abgasstroms eines Verbrennungsmotors

Verfahren zum Oxidieren von Kohlenmonoxid (CO) zu CO2 in einem Gas, welches auch Ammoniak (NH3) und Sauerstoff enthält, wobei sich das Gas bei einer Temperatur in dem Bereich von 200400°C befindet; wobei das Verfahren umfasst, dass: ein Strom des CO-haltigen Gases in Kontakt mit Katalysatorpartikeln geleitet wird, welche Mischoxide von Cer (Ce), Zirkonium (Zr) und Kupfer (Cu) umfassen, wobei das CO-haltige Gas mit den Katalysatorpartikeln für eine Zeit in Kontakt steht, die geeignet ist, um CO ohne eine Oxidation des Ammoniakgehaltes des Gases zu CO2 zu oxidieren.

Method

Methanol process

1,3-부타디엔의 제조방법

... 본 발명은 에탄올로부터 1,3-부타디엔의 제조에 사용되는 신규한 실리카-담지 3성분 금속 (La/Zr/Zn) 촉매의 용도에 관한 것이다. 지르코늄 및 아연을 더 포함하는 촉매 중에서 란탄의 존재는 촉매 수율 및 1,3-부타디엔에 대한 선택성을 증가시킨다.

METHODS FOR GAS PHASE OXIDATIVE DESULPHURIZATION OF HYDROCARBONS USING CuZnAl CATALYSTS PROMOTED WITH GROUP VIB METAL OXIDES

A catalytic composition is disclosed, which exhibits an X-ray amorphous oxide with a spinel formula, and crystals of ZnO, CuO, and at least one Group VIB metal oxide, and preferably, at least one acidic oxide of B, P. or Si, as well. The composition is useful in oxidative processes for removing sulfur from gaseous hydrocarbons.

Gas clean-up for alkane oxidative dehydrogenation effluent

The invention relates to a process for the production of an alkene by alkane oxidative dehydrogenation, comprising: (a) subjecting a stream comprising an alkane to oxidative dehydrogenation conditions, comprising contacting the alkane with oxygen in the presence of a catalyst comprising a mixed metal oxide, resulting in a stream comprising alkene, unconverted alkane, water, carbon dioxide, unconverted oxygen, carbon monoxide and optionally an alkyne; (b) removing water from at least part of the stream comprising alkene, unconverted alkane, water, carbon dioxide, unconverted oxygen, carbon monoxide and optionally an alkyne resulting from step (a), resulting in a stream comprising alkene, unconverted alkane, carbon dioxide, unconverted oxygen, carbon monoxide and optionally alkyne; (c) removing unconverted oxygen, carbon monoxide and optionally alkyne from at least part of the stream comprising alkene, unconverted alkane, carbon dioxide, unconverted oxygen, carbon monoxide and optionally ...

Metal complex catalysts for selective formation of cyclic carbonates and process for preparing cyclic carbonate using the same

본 발명은 고리형 카보네이트를 제조하기 위한 신규 금속 착화합물 및 이를 촉매로 이용하여 고리형 카보네이트를 제조하는 방법에 관한 것으로, 보다 상세하게는 신규 구조의 리간드 화합물과 2가 금속을 포함하는 금속 착화합물을 촉매로 사용하여 다양한 구조의 에폭사이드 화합물과 이산화탄소를 원료 물질로 사용하여 기존 촉매에 비해 높은 전환율로 고리형 카보네이트를 고수율로 선택적으로 제조하는 방법에 관한 것이다.

Process for gas phase oxidative desulfurization using VIB catalysts promoted with CuZnAl metal oxides

Solid, heterogeneous catalysts and methods of use

Solid mixed catalysts and methods for use in conversion of triglycerides and free fatty acids to biodiesel are described. A batch or continuous process may be used with the catalysts for transesterification of triglycerides with an alkyl alcohol to produce corresponding mono carboxylic acid esters and glycerol in high yields and purity. Similarly, alkyl and aryl carboxylic acids and free fatty acids are also converted to corresponding alkyl esters. The described catalysts are thermostable, long lasting, and highly active.

Tablettierter Katalysator mit erhöhter Stabilität gegenüber Säureeinwirkung

Die vorliegende Erfindung betrifft einen verbesserten Katalysator auf Basis eines tablettierten Katalysatorformkörpers mit Calciumaluminat als Bindermaterial zur Hydrierung von Carbonylgruppen in organischen Verbindungen, dadurch gekennzeichnet, dass der Katalysatorformkörper einen Anteil von Calciumaluminat in einer Menge von 0,5 bis 10 Gew.-% umfasst. Die vorliegende Erfindung betrifft außerdem auch die Herstellung des Katalysators sowie dessen Verwendung in der Hydrierung von Carbonylgruppen in organischen Verbindungen.

CATALYST WITH ENHANCED STABILITY COMPRESSED WITH RESPECT TO THE ACTION OF ACIDS

La presente hace referencia a un catalizador mejorado en base a un cuerpo moldeado catalizador comprimido con aluminato de calcio como material aglutinante para hidrogenar grupos carbonilo en compuestos orgánicos, caracterizado porque el cuerpo moldeado catalizador comprende una parte de aluminato de calcio en una cantidad de 0.5 a 20% en peso. La presente hace referencia además a la producción del catalizador, así como a su utilización en la hidrogenación de grupos carbonilo en compuestos orgánicos.

Prussian blue derived catalysts

Prussian blue analog derived catalysts having a composition of highly porous transition metal (“TM”) oxides with nano particle size. Such OER catalysts are synthesized from the PBA, containing cobalt, iron, nickel, copper, manganese, zinc, magnesium etc., as secondary building units (“SBUs”) coordinated by hexacyano-based ligands. Furthermore, the PBA-derived catalysts may also integrated into a highly graphitized carbon network to further improve the conductivity, mass transport and durability against oxidative corrosion.

Tablettierter Katalysator für die Methanolsynthese mit erhöhter mechanischer Stabilität

Die vorliegende Erfindung betrifft einen verbesserten Katalysator auf Basis eines tablettierten Katalysatorformkörpers, enthaltend ein metallhaltiges Gemisch, enthaltend Kupfer, Zink und Aluminium, mit Calciumaluminat als Bindermaterial mit einem Gewichtsanteil von Calciumaluminat im Bereich von 1,0 % bis 30,0 % zur Synthese von Methanol aus Synthesegas. Die vorliegende Erfindung betrifft außerdem auch die Herstellung des Katalysators sowie dessen Verwendung in der Synthese von Methanol aus Synthesegas.

CO-production 1- chloro -3, 3, 3- trifluoropropene, 2, 3, 3, 3- tetrafluoropropene and 1, 3, 3, 3- tetrafluoropropene

본 발명은 1-클로로-3,3,3-트리플루오로프로펜 (1-chloro-3,3,3-trifluoropropene), 2,3,3,3-테트라플루오로프로펜 (2,3,3,3-tetrafluoropropene) 및 1,3,3,3-테트라플루오로프로펜 (1,3,3,3-tetrafluoropropene)을 공동으로 제조하는 방법을 공개하였으며, 플루오르화수소와 1,1,1,3,3-펜타클로로프로판의 혼합가스를 1,1,2,3-테트라클로로프로펜과 함께 제1 반응기에 동시 통과시켜 반응하게 하여, 반응산물을 얻으며; 얻은 산물을 제2 반응기에 바로 보내어, 촉매의 작용하에서 반응하게 하고, 얻은 산물을 염화수소 분리, 물 세척, 알칼리 세정, 건조시킨 후 정류하여 1-클로로-3,3,3-트리플루오로프로펜, 2,3,3,3-테트라플루오로프로펜 및 1,3,3,3-테트라플루오로프로펜 제품을 각각 얻는다. 본 발명은 생산이 편리하고, 공정이 간단하며, 투자가 적고, 에너지 소모가 작고, 전환율이 높은 장점이 있다. The present invention is 1-chloro-3,3,3-trifluoropropene (1-chloro-3,3,3-trifluoropropene), 2,3,3,3-tetrafluoropropene (2,3, 3,3-tetrafluoropropene) and 1,3,3,3-tetrafluoropropene (1,3,3,3-tetrafluoropropene) have been disclosed, and hydrogen fluoride and 1,1,1, The reaction product is obtained by simultaneously passing the mixed gas of 3,3-pentachloropropane together with 1,1,2,3-tetrachloropropene through the first reactor to react; The obtained product is sent directly to the second reactor to react under the action of a catalyst, and the obtained product is separated by hydrogen chloride, washed with water, washed with alkali and rectified after drying to rectify 1-chloro-3,3,3-trifluoropropene. , 2,3,3,3-tetrafluoropropene and 1,3,3,3-tetrafluoropropene products, respectively. The present invention has advantages of convenient production, simple process, low investment, low energy consumption, and high conversion rate.

Ozone-decomposing agent

Catalyst for the oxidative esterification of aldehydes to carboxylic esters

The present invention relates to novel catalysts for oxidative esterification, by means of which, for example, (meth)acrolein can be converted to methyl (meth)acrylate. The catalysts of the invention are especially notable for high mechanical and chemical stability even over very long periods. This especially relates to an improvement in the catalyst service life, activity and selectivity over prior art catalysts which lose activity and/or selectivity relatively quickly in continuous operation in media having even a small water content.

COMPOSITIONS AND METHODS OF MAKING AND USING METAL-ORGANIC FRAMEWORK COMPOSITIONS

Embodiments of the present disclosure include a metal-organic framework (MOF) composition comprising one or more metal ions, a plurality of organic ligands, and a solvent, wherein the one or more metal ions associate with the plurality of organic ligands sufficient to form a MOF with kag topology. Embodiments of the present disclosure further include a method of making a MOF composition comprising contacting one or more metal ions with a plurality of organic ligands in the presence of a solvent, sufficient to form a MOF with kag topology, wherein the solvent comprises water only. Embodiments of the present disclosure also describe a method of capturing chemical species from a fluid composition comprising contacting a MOF composition with kag topology and pore size of about 3.4 Å to 4.8 Å with a fluid composition comprising two or more chemical species and capturing one or more captured chemical species from the fluid composition. 113-. (canceled)14. A method of capturing chemical species from a fluid composition , the method comprisingcontacting a metal organic framework (MOF) composition with kag topology with a fluid composition comprising two or more chemical species; andcapturing one or more captured chemical species from the fluid composition.15. The method of claim 14 , wherein the MOF composition includes one or more of Zn claim 14 , Cu claim 14 , Ni claim 14 , and Co metal ions.16. The method of claim 14 , wherein the MOF composition includes a plurality of organic ligands.17. The method of claim 16 , wherein the ligands of the MOF composition includes N donor ligands.18. The method of claim 16 , wherein the ligands of the MOF composition include one or more of tetrazole claim 16 , triazole claim 16 , derivatives of tetrazole claim 16 , and derivatives of triazole.19. The method of claim 14 , wherein capturing includes adsorbing the one or more captured chemical species by the metal organic framework.2024-. (canceled)25. The method of claim 14 , wherein the ...

1-클로로-3,3,3-트리플루오로프로펜, 2,3,3,3-테트라플루오로프로펜 및 1,3,3,3-테트라플루오로프로펜을 공동으로 제조하는 방법

... 본 발명은 1-클로로-3,3,3-트리플루오로프로펜 (1-chloro-3,3,3-trifluoropropene), 2,3,3,3-테트라플루오로프로펜 (2,3,3,3-tetrafluoropropene) 및 1,3,3,3-테트라플루오로프로펜 (1,3,3,3-tetrafluoropropene)을 공동으로 제조하는 방법을 공개하였으며, 플루오르화수소와 1,1,1,3,3-펜타클로로프로판의 혼합가스를 1,1,2,3-테트라클로로프로펜과 함께 제1 반응기에 동시 통과시켜 반응하게 하여, 반응산물을 얻으며; 얻은 산물을 제2 반응기에 바로 보내어, 촉매의 작용하에서 반응하게 하고, 얻은 산물을 염화수소 분리, 물 세척, 알칼리 세정, 건조시킨 후 정류하여 1-클로로-3,3,3-트리플루오로프로펜, 2,3,3,3-테트라플루오로프로펜 및 1,3,3,3-테트라플루오로프로펜 제품을 각각 얻는다. 본 발명은 생산이 편리하고, 공정이 간단하며, 투자가 적고, 에너지 소모가 작고, 전환율이 높은 장점이 있다.

Additive and a catalyst composition comprising the additive for FCC process

The present disclosure relates to an additive and a catalyst composition for a catalytic cracking process of vacuum gas oil for preparing cracked run naphtha having reduced liquid olefin content, and increased propylene and butylene yields in the LPG fraction. The process makes use of a catalyst composition which is a mixture of an FCC equilibrated catalyst and an additive comprising a zeolite, phosphorus and a combination of metal promoters. The process is successful in achieving high propylene and butylene yields in the LPG fraction along with a lower liquid olefin content and increased aromatic content with increase in RON unit in the resultant cracked run naphtha, as compared to that achieved using an FCC equilibrated catalyst alone.

Additive and a catalyst composition comprising the additive for FCC process

The present disclosure relates to an additive and a catalyst composition for a catalytic cracking process of vacuum gas oil for preparing cracked run naphtha having reduced liquid olefin content, and increased propylene and butylene yields in the LPG fraction. The process makes use of a catalyst composition which is a mixture of an FCC equilibrated catalyst and an additive comprising a zeolite, phosphorus and a combination of metal promoters. The process is successful in achieving high propylene and butylene yields in the LPG fraction along with a lower liquid olefin content and increased aromatic content with increase in RON unit in the resultant cracked run naphtha, as compared to that achieved using an FCC equilibrated catalyst alone.

1,3-부타디엔의 제조방법

... 본 발명은 에탄올로부터 1,3-부타디엔의 제조에 사용되는 신규한 실리카-담지 3성분 금속 (La/Zr/Zn) 촉매의 용도에 관한 것이다. 지르코늄 및 아연을 더 포함하는 촉매 중에서 란탄의 존재는 촉매 수율 및 1,3-부타디엔에 대한 선택성을 증가시킨다.

SOLID, HETEROGENEOUS CATALYSTS AND METHODS OF USE

Solid mixed catalysts and methods for use in conversion of triglycerides and free fatty acids to biodiesel are described. A batch or continuous process may be used with the catalysts for transesterification of triglycerides with an alkyl alcohol to produce corresponding mono carboxylic acid esters and glycerol in high yields and purity. Similarly, alkyl and aryl carboxylic acids and free fatty acids are also converted to corresponding alkyl esters. The described catalysts are thermostable, long lasting, and highly active.

CATALYTIC BODY COATED WITH METAL OXIDE, METHOD OF MANUFACTURING THE SAME, AND METHOD OF PREPARING 1,3-BUTADIENE USING THE SAME

According to an embodiment of the present invention, there are provided a catalytic body, a method of manufacturing the same, and a method of preparing 1,3-butadiene using the same. The catalytic body includes an inactive support; an intermediate layer disposed on a surface of the inactive support; and an active layer disposed on a surface of the intermediate layer, wherein the active layer includes catalyst powder and a binder. 1. A catalytic body comprising:an inactive support;an intermediate layer disposed on a surface of the inactive support; andan active layer disposed on a surface of the intermediate layer,wherein the active layer includes catalyst powder and a binder.2. The catalytic body of claim 1 , wherein the inactive support has a porosity of 70 vol % or less.3. The catalytic body of claim 2 , wherein the inactive support is of one shape selected from the group consisting of a spherical shape claim 2 , a cylindrical shape claim 2 , a ring shape claim 2 , a platy shape claim 2 , and a combination of two or more thereof.4. The catalytic body of claim 3 , wherein the inactive support is one selected from the group consisting of alumina claim 3 , silica claim 3 , zirconia claim 3 , silicon carbide claim 3 , cordierite claim 3 , and a combination of two or more thereof.5. The catalytic body of claim 1 , wherein the intermediate layer may consist of one selected from the group consisting of alumina claim 1 , silica claim 1 , kaolin claim 1 , TiO claim 1 , ZnO claim 1 , bentonite claim 1 , and a combination of two or more thereof.6. The catalytic body of claim 1 , wherein the intermediate layer has a weight of 3 to 15 g/L with respect to a volume of the inactive support.7. The catalytic body of claim 1 , wherein the catalyst powder is an oxide derived from one selected from the group consisting of iron claim 1 , magnesium claim 1 , manganese claim 1 , zinc claim 1 , bismuth claim 1 , molybdenum claim 1 , and a combination of two or more thereof.8. The catalytic ...

For coproducing trifluoro propylene products and tetrafluoroethylene propylene product of the method

本发明公开了一种联产1‑氯‑3,3,3‑三氟丙烯、2,3,3,3‑四氟丙烯和1,3,3,3‑四氟丙烯的方法，将氟化氢和1,1,1,3,3‑五氯丙烷混合气与1,1,2,3‑四氯丙烯同时通入第一反应器进行反应，得到反应产物；将得到的产物直接进入第二反应器，在催化剂的作用下进行反应，将得到的产物分离氯化氢、水洗、碱洗、干燥后精馏分别得到1‑氯‑3,3,3‑三氟丙烯、2,3,3,3‑四氟丙烯和1,3,3,3‑四氟丙烯产品。本发明具有生产灵活、工艺简单、投资小、能耗低，转化率高的优点。

Tableted catalyst having increased stability to action of acids

The present invention relates to an improved catalyst based on a tableted shaped catalyst body comprising calcium aluminate as binder material for hydrogenating carbonyl groups in organic compounds, wherein the shaped catalyst body comprises a proportion of calcium aluminate in an amount of from 0.5 to 10% by weight. The present invention additionally relates to the production of the catalyst and to its use in the hydrogenation of carbonyl groups in organic compounds.

CATALYSTS FOR SOFT OXIDATION COUPLING OF METHANE TO ETHYLENE AND ETHANE

Disclosed is a catalyst and methods for the oxidative coupling of methane (OCM) reaction using elemental sulfur as a soft oxidant. The process can provide ethylene from methane with high conversion and selectivity. 1. A method of producing an olefin from methane and elemental sulfur , the method comprising:(a) obtaining a reaction mixture comprising methane and elemental sulfur gas; and(b) contacting the reaction mixture with a catalyst under reaction conditions sufficient to produce a product stream comprising an olefin, wherein the catalyst is a metal, a mixed metal oxide, mixed metal sulfide, a metal oxysulfide, mixed metal oxysulfide, or any mixture thereof.2. The method of claim 1 , wherein the olefin comprises C+ hydrocarbons claim 1 , preferably ethylene.3. The method of claim 1 , wherein the product stream further comprises hydrogen sulfide.4. The method of claim 1 , wherein the reaction mixture comprises a methane to elemental sulfur molar ratio of 1:2 to 20:1.5. The method of claim 1 , wherein the conditions sufficient to produce a product stream in step (b) comprise a reaction temperature of at least 450° C.6. The method of claim 1 , wherein the conditions sufficient to produce a product stream comprise a reaction pressure of 0.05 to 10.0 MPa or 0.1 to 10.0 MPa claim 1 , a gas hourly space velocity (GHSV) of 500 to 100 claim 1 ,000 or both.7. The method of claim 1 , wherein the metal claim 1 , the mixed metal oxide claim 1 , the mixed metal sulfide claim 1 , the metal oxysulfide claim 1 , mixed metal oxysulfide claim 1 , or the metal sulfide comprises:an alkaline earth metal, preferably magnesium (Mg), calcium (Ca), strontium (Sr), barium (Ba), or any combination thereof;a transition metal, preferably yttrium (Y), zirconium (Zr), vanadium (V), tantalum (Ta), tungsten (W), manganese (Mn), rhenium (Rh), iron (Fe), cobalt (Co), iridium (Ir), nickel (Ni), copper (Cu), zinc (Zn), or any combination thereof;a post-transition metal, preferably aluminum (Al), ...

GAS CLEAN-UP FOR ALKANE OXIDATIVE DEHYDROGENATION EFFLUENT

Highly active quaternary metallic materials using short-chain alkyl quaternary ammonium compounds

A highly active quaternary mixed transition metal oxide material has been developed. The material may be sulfided to generate metal sulfides which are used as catalyst in a conversion process such as hydroprocessing. The hydroprocessing may include hydrodenitrification, hydrodesulfurization, hydrodemetallation, hydrodesilication, hydrodearomatization, hydroisomerization, hydrotreating, hydrofining, and hydrocracking.

TABLET-FORM COPPER MANGANESE-BASED CATALYST WITH INCREASED STABILITY AGAINST THE ACTION OF ACID

The invention relates to a copper manganese-based catalyst on the basis of a tablet-form shaped catalyst body, comprising calcium aluminate as a binder, for hydrating carbonyl groups in organic compounds, characterised in that said shaped catalyst body comprises calcium aluminate in an amount of 0.5 to 20 wt. %. The invention also relates to the production of the catalyst and to the use of same in the hydration of carbonyl groups in organic compound. 1. A shaped catalyst body comprising a material of the formula CuAlMnZnOwhere a is a number between 0 and 2.5 , b is a number between 0.001 and 0.6 and c is a number between 0 and 2.5 , and d is chosen such that the overall charge of the empirical formula is zero , wherein the shaped catalyst body is in tablet form and contains calcium aluminate as binder material in a proportion by weight of 0.5% to 20.0% , based on the shaped catalyst body.2. The shaped catalyst body as claimed in claim 1 , wherein the calcium aluminate is present in a proportion by weight of 0.5% to 10.0% claim 1 , preferably of 0.5% to 5.0% claim 1 , more preferably of 0.5% to less than 5.0% claim 1 , most preferably of 0.5% to 3.0% claim 1 , based on the shaped catalyst body.3. The shaped catalyst body as claimed in claim 1 , wherein the side crushing strength is 100-300 N.4. A process for producing a shaped catalyst body comprising a material of the formula CuAlMnZnOand comprising calcium aluminate as binder material in a proportion by weight of 0.5% to 20.0% claim 1 , based on the shaped catalyst body claim 1 , comprising the following steps:a) mixing a metal-containing mixture comprising copper, manganese and at least one element selected from zinc and aluminum with calcium aluminate, a lubricant and waterb) tableting the mixture according to step a) to obtain a tableted shaped bodyc) subjecting the tableted shaped bodies to thermal treatment at a temperature between 200 and 800° C. for a period between 30 min and 4 h,where a is between 0 and 2. ...

Conversion of alcohols to hydrocarbons using a dual catalyst system comprising basic oxide on mixed oxide or mesoporous carrier and etched metal loaded zeolite catalyst

A method for converting an alcohol to hydrocarbons comprises two serially placed catalysts. The fraction of aromatics is reduced to desired levels. The method comprises: a) contacting the alcohol with a first catalyst on a carrier, said carrier is selected from a mixed oxide and a mesoporous carrier, said first catalyst comprises at least one basic oxide and optionally at least one selected from the group consisting of metals and metal oxides, then b) contacting the resulting mixture from step a) with a second catalyst wherein said second catalyst is an etched metal loaded zeolite catalyst wherein the etched metal loaded zeolite catalyst is manufactured with a method comprising etching with subsequent loading of metal onto the catalyst, wherein the metal is in the form of nanoparticles, and wherein at least two different metals are loaded onto the etched zeolite catalyst. The hydrocarbons are recovered and used for instance for fuel including gasoline, kerosene, diesel, and jet propellant ...

MACROPOROUS CATALYST FOR THE PREPARATION OF ALIPHATIC AMINES

A process for the preparation of aliphatic amines, comprises reacting an aliphatic alcohol with an aminating agent in the presence of a catalyst. The catalyst contains copper oxide on a support made of porous alumina, wherein the porous alumina has a volume, corresponding to pores greater than 500 Å in diameter, of from 10 ml/100 g to 95 ml/100 g. 2. The process according to claim 1 , wherein the porous alumina has a volume claim 1 , corresponding to pores greater than 500 Å in diameter claim 1 , of from 20 ml/100 g to 95 ml/100 g.3. The process according to claim 1 , wherein the porous alumina has a volume claim 1 , corresponding to pores greater than 500 Å in diameter claim 1 , of from 30 ml/100 g to 95 ml/100 g.4. The process according to claim 1 , wherein the porous alumina has a specific surface area of from 10 m/g to 280 m/g.5. The process according to claim 1 , wherein the porous alumina has a specific surface area of from 50 m/g to 280 m/g.6. The process according to claim 1 , wherein the catalyst further comprises a compound of at least one element selected from Fe claim 1 , Co claim 1 , Zn claim 1 , Ni claim 1 , Cr claim 1 , Mn claim 1 , Mg claim 1 , Ba and rare earth metals.7. The process according to claim 1 , wherein the catalyst comprises from 5 wt % to 50 wt % of copper oxide claim 1 , weight percentage based on the total weight of the catalyst.9. The process according to claim 1 , wherein the aliphatic alcohol and the aminating agent are mixed together with a flow of hydrogen and the mixture is continuously introduced into a reaction zone claim 1 , wherein the molar ratio of the aliphatic alcohol/the aminating agent/the hydrogen is in the range of from 1:1:5 to 1:2:20.10. The process according to claim 9 , wherein the molar ratio of the aliphatic alcohol/the aminating agent/the hydrogen is in the range of from 1:1:5 to 1:1.2:15.11. The process according to claim 1 , wherein the reaction is carried out at a temperature of from 150° C. to 350° C.12. ...

TABLETED CATALYST FOR METHANOL SYNTHESIS HAVING INCREASED MECHANICAL STABILITY

The invention relates to an improved catalyst based on a tableted molded catalyst body, containing a metal-containing mixture, containing copper, zinc, and aluminum, with calcium aluminate as a binder material with a weight fraction of calcium aluminate in the range of 1.0% to 30.0%, for synthesizing methanol from synthesis gas. The invention further relates to the production of the catalyst and to the use of the catalyst in the synthesis of methanol from synthesis gas. 1. A shaped catalyst body containing copper , zinc and aluminum , characterized in that the shaped catalyst body is present in tablet form and contains calcium aluminate as binder material with a proportion by weight of calcium aluminate in the range from 1.0% to 30.0% , based on the shaped catalyst body.2. The shaped catalyst body as claimed in claim 1 , wherein the proportion by weight is in the range from 5.0% to 20.0%.3. The shaped catalyst body as claimed in claim 1 , wherein the fracture strength is from 2 to 10%.4. The shaped catalyst body as claimed in claim 1 , wherein the lateral compressive strength after reduction and dry stabilization is from 40 to 200 N claim 1 , preferably from 40 to 100 N claim 1 , more preferably from 50 to 100 N.5. The shaped catalyst body as claimed in claim 1 , wherein the BET surface area is in the range from 70 to 150 m/ claim 1 , preferably from 75 to 140 m/g and particularly preferably from 80 to 120 m/g.6. The shaped catalyst body as claimed in claim 1 , wherein the pore volume claim 1 , measured by means of mercury porosimetry claim 1 , is between 150 mm/g and 400 mm/g claim 1 , preferably between 250 mm/g and 350 mm/g claim 1 , particularly preferably between 300 mm/g and 350 mm/g.7. The shaped catalyst body as claimed in claim 1 , wherein the copper surface area after reduction is between 20 m/g and 50 m/g claim 1 , preferably between 20 m/g and 40 m/g claim 1 , particularly preferably between 25 m/g and 36 m/g.8. The shaped catalyst body as claimed in ...

GAS CLEAN-UP FOR ALKANE OXIDATIVE DEHYDROGENATION EFFLUENT

The invention relates to a process for the production of an alkene by alkane oxidative dehydrogenation, comprising: (a) subjecting a stream comprising an alkane to oxidative dehydrogenation conditions, comprising contacting the alkane with oxygen in the presence of a catalyst comprising a mixed metal oxide, resulting in a stream comprising alkene, unconverted alkane, water, carbon dioxide, unconverted oxygen, carbon monoxide and optionally an alkyne; (b) removing water from at least part of the stream comprising alkene, unconverted alkane, water, carbon dioxide, unconverted oxygen, carbon monoxide and optionally an alkyne resulting from step (a), resulting in a stream comprising alkene, unconverted alkane, carbon dioxide, unconverted oxygen, carbon monoxide and optionally alkyne; (c) removing unconverted oxygen, carbon monoxide and optionally alkyne from at least part of the stream comprising alkene, unconverted alkane, carbon dioxide, unconverted oxygen, carbon monoxide and optionally alkyne resulting from step (b), wherein carbon monoxide and optionally alkyne are oxidized into carbon dioxide, resulting in a stream comprising alkene, unconverted alkane and carbon dioxide; (d) optionally removing carbon dioxide from at least part of the stream comprising alkene, unconverted alkane in and carbon dioxide resulting from step (c), resulting in a stream comprising alkene and unconverted alkane; (e) optionally separating at least part of the stream comprising alkene and unconverted alkane resulting from step (d), into a stream comprising alkene and a stream comprising unconverted alkane; (f) optionally recycling unconverted alkane from at least part of the stream comprising unconverted alkane resulting from step (e), to step (a). 1. A process for the production of an alkene by alkane oxidative dehydrogenation , comprising:(a) subjecting a stream comprising an alkane to oxidative dehydrogenation conditions, comprising contacting the alkane with oxygen in the presence of a ...

METHANOL PROCESS

A process is described for the synthesis of methanol comprising the steps of: (i) passing a first synthesis gas mixture comprising a make-up gas through a first synthesis reactor containing a cooled methanol synthesis catalyst to form a first product gas stream, (ii) recovering methanol from the first product gas stream thereby forming a first methanol-depleted gas mixture, (iii) combining the first methanol-depleted gas mixture with a loop recycle gas stream to form a second synthesis gas mixture, (iv) passing the second synthesis gas mixture through a second synthesis reactor containing a cooled methanol synthesis catalyst to form a second product gas stream, (v) recovering methanol from the second product gas stream thereby forming a second methanol-depleted gas mixture, and (vi) using at least part of the second methanol-depleted gas mixture as the loop recycle gas stream, wherein the first synthesis reactor has a higher heat transfer per cubic metre of catalyst than the second synthesis reactor, none of the loop recycle gas stream is fed to the first synthesis gas mixture and the recycle ratio of the loop recycle gas stream to form the second synthesis gas mixture is in the range 1.1:1 to 6:1. 1. A process for synthesizing methanol comprising the steps of:(i) passing a first synthesis gas mixture comprising a make-up gas through a first synthesis reactor containing a first cooled methanol synthesis catalyst to form a first product gas stream,(ii) recovering methanol from the first product gas stream to form a first methanol-depleted gas mixture,(iii) combining the first methanol-depleted gas mixture with a loop recycle gas stream to form a second synthesis gas mixture,(iv) passing the second synthesis gas mixture through a second synthesis reactor containing a second cooled methanol synthesis catalyst to form a second product gas stream,(v) recovering methanol from the second product gas stream to form a second methanol-depleted gas mixture, and(vi) using at ...

METHOD FOR PRODUCING METAL COMPLEX CATALYST, AND METAL COMPLEX CATALYST PRODUCED BY SAME

A method for preparing a metal complex catalyst by (A) obtaining a precipitate by bringing a metal precursor solution comprising a zinc (Zn) precursor, a ferrite (Fe) precursor, and water into contact with a basic aqueous solution; (B) obtaining a zinc ferrite catalyst by filtering and calcining the precipitate; and (C) supporting an acid onto the zinc ferrite catalyst, and a metal complex catalyst prepared thereby. 1. A method for preparing a metal complex catalyst , the method comprising:(A) obtaining a precipitate by bringing a metal precursor solution comprising a zinc (Zn) precursor, a ferrite (Fe) precursor, and water into contact with a basic aqueous solution;(B) obtaining a zinc ferrite catalyst by filtering and calcining the precipitate; and(C) supporting an acid onto the zinc ferrite catalyst.2. The method of claim 1 , wherein in Step (A) claim 1 , a content of the zinc precursor is 0.1 wt % to 5 wt % based on weight of water of the metal precursor solution.3. The method of claim 1 , wherein in Step (A) claim 1 , a content of the ferrite precursor is 1 wt % to 10 wt % based on weight of water of the metal precursor solution.4. The method of claim 1 , wherein in Step (C) claim 1 , the acid is phosphoric acid.5. The method of claim 1 , wherein in Step (C) claim 1 , a content of the acid is 0.05 wt % to 0.2 wt % based on weight of the zinc ferrite catalyst.6. The method of claim 1 , wherein the zinc precursor and the ferrite precursor are each independently one or more selected from the group consisting of a nitrate claim 1 , an ammonium salt claim 1 , a sulfate claim 1 , and a chloride claim 1 , and a hydrate thereof.7. The method of claim 1 , wherein the zinc precursor is zinc chloride (ZnCl).8. The method of claim 1 , wherein the ferrite precursor is ferric chloride hydrate (FeCl.6HO).9. The method of claim 1 , wherein a pH of the basic aqueous solution is 7 to 11.10. The method of claim 1 , wherein the basic aqueous solution is one or more selected from ...

METHOD FOR CO-PRODUCTION OF 1-CHLORO-3,3,3-TRIFLUOROPROPENE, 2,3,3,3-TETRAFLUOROPROPENE AND 1,3,3,3-TETRAFLUOROPROPENE

This invention discloses a method for co-production of 1-chloro-3,3,3-trifluoropropene, 2,3,3,3-tetrafluoropropene and 1,3,3,3-tetrafluoropropene. This method includes inputting the mixed gases of hydrogen fluoride and 1,1,1,3,3-pentachloropropane together with 1,1,2,3-tetrachloropropene into a first reactor for a reaction to obtain a reaction product; directly inputting the reaction product into a second reactor to perform a reaction in the presence of a catalyst; separating hydrogen chloride from the obtained product; obtaining 1-chloro-3,3,3-trifluoropropene, 2,3,3,3-tetrafluoropropene and 1,3,3,3-tetrafluoropropene respectively after water washing, alkaline washing, drying and rectifying. This invention has the advantages of flexible production, simple process, small investment, low energy consumption and high conversion rate. 17-. (canceled)8. A method for co-production of 1-chloro-3 ,3 ,3-trifluoropropene , 2 ,3 ,3 ,3-tetrafluoropropene and 1 ,3 ,3 ,3-tetrafluoropropene , the method comprising:{'sup': '−1', '(a) preheating and then directing hydrogen fluoride and 1,1,1,3,3-pentachloropropane into a first reactor in a molar ratio of 9:1-15:1, wherein the first reactor comprises an upper section filled with an aluminum oxide supported chromium metal catalyst and a lower section filled with a chromic oxide supported indium metal catalyst, wherein the hydrogen fluoride and the 1,1,1,3,3-pentachloropropane are reacted in the upper section of the first reactor at a temperature of 200-400° C. and at an air flow rate of 300-1,000 h, and a product from the upper section enters the lower section of the first reactor to continuously react with the 1,1,2,3-tetrachloropropane to obtain a first reaction product of the first reactor, wherein a molar ratio of the 1,1,2,3-tetrachloropropane to the hydrogen fluoride in the lower section of the first reactor is 3:9-5:9;'}{'sup': '−1', '(b) directly directing the first reaction product of the first reactor into a second reactor ...

HYDROGENOLYSIS CATALYSTS WITH HIGH ACID TOLERANCE

A catalyst includes a mixed metal oxide; an alumina; silica, and calcium, where the mixed metal oxide includes Cu and at least one of Mn, Zn, Ni, or Co. Such catalysts exhibit enhanced tolerance sulfur-containing compounds and free fatty acids. 1. A catalyst comprising:a mixed metal oxide comprising Cu and at least one of Mn, Zn, Ni, or Co;an alumina;silica; andcalcium;wherein the catalyst comprises a surface, wherein the percent of Cu at the surface in relation to total Cu content of the catalyst is from about 0.5% to about 20%.2. (canceled)3. The catalyst of claim 1 , wherein the catalyst comprises about 15 wt % to about 50 wt % Cu.4. The catalyst of claim 1 , wherein the mixed metal oxide comprises Cu and Mn.5. The catalyst of claim 4 , wherein the mixed metal oxide comprises Cu and Mn claim 4 , and the catalyst comprises about 2 wt % to about 10 wt % Mn.6. (canceled)7. The catalyst of claim 4 , wherein the mixed metal oxide comprises Cu and Zn claim 4 , and the catalyst comprises about 15 wt % to about 50 wt % Zn.8. The catalyst of claim 1 , wherein the alumina is present in the catalyst at about 10 wt % to about 30 wt %.9. The catalyst of claim 1 , wherein the silica is present in the catalyst at about 10 wt % to about 30 wt %.10. (canceled)11. The catalyst of claim 1 , wherein the calcium is present in the catalyst at about 2 wt % to about 10 wt %.12. (canceled)13. The catalyst of claim 1 , wherein the catalyst is substantially free of sodium claim 1 , chromium claim 1 , barium claim 1 , or a combination of two or more thereof.1415-. (canceled)16. The catalyst of claim 1 , wherein the catalyst has a Brunauer-Emmett-Teller surface area from about 10 m/g to about 150 m/g.17. (canceled)18. The catalyst of claim 1 , wherein the catalyst has a mercury pore volume from about 0.10 cm/g to about 0.80 cm/g.19. The catalyst of claim 1 , wherein the catalyst has a packed ambient bulk density from about 0.3 g/cmto about 1.6 g/cm.20. The catalyst of claim 1 , wherein the ...

Method for producing ethanolamines and/or ethyleneamines

The present invention relates to a process for preparing ethanolamines and/or ethyleneamines in the gas phase by reacting ethylene glycol with ammonia in the presence of an amination catalyst. It is a characteristic feature of the process that the amination catalyst is prepared by reducing a calcined catalyst precursor comprising an active composition, where the active composition comprises one or more active metals selected from the group consisting of the elements of groups 8, 9, 10 and 11 of the Periodic Table of the Elements and optionally one or more added catalyst elements selected group consisting of the metals and semimetals of groups 3 to 7 and 12 to 17, the element P and the rare earth elements. It is a further characteristic feature of the process that a catalyst precursor having low basicity is used, the low basicity being achieved in that a) the catalyst precursor is prepared by coprecipitation and the active composition additionally comprises one or more basic elements selected from the group consisting of the alkali metals and alkaline earth metals; or b) the catalyst precursor, as well as the active composition, additionally comprises a support material and is prepared by impregnating the support material or precipitative application onto the support material and the support material comprises one or more basic elements selected from the group consisting of the alkali metals, Be, Ca, Ba and Sr or one or more minerals selected from the group consisting of hydrotalcite, chrysotile and sepiolite; or c) the catalyst precursor, as well as the active composition, additionally comprises a support material and is prepared by impregnating the support material or precipitative application onto the support material and the active composition of the catalyst support comprises one or more basic elements selected from the group consisting of the alkali metals and the alkaline earth metals; or d) the catalyst precursor is calcined at temperatures of 600° C. or more ...

CATALYST AND METHOD FOR CONVERTING CARBON-CONTAINING STREAM TO C2 TO C5 PARAFFINS USING IT

A process for preparing Cto Cparaffins includes introducing a feed stream comprising hydrogen gas and a carbon-containing gas into a reaction zone of a reactor, and converting the feed stream into a product stream comprising Cto Cparaffins in the reaction zone in the presence of a hybrid catalyst. The hybrid catalyst includes a metal oxide catalyst component and a microporous catalyst component. The metal oxide catalyst component satisfies: an atomic ratio of Cu/Zn from 0.01 to 3.00; an atomic ratio of Cr/Zn from 0.01 to 1.50; and percentage of (Al+Cr) from greater than 0.0 at % to 50.0 at % based on a total amount of metal in the metal oxide catalyst component. 1. A process for preparing Cto Cparaffins comprising:introducing a feed stream comprising hydrogen gas and a carbon-containing gas selected from the group consisting of carbon monoxide, carbon dioxide, and mixtures thereof into a reaction zone of a reactor; and{'sub': 2', '5, 'claim-text': a metal oxide catalyst component comprising copper, chromium, and zinc; and', 'a microporous catalyst component that is a molecular sieve having 8-MR pore openings, wherein, 'converting the feed stream into a product stream comprising Cto Cparaffins in the reaction zone in the presence of a hybrid catalyst, the hybrid catalyst comprising an atomic ratio of Cu/Zn from 0.01 to 3.00;', 'an atomic ratio of Cr/Zn from 0.01 to 1.50; and', 'an atomic percentage of (Al+Cr) from greater than 0.0 at % to 50.0 at % based on a total amount of metal in the metal oxide catalyst component., 'the metal oxide catalyst component satisfies2. The process for preparing Cto Cparaffins according to claim 1 , wherein the metal oxide catalyst component satisfies:an atomic ratio of Cu/Zn from 0.25 to 1.00;an atomic ratio of Cr/Zn from 0.20 to 0.50; andan atomic percentage of (Al+Cr) from 10.0 at % to 30.0 at % based on a total amount of metal in the metal oxide catalyst component.3. The process for preparing Cto Cparaffins according to claim 1 , ...

ZnWO4 PHOTOCATALYTIC MATERIAL WITH OXYGEN VACANCY AND PREPARATION METHOD THEREOF

The invention belongs to the field of novel photocatalytic materials, and particularly relates to a ZnWO4 photocatalytic material containing oxygen vacancy. According to the material, absorption exists in a near infrared region of an ultraviolet-visible light diffuse reflection spectrum, wherein the wavelength range of the near infrared region is 780-2500 nm. The invention further relates to a preparation method of the ZnWO4 photocatalytic material containing oxygen vacancy. Na2WO4 and soluble zinc salt are used as raw materials, ZnWO4 crystals are formed through a hydrothermal crystallization reaction and then roasted in the presence of hydrogen so as to achieve partial reduction of ZnWO4, and then the ZnWO4 photocatalytic material containing oxygen vacancy is obtained. 1. A ZnWOphotocatalytic material containing oxygen vacancy , characterized in that absorption exists in a near infrared region of an ultraviolet-visible light diffuse reflection spectrum of the material , wherein a wavelength range of the near infrared region is 780-2500 nm.2. The ZnWOphotocatalytic material containing oxygen vacancy of claim 1 , characterized in that ZnWOis roasted in the presence of hydrogen so as to achieve partial reduction of ZnWO claim 1 , and then the ZnWOphotocatalytic material containing oxygen vacancy is obtained.3. The ZnWOphotocatalytic material containing oxygen vacancy of claim 2 , characterized in that a roasting temperature is 350-600 DEG C. claim 2 , and a roasting time is 1-4 h.4. The ZnWOphotocatalytic material containing oxygen vacancy of claim 2 , characterized in that a temperature increasing rate during roasting is 1-5 DEG C./min.5. A preparation method of the ZnWOphotocatalytic material containing oxygen vacancy claim 2 , characterized in that NaWOand soluble zinc salt are used as raw materials claim 2 , ZnWOcrystals are formed through a hydrothermal crystallization reaction and then roasted in the presence of hydrogen so as to achieve partial reduction of ...

CATALYST FOR PREPARING 2,5-FURANCARBOXYLIC ACID AND METHOD FOR PREPARING 2,5-FURANCARBOXYLIC ACID USING CATALYST

The present invention relates to a catalyst for preparing 2,5-furandicarboxylic acid (FDCA), which is a catalyst for carboxylation of a furan-based compound containing a hydroxyl group and a carbonyl group or a derivative thereof and is configured such that noble metal nanoparticles are incorporated into a spinel-type support, and to a method of preparing 2,5-furandicarboxylic acid (FDCA), including carboxylating a furan-based compound containing a hydroxyl group and a carbonyl group or a derivative thereof in the presence of a catalyst configured such that noble metal nanoparticles are incorporated into a spinel-type support. 1. A catalyst for preparing 2 ,5-furandicarboxylic acid (FDCA) , which is a catalyst for carboxylation of a furan-based compound containing a hydroxyl group and a carbonyl group or a derivative thereof and is configured such that noble metal nanoparticles are incorporated into a spinel-type support.2. The catalyst of claim 1 , wherein the spinel-type support is at least one selected from the group consisting of MnCoO claim 1 , CoMnO claim 1 , ZnAlO claim 1 , FeAlO claim 1 , CuFeO claim 1 , ZnMnO claim 1 , MnFeO claim 1 , FeO claim 1 , TiFeO claim 1 , ZnFeO claim 1 , MgSiO claim 1 , and FeSiO.3. The catalyst of claim 1 , wherein the support has an average particle size (D) of 2.0 to 4.0 μm.4. The catalyst of claim 1 , wherein the noble metal is at least one selected from the group consisting of platinum claim 1 , palladium claim 1 , and ruthenium.5. The catalyst of claim 4 , wherein the noble metal is ruthenium.6. The catalyst of claim 1 , wherein the furan-based compound is 5-hydroxymethylfurfural (HMF).7. The catalyst of claim 1 , wherein the derivative of the furan-based compound is 2-acetoxymethyl-5-furfural (AMF).8. The catalyst of claim 1 , wherein the noble metal nanoparticles are used in an amount of 0.1 to 10 wt % based on a total weight of the catalyst.9. A method of preparing 2 claim 1 ,5-furandicarboxylic acid (FDCA) claim 1 , ...

CATALYST FOR CONVERTING CARBON-CONTAINING STREAM TO C2 TO C5 PARAFFINS AND METHOD USING THE CATALYST

A process for preparing Cto Cparaffins includes introducing a feed stream comprising hydrogen gas and a carbon-containing gas into a reaction zone of a reactor, and converting the feed stream into a product stream comprising Cto Cparaffins in the reaction zone in the presence of a hybrid catalyst. The hybrid catalyst includes a metal oxide catalyst component and a microporous catalyst component. The metal oxide catalyst component satisfies: an atomic ratio of Cu/Zn from 0.01 to 3.00; an atomic ratio of Cr/Zn from 0.01 to 1.50; and percentage of (Al+Cr) from greater than 0.0 at % to 50.0 at % based on a total amount of metal in the metal oxide catalyst component.

A catalyst for converting synthesis gas to alcohols

A catalyst for converting a synthesis gas, said catalyst comprising a first catalyst component and a second catalyst component, wherein the first catalyst component comprises, supported on a first porous oxidic substrate, Rh, Mn, an alkali metal M and Fe, and wherein the second catalyst component comprises, supported on a second porous oxidic support material, Cu and a transition metal other than Cu.

MULTITUBULAR REACTOR FOR LIQUID PHASE ALCOHOL DEHYDROGENATION AND METHOD FOR LIQUID PHASE ALCOHOL DEHYDROGENATION

The invention relates to a multitubular reactor for dehydrogenation of liquid phase alcohol dehydrogenation and a method of liquid phase alcohol dehydrogenation. Most of the alcohol dehydrogenation reaction is endothermic reaction, the reaction temperature is high and the equilibrium conversion rate is low. 110-. (canceled)11. A multitubular reactor for liquid phase alcohol dehydrogenation , comprising:a reactor shell;a plurality of tubes spaced within the reactor shell, wherein the tubes are made of a gas selectively permeable membrane, which is permeable to hydrogen and oxygen but impermeable to liquid molecules, and wherein one end of the tubes is a liquid phase alcohol inlet, and another end of the tubes is a dehydrogenation product outlet;a dehydrogenation catalyst being provided inside the tubes;an oxidation catalyst being provided outside the tubes and in the reactor shell;at least one oxygen membrane tube disposed in the reactor shell, wherein one end of the oxygen membrane tube is an oxygen inlet, and another end of the oxygen membrane tube is closed; andan oxidation product outlet disposed on the reactor shell.12. The multitubular reactor for liquid phase alcohol dehydrogenation of claim 11 , wherein the gas selectively permeable membrane is made of a molecular sieve claim 11 , silica claim 11 , carbon claim 11 , ceramics claim 11 , porous stainless steel or a composite formed by two or more thereof.13. The multitubular reactor for liquid phase alcohol dehydrogenation of claim 11 , wherein the dehydrogenation catalyst is filled in the form of particles within the tubes claim 11 , and the dehydrogenation catalyst comprises:a supported noble metal and a support thereof, wherein the noble metal is Pd, Pt, Ru or Au, and the support is a metal oxide, a molecular sieve, a carbon material or an organic polymer; anda non-noble metal, wherein the non-noble metal is Cu, Zn, Mn, Ni, Co, Cr or V.14. The multitubular reactor for liquid phase alcohol dehydrogenation of ...

Highly active quaternary metallic materials using short-chain alkyl quaternary ammonium compounds

A highly active quaternary mixed transition metal oxide material has been developed. The material may be sulfided to generate metal sulfides which are used as a catalyst in a conversion process such as hydroprocessing. The hydroprocessing may include hydrodenitrification, hydrodesulfurization, hydrodemetallation, hydrodesilication, hydrodearomatization, hydroisomerization, hydrotreating, hydrofining, and hydrocracking.

Natural 1,2-Alkanediols, Compositions Having Natural 1,2-Alkanediols and Processes for Making the Same

A process is incorporated herein for the synthesis of bio-1,2-alkanediols, comprising: providing a bio-alkene having a carbon chain of about 5 to about 20 carbon atoms and a bio-1-alkene regioselectivity of at least about 80%, at least about 92% and/or at least about 95%; and converting the bio-alkene to a bio-1,2-alkanediol having a carbon chain length of about 5 to about 20 carbon atoms. Methods for treating catalysts which may be incorporated in the process for the synthesis of bio-1,2-alkanediols are also included herein. Such bio-1,2-alkanediols are used in compositions and products alone as antimicrobial materials, or with existing bio-compounds and/or antimicrobials, preservatives, alternative preservation systems and/or hurdle technology components. The bio-1,2-alkanediols incorporate a natural and bio-based pathway for antimicrobial effects in various compositions such as cosmetic, pharmaceutical, industrial and household products. 1. A method for making a bio-alkene , comprising:dehydrating a bio-1-alcohol by heating the bio-1-alcohol in a reactor with a catalyst, wherein the resulting bio-alkene has a carbon chain of about 5 to about 20 carbon atoms and a bio-1-alkene regioselectivity of at least about 80%.2. The method of claim 1 , wherein the bio-alkene has a carbon chain of about 6 to about 14 carbon atoms.3. The method according to claim 2 , wherein the bio-alkene has a carbon chain length of about 6 to about 10 carbon atoms.4. The method according to claim 3 , wherein the bio-alkene has a carbon chain length of about 6 to about 8 carbon atoms.5. The method according to claim 1 , wherein the bio-alkene is bio-octene.6. The method according to claim 1 , wherein the reactor is a fixed bed reactor.7. The method according to claim 6 , wherein the fixed bed reactor is a fluidized bed reactor.8. The method according to claim 1 , wherein the catalyst is selected from ZnAlOand a -alumina catalyst.9. The method according to claim 1 , wherein the bio-alkene has ...

CATALYST FOR SYNTHESIZING AROMATIC HYDROCARBONS AND PREPARATION METHOD THEREFOR

A catalyst for synthesizing aromatic hydrocarbons, a preparation method thereof and a method for synthesizing aromatic hydrocarbons by using the catalyst. The catalyst comprises acidic molecular sieve particles and zinc-aluminum composite oxide particles. The catalyst has relatively high selectivity to aromatic hydrocarbons, particularly BTX, stable performance, and a long single-pass life. 1. A catalyst , wherein the catalyst comprises acidic molecular sieve particles and zinc-aluminum composite oxide particles.2. The catalyst according to claim 1 , wherein the zinc-aluminum composite oxide particles further comprise other metal elements;preferably, the other metal elements are metal elements other than zinc, aluminum, and radioactive elements;more preferably, the other metal elements comprise at least one selected from a group consisting of zirconium, copper, platinum, palladium, and chromium.3. The catalyst according to claim 1 , wherein the mass ratio of the acidic molecular sieve particles to the zinc-aluminum composite oxide particles is in a range from 1:19 to 19:1;preferably, the mass ratio of the acidic molecular sieve particles to the zinc-aluminum composite oxide particles is in a range from 4:1 to 1:4; more preferably, the mass ratio of the acidic molecular sieve particles to the zinc-aluminum composite oxide particles is in a range from 2:1 to 1:2.4. The catalyst according to claim 1 , wherein the particle diameters of the acidic molecular sieve particles and the zinc-aluminum composite oxide are each independently less than or equal to 5 mm;preferably, the particle diameters of the acidic molecular sieve particles and the zinc-aluminum composite oxide are each independently less than or equal to 1 mm and greater than or equal to 0.1 mm.5. The catalyst according to claim 1 , wherein the acidic molecular sieve is an acidic molecular sieve having a pore framework with 10-membered and larger rings 10-membered and larger rings 10-membered and larger rings.6 ...

PRUSSIAN BLUE DERIVED CATALYSTS

Prussian blue analog derived catalysts having a composition of highly porous transition metal (“TM”) oxides with nano particle size. Such OER catalysts are synthesized from the PBA, containing cobalt, iron, nickel, copper, manganese, zinc, magnesium etc., as secondary building units (“SBUs”) coordinated by hexacyano-based ligands. Furthermore, the PBA-derived catalysts may also integrated into a highly graphitized carbon network to further improve the conductivity, mass transport and durability against oxidative corrosion. 1. A method of making a catalyst material comprising:preparing Prussian blue analogue having at least one metal;mechanically processing the Prussian blue analogue with graphitized carbon in an organic solvent;forming a Prussian blue analogue and graphitized carbon (PBA/GC) material;applying a thermolysis treatment to the PBA/GC material; andforming a PBA derived metal oxide catalyst material.2. The method of claim 1 , wherein preparing the Prussian blue analogue comprises:dissolving a metal salt in a solution of water and alcohol forming a metal solution;adding an organic ligand solution comprising an organic ligand and an organic ligand solvent; andcollecting the Prussian blue analogue.3. The method of claim 1 , wherein the at least one metal is at least two metals.4. The method of claim 1 , wherein the least one metal is at least three metals.5. The method of claim 1 , wherein the at least one metal is selected from the group consisting of cobalt claim 1 , iron claim 1 , manganese claim 1 , nickel claim 1 , copper claim 1 , zinc claim 1 , lanthanide claim 1 , and actinide.6. The method of claim 1 , wherein the mechanical processing is by ballmilling or grinding.7. The method of claim 1 , wherein prior to mechanical processing the graphitic carbon is sonicated in the organic solvent.8. The method of claim 1 , wherein mechanical processing comprises a ratio between 50:1 to 1:1 of Prussian blue analogue to graphitized carbon.9. The method of claim ...

GOLD-BASED CATALYST FOR OXIDATIVE ESTERIFICATION OF ALDEHYDES TO CARBOXYLIC ACID ESTERS

The present invention relates to novel catalysts for oxidative esterification, by means of which, for example, (meth)acrolein can be converted to methyl (meth)acrylate. The catalysts of the invention are especially notable for high mechanical and chemical stability even over very long periods. This especially relates to an improvement in the catalyst service life, activity and selectivity over prior art catalysts which lose activity and/or selectivity relatively quickly in continuous operation in media having even a small water content. 1: A catalyst particle comprising oxygen , silicon , aluminum , a basic element , gold and at least one element selected from the group consisting of iron , zinc and cobalt ,wherein a maximum gold concentration or a maximum iron, zinc and/or cobalt concentration of the catalyst particle in an outer region which makes up a maximum of 60% of a geometric equivalent diameter is at least 1.5 times as high as a gold concentration or iron, zinc or cobalt concentration in a middle region which makes up the remaining region of the geometric equivalent diameter.2: The catalyst particle according to claim 1 , wherein the particle comprises oxygen claim 1 , silicon claim 1 , aluminum claim 1 , a basic element claim 1 , gold and cobalt.3: The catalyst particle according to claim 1 , wherein the basic element is an alkali metal claim 1 , an alkaline earth metal claim 1 , a rare earth metal or a mixture of one or more of these metals.4: The catalyst particle according to claim 1 , wherein the catalyst particle comprises claim 1 , based on the total molar amount of gold claim 1 , silicon claim 1 , aluminum and basic elements claim 1 , and iron claim 1 , zinc and/or cobalt claim 1 , 0.03 to 3 mol % of gold claim 1 , 40 to 90 mol % of silicon claim 1 , 3 to 40 mol % of aluminum claim 1 , 2 to 40 mol % of the basic element and 0.1 to 20 mol % of iron claim 1 , zinc and/or cobalt claim 1 , where the molar ratio of iron claim 1 , zinc and/or cobalt to ...

EMISSIONS CONTROL SYSTEM INCLUDING CAPABILITY TO CLEAN AND/OR REJUVENATE CZTS SORBENTS, CZTS-ALLOY SORBENTS, AND/OR CZTS-MIXTURE SORBENTS, AND METHOD OF USE

An emissions control system including a fluidized bed apparatus containing a reactive sorbent material is disclosed for gaseous and non-gaseous contaminated emissions. The reactive sorbent material may be CZTS, CZTS-Alloy, or a CZTS-Mixture sorbent material. The fluidized bed apparatus is configured with one or more closed loop sorbent recycling subsystems. The sorbent recycling subsystems include the capability to separate sorbents from each other, separate contaminates from sorbents for disposal and/or recycling, clean and/or rejuvenate sorbents for return to the fluidized bed apparatus, dispose of spent and exhausted sorbents, and replace the spent and exhausted sorbents with new sorbent to maintain consistent sorbent function in the fluidized bed apparatus. Monitoring sensors provide information useful in a method for establishing and maintaining consistent process parameter controls. 1. An emissions control system including a fluidized bed apparatus for removing contaminants from emissions , comprising:a housing shaped as a reverse venturi, said housing including an entry portion for receiving the emissions at a pre-determined entry flow rate, an exit portion for expelling the emissions at a pre-determined exit flow rate, and an enlarged portion disposed between said entry portion and said exit portion of said housing for trapping the contaminants in the emissions;said entry portion, said exit portion, and said enlarged portion of said housing being arranged in fluid communication with each other;a mass of reactive material disposed within said enlarged portion of said housing;said mass of reactive material having a reactive outer surface disposed in contact with the emissions;said mass of reactive material including at least one sorbent; andat least one sorbent recycling subsystem disposed in fluid communication with said housing that receives contaminated sorbent from said housing via at least one sorbent discharge port and returns clean sorbent to said ...

Methods for the oxidative dehydrogenation of butene to produce butadiene

Methods for producing butadiene by the oxidative dehydrogenation of butene are provided. Methods for producing butadiene from a feed stream including oxygen and butene in a molar ratio of oxygen to butene (O 2 /C 4 H 8 ) from about 0.9 to about 1.5 can include introducing the feed stream to a catalyst in the presence of steam. The molar ratio of steam to butene (H 2 O/C 4 H 8 ) can be from about 10 to about 20. Methods can further include reacting the butene to generate a product stream therefrom comprising butadiene and water. Methods can further include separating water from the product stream to generate a butadiene stream including greater than about 85 wt-% butadiene.

CONVERSION OF ALCOHOLS TO HYDROCARBONS USING A DUAL CATALYST SYSTEM COMPRISING BASIC OXIDE ON MIXED OXIDE OR MESOPOROUS CARRIER AND ETCHED METAL LOADED ZEOLITE CATALYST

A method for converting an alcohol to hydrocarbons comprises two serially placed catalysts. The fraction of aromatics is reduced to desired levels. The method comprises: a) contacting the alcohol with a first catalyst on a carrier, said carrier is selected from a mixed oxide and a mesoporous carrier, said first catalyst comprises at least one basic oxide and optionally at least one selected from the group consisting of metals and metal oxides, then b) contacting the resulting mixture from step a) with a second catalyst wherein said second catalyst is an etched metal loaded zeolite catalyst wherein the etched metal loaded zeolite catalyst is manufactured with a method comprising etching with subsequent loading of metal onto the catalyst, wherein the metal is in the form of nanoparticles, and wherein at least two different metals are loaded onto the etched zeolite catalyst. The hydrocarbons are recovered and used for instance for fuel including gasoline, kerosene, diesel, and jet propellant, and jet fuel. Naturally, other uses of hydrocarbons should not be excluded. 1. A method for converting an alcohol to hydrocarbons , said method comprising the steps of:a) contacting the alcohol with a first catalyst on carrier, said carrier is selected from a mixed oxide and a mesoporous carrier, said first catalyst comprises at least one basic oxide and optionally at least one selected from the group consisting of metals and metal oxides,b) contacting the resulting mixture from step a) with a second catalyst wherein said second catalyst is an etched metal loaded zeolite catalyst wherein the etched metal loaded zeolite catalyst is manufactured with a method comprising a step of etching with subsequent loading of metal onto the catalyst, wherein the metal is in the form of nanoparticles, and wherein at least two different metals are loaded onto the etched zeolite catalyst,c) recovering the hydrocarbons resulting from the reaction.2. The method according to claim 1 , wherein the ...

Catalysts for preparation of butadiene by oxydehydrogenation of butene in fluidized bed reactor and method of preparing same and use of same

The invention relates to a catalyst for preparation of butadiene by oxydehydrogenation of butene in a fluidized bed reactor, a method of preparing the same, and use of the same, wherein a method according to an embodiment of the invention comprises: reacting a metal precursor with an alkaline substance to obtain a slurry containing insoluble compound, followed by filtering and washing the slurry; adding a binder and deionized water, followed by agitation to regulate the solid content of the slurry to 10-50%; subjecting the slurry to spray drying granulation, wherein the temperature at the feed port is controlled between 200-400° C., and the temperature at the discharge port is controlled between 100-160° C., to obtain catalyst microspheres; and drying the catalyst microspheres at 80-200° C. for 1-24 h, and then calcining the catalyst microspheres at 500-900° C. for 4-24 h to obtain a catalyst having a general formula of FeXaYbZcOd, comprising Fe, Mg, Zn, Bi, Mo, Mn, Ni, Co, Ba, Ca, and other metals. The catalyst microspheres prepared according to the exemplary method exhibit high mobility, desirable particle size distribution, extremely high mechanical strength and catalytic activity, and are applicable to industrial production of butadiene by oxydehydrogenation of butene in a fluidized bed. When this catalyst is used to prepare butadiene by oxydehydrogenation of butene, the yield of butadiene is 76-86%, and the selectivity to butadiene is 94-97%.

Catalyst and method for the direct synthesis of dimethyl ether from synthesis gas

Catalysts and methods for their manufacture and use for the synthesis of dimethyl ether from syngas are disclosed. The catalysts comprise ZnO, CuO, ZrO 2 , alumina and one or more of boron oxide, tantalum oxide, phosphorus oxide and niobium oxide. The catalysts may also comprise ceria. The catalysts described herein are able to synthesize dimethyl ether directly from synthesis gas, including synthesis gas that is rich in carbon monoxide.

Carbon monoxide conversion catalyst and carbon monoxide conversion method using the same

Process for the continuous hydrogenation of unsaturated fatty alkyl ester

본 발명은 불포화 지방산 알킬 에스테르를 연속적으로 수소화하는 방법에 관한 것으로, 하기 화학식 1로 표시되는 4성분계 금속산화물 촉매의 존재 하에 탄소수가 8~24인 불포화 지방산 알킬 에스테르를 수소화 반응시켜 고정상 반응기에서 연속적으로 제조하는 본 발명에 따른 방법은 요오드값이 0.1이하인 포화 지방산 알킬 에스테르를 고수율로 제조할 수 있다 : The present invention relates to a method for continuously hydrogenating an unsaturated fatty acid alkyl ester, wherein the unsaturated fatty acid alkyl ester having 8 to 24 carbon atoms is hydrogenated in the presence of a four-component metal oxide catalyst represented by the following Chemical Formula 1 to continuously react in a fixed bed reactor. The process according to the present invention can produce saturated fatty acid alkyl esters having an iodine value of 0.1 or less in high yield: [화학식 1] [Formula 1] (NiO) a ·(MgO) b ·(ZnO) c ·(Al 2 O 3 ) d (NiO) a. (MgO) b. (ZnO) c. (Al 2 O 3 ) d 상기 화학식 1에서, a, b, c 및 d는 촉매 총 중량에 대한 함량을 의미하며, a는 40 내지 80중량%이고, b는 1 내지 20중량%이고, c는 0.5 내지 10중량%이고, d는 10 내지 40중량%이다. In Formula 1, a, b, c and d means the content relative to the total weight of the catalyst, a is 40 to 80% by weight, b is 1 to 20% by weight, c is 0.5 to 10% by weight, d is 10 to 40% by weight. 니켈 촉매, 펠렛형 니켈 촉매, 수소화, 불포화 지방산 알킬 에스테르 Nickel catalyst, pelletized nickel catalyst, hydrogenated, unsaturated fatty acid alkyl ester

Catalyst for producing 2,5- furandicarboxlic acid and method for producing 2,5- furandicarboxlic acid using the same

본 발명은 히드록시기 및 카르보닐기를 포함하는 퓨란계 화합물 또는 그 유도체의 카르복시화 촉매로서, 스피넬 구조의 지지체 내에 귀금속 나노 입자가 포함된 2,5-퓨란디카르복시산(FDCA) 제조용 촉매 및 스피넬 구조의 지지체 내에 귀금속 나노 입자가 포함된 촉매 존재 하에, 히드록시기 및 카르보닐기를 포함하는 퓨란계 화합물 또는 그 유도체를 카르복시화시키는 것을 포함하는 것인 2,5-퓨란디카르복시산(FDCA)의 제조방법을 제공한다. 본 발명의 스피넬 구조의 지지체 내에 귀금속 나노 입자가 포함된 촉매를 이용하면, 복잡한 공정을 거치지 않고서도 베이스 프리(base-free) 환경에서 고수율로, 종래 보다 저온, 저압의 공기압(air) 조건으로 FDCA를 수득할 수 있으면서, 부산물의 발생도 최소화 할 수 있다 The present invention relates to a catalyst for the production of 2,5-furan dicarboxylic acid (FDCA) in which noble metal nanoparticles are contained in a support having a spinel structure, and a catalyst for the production of 2,5-furan dicarboxylic acid Furan dicarboxylic acid (FDCA), which comprises carboxylating a furan compound or a derivative thereof containing a hydroxyl group and a carbonyl group in the presence of a catalyst containing noble metal nanoparticles. Using a catalyst containing noble metal nanoparticles in the support of the spinel structure of the present invention, it is possible to achieve a high yield in a base-free environment and a low-temperature, low-pressure air condition FDCA can be obtained, and the occurrence of by-products can be minimized

Crystalline transition metal tungstate

A hydroprocessing catalyst has been developed. The catalyst is a crystalline transition metal tungstate material or metal sulfides derived therefrom, or both. The hydroprocessing using the crystalline transition metal tungstate material may include hydrodenitrification, hydrodesulfurization, hydrodemetallation, hydrodesilication, hydrodearomatization, hydroisomerization, hydrotreating, hydrofining, and hydrocracking.

Highly active quaternary metallic materials using short-chain alkyl quaternary ammonium compounds

A highly active quaternary mixed transition metal oxide material has been developed. The material may be sulfided to generate metal sulfides which are used as a catalyst in a conversion process such as hydroprocessing. The hydroprocessing may include hydrodenitrification, hydrodesulfurization, hydrodemetallation, hydrodesilication, hydrodearomatization, hydroisomerization, hydrotreating, hydrofining, and hydrocracking.

Transition metal molybdotungstate material

A hydroprocessing catalyst or catalyst precursor has been developed. The catalyst is a transition metal molybdotungstate material or metal sulfides derived therefrom. The hydroprocessing using the transition metal molybdotungstate material may include hydrodenitrification, hydrodesulfurization, hydrodemetallation, hydrodesilication, hydrodearomatization, hydroisomerization, hydrotreating, hydrofining, and hydrocracking.

Method for preparing metal complex catalyst and metal complex catalyst prepared thereof

본 명세서는 (A) 아연(Zn) 전구체, 페라이트(Fe) 전구체 및 물을 포함하는 금속 전구체 용액을 염기성 수용액과 접촉시켜 침전물을 얻는 단계; (B) 상기 침전물을 여과하고 소성하여 아연 페라이트 촉매를 얻는 단계; 및 (C) 상기 아연 페라이트 촉매에 산을 담지하는 단계를 포함하는 금속 복합 촉매의 제조방법 및 이에 의해 제조된 금속 복합 촉매에 관한 것이다. (A) a zinc (Zn) precursor, a ferrite (Fe) precursor, and the step of obtaining a precipitate by contacting a metal precursor solution including water with a basic aqueous solution; (B) filtering and firing the precipitate to obtain a zinc ferrite catalyst; And (C) supporting an acid on the zinc ferrite catalyst, and to a metal composite catalyst prepared thereby.

A catalyst article coated with metal oxide, a method for manufacturing the same, and a method for manufacturing 1,3-butadiene using the same

An embodiment of the present invention provides a catalyst molded article coated with metal oxide, a method for manufacturing the same, and a method for manufacturing 1,3-butadiene using the same, wherein the catalyst molded article includes: an inert support; an intermediate layer located on the surface of the inert support; and an active layer located on the surface of the intermediate layer. The active layer comprises catalyst powder and a binder. According to the present invention, the catalyst powder exhibits excellent adhesion and binding force to the support even when a small amount of binder is used.

Method for producing α-amino acid

Hybrid material with multifunctional properties

본 발명은 가시광선 및 자외선 흡수능이 우수한 다기능성 복합소재에 관한 것으로서, 더욱 상세하게는 다음 화학식 1로 표시되는 바와 같이 맥반석, 제올라이트, 실리카, 활성탄, 아파타이트 등의 다공성 물질 또는 벤토나이트, 몬모리로나이트, 카올린 등의 점토류로 구성된 지지체 표면에 특이성 있게 구성된 산화물이 코팅 또는 함침처리되어 있어 가시광선 및 자외선 흡수능이 우수하므로 실외에서는 물론 어두운 실내에서도 우수한 광활성을 나타내어 고체산, 탈취제 및 항균·살균제 등으로 사용되어서도 시간과 장소에 구애받지 않고 지속적으로 활성을 나타내게 되는 다기능성 복합소재에 관한 것이다. The present invention relates to a multifunctional composite material having excellent visible light and ultraviolet light absorbing ability, and more particularly, as shown in the following Chemical Formula 1, porous materials such as elvan, zeolite, silica, activated carbon, apatite, or bentonite and montmorillonite. It is coated or impregnated with an oxide specifically composed on the surface of a support made of clay, kaolin, etc., so it has excellent absorption of visible light and ultraviolet rays, so it shows excellent photoactivity in outdoor as well as in dark rooms.It can be used as a solid acid, deodorant and antibacterial and disinfectant. The present invention relates to a multifunctional composite material which is continuously used regardless of time and place even when used. [A a D d E e O x ] y [지지체] z [A a D d E e O x ] y [Support] z 상기 화학식 1에서: A, D, E, a, d, e, x, y 및 z은 각각 발명의 상세한 설명에서 정의한 바와 같다. In Chemical Formula 1, A, D, E, a, d, e, x, y and z are as defined in the detailed description of the invention, respectively.

Carbon monoxide-selective oxidation catalysts

本发明涉及一氧化碳选择性氧化催化剂。具体地，铈、锆和铜的混合氧化物(CeZrCuO X )的颗粒可制备成催化剂并且用于优先地催化含CO和NH 3 的排出气流中的CO的氧化。在一个实践中，这种CeZrCuO X 催化剂可与下述催化剂组合使用：促进浓燃运转期间排气中的NH 3 的形成的接近联接的PGM催化剂，以及至少一个地板下的NH 3 -SCR催化剂，所述NH 3 -SCR催化剂使用NH 3 作为还原剂在稀燃运转期间催化排出气流中的NO X 的还原。在浓燃发动机运转期间，排出气流可在PGM催化剂的下游掺入氧气并且穿过并接触CeZrCuO X 催化剂的颗粒，以便在NH 3 没有发生氧化或其他转换的情况下使排气中的剩余CO可氧化成CO 2 。

Mesoporous mixed-oxide catalyst including silicon

L'invention concerne un catalyseur oxyde mixte mésoporeux comprenant du silicium et au moins un métal M choisi dans le groupe constitué par les éléments des groupes 4 et 5 du tableau périodique et leurs mélanges, la masse de métal M étant comprise entre 0,1 et 20% de la masse de l'oxyde mixte. De préférence, le catalyseur est préparé par la voie sol-gel moderne métallo-organique. L'invention concerne aussi l'utilisation du catalyseur pour la conversion de l'éthanol en butadiène.

Method for producing catalysts having increased strength and decreased volume reduction

The invention relates to a process for producing copper-containing catalysts, in particular shaped catalyst bodies having increased mechanical strength and a low volume shrinkage, and also the shaped catalyst bodies produced by the process of the invention and the use thereof as catalysts or as precursors and components for catalysts. The catalysts of the invention are particularly suitable for the synthesis of methanol and for the low-temperature conversion of CO into CO 2 .

Chemical recycling of waste plastic materials using improved solvolysis catalysts

混合廃プラスチックの処理のための化学的再生処理施設が提供される。このような施設は、混合プラスチック廃棄物流を処理する能力を有し、かつ種々の再生処理設備、例えば、加溶媒分解設備、熱分解設備、クラッキング設備、部分酸化ガス化設備、エネルギー回収設備、及び固化設備を利用する。これらの個々の設備のうちの１つ以上からの流れを、他の設備のうちの１つ以上への供給流として使用してもよく、それにより価値のある化学成分の回収が最大化され、使用不可の廃棄物流が最小限に抑えられる。【選択図】図１Ａ

An additive and a catalyst composition comprising the additive for fcc process

The present disclosure relates to an additive and a catalyst composition for a catalytic cracking process of vacuum gas oil for preparing cracked run naphtha having reduced liquid olefin content, and increased propylene and butylene yields in the LPG fraction. The process makes use of a catalyst composition which is a mixture of an FCC equilibrated catalyst and an additive comprising a zeolite, phosphorus and a combination of metal promoters. The process is successful in achieving high propylene and butylene yields in the LPG fraction along with a lower liquid olefin content and increased aromatic content with increase in RON unit in the resultant cracked run naphtha, as compared to that achieved using an FCC equilibrated catalyst alone.

Chemical recycling of waste plastic materials with improved solvolysis catalysts

本文提供了用于处理混合废塑料的化学回收设施。这种设施具有处理混合塑料废物流的能力，并利用各种回收设施，例如溶剂分解设施、热解设施、裂化器设施、部分氧化气化设施、能量回收设施和固化设施。来自这些个体设施中的一个或多个的流可以用作一个或多个其它设施的进料，从而使有价值的化学组分的回收最大化，并使不可用的废物流最小化。

Catalyst for conversion of synthesis gas

The disclosed subject matter presents a catalyst or catalyst composition as well as the methods of making and using the catalyst or catalyst composition. In one aspect, the disclosed subject matter relates to a catalyst comprising CoMn a Si b X c Y d O x wherein in X comprises an element from Group 11; Y comprises an element from Group 12; a ranges from 0.8 to 1.2; b ranges from 0.1 to 1; c ranges from 0.01 to 0.05; d ranges from 0.01 to 0.05; x is a number determined by the valency requirements of the other elements present; and wherein the catalyst converts synthesis gas to at least one olefin.

Catalyst Ta-Nb for the production of 1,3-butadiene

The invention relates to a catalyst that comprises a mesoporous oxide matrix, with said matrix comprising at least one oxide of an element X that is selected from among silicon and titanium, taken by itself or in a mixture, with said catalyst comprising at least the tantalum element and the niobium element, with the tantalum mass representing between 0.1 to 30% by weight of the mass of the mesoporous oxide matrix, the niobium mass representing between 0.02 to 6% by weight of the mass of the mesoporous oxide matrix, the content by mass of the tantalum element being greater than or equal to the content by mass of the niobium element. The invention also relates to the use of this catalyst in a method for the production of 1,3-butadiene from a feedstock that comprises at least ethanol.

Highly active quaternary metallic materials using short-chain alkyl quaternary ammonium compounds

A highly active quaternary mixed transition metal oxide material has been developed. The material may be sulfided to generate metal sulfides which are used as catalyst in a conversion process such as hydroprocessing. The hydroprocessing may include hydrodenitrification, hydrodesulfurization, hydrodemetallation, hydrodesilication, hydrodearomatization, hydroisomerization, hydrotreating, hydrofining, and hydrocracking.

Process for preparing catalysts

A process for manufacturing a catalyst composition comprises the steps of (i) precipitating one or more metal compounds from solution using an alkaline precipitant, preferably comprising an alkaline carbonate, optionally in the presence of a thermostabilizing material, ii) ageing the precipitated composition, and (iii) recovering and drying the aged composition, wherein the ageing step is performed using a pulse-flow reactor.

Methanol process

Fe-based hydrogenation catalyst and use thereof

The present invention relates to a Fe-based hydrogenation catalyst having Fe as a primary active metal component, and zinc and potassium as a first co-active metal component. The molar ratio of the primary active metal component to the first co-active metal component is 0.5-200:1. The Fe-based hydrogenation catalyst in present invention overcomes the problem of limiting to the active metal components as used over decades for the conventional hydrogenation catalyst, and thus has long-term values for industrial application.

Conversion of methane to ethylene comprising integration with the in-situ ethane cracking and direct conversion of co2 byproduct to methanol

Methods and catalysts for producing ethylene and methanol from natural gas are presented. Methods include integration of oxidative conversion of methane to ethane, ethane in situ thermal cracking using the thermal heat generated thereby and direct hydrogenation of byproducts to methanol or oxidative CO2 autothermal reforming of methane to syngas.

Hydrogenation catalyst for heavy hydrocarbon oil, production method for hydrogenation catalyst for heavy hydrocarbon oil, and hydrogenation method for heavy hydrocarbon oil

The hydrogenation catalyst for heavy hydrocarbon oil, includes: as a carrier, phosphorous-zinc-containing alumina that contains 0.1% by mass to 4% by mass, in terms of oxide based on the carrier, of phosphorous and 1% by mass to 12% by mass, based on the carrier, of zinc oxide particles, and supporting, on the carrier, 8% by mass to 20% by mass, in terms of oxide based on the catalyst, of at least one selected from metals in Group 6 of the periodic table and 2% by mass to 6% by mass, in terms of oxide based on the catalyst, of at least one selected from metals in Groups 8 to 10 of the periodic table, and the average particle diameter of the zinc oxide particles being 2 μm to 12 μm.

Process for vapor phase hydrogenation

A process for selective formation of ethanol from acetic acid includes contacting a feed stream containing acetic acid and hydrogen at an elevated temperature with catalyst comprising platinum and tin on a high surface area silica promoted with calcium metasilicate. Selectivities to ethanol of over 85% are achieved at 280° C. with catalyst life in the hundreds of hours.

Highly active quaternary metallic materials using short-chain alkyl quaternary ammonium compounds

Method for producing ethanolamines and/or ethyleneamines

The invention relates to a method for producing ethanolamines and/or ethyleneamines in the gas phase by reacting ethylene glycol with ammonia in the presence of an amination catalyst. The method is characterized in that the amination catalyst is produced by reducing a calcined catalyst precursor, which comprises an active mass, wherein the active mass contains one or more active metals selected from the group consisting of the elements of groups 8, 9, 10, and 11 of the periodic table of the elements and optionally contains one or more catalyst additional elements selected from the group consisting of the metals and semimetals of groups 3 to 7 and 12 to 17, the element P and the rare-earth elements. Furthermore, the method is characterized in that a catalyst precursor having a low basicity is used, wherein the low basicity is achieved in that a) the catalyst precursor is produced by co-precipitation and the active mass additionally contains one or more alkaline elements selected from the group consisting of the alkali metals and alkaline-earth metals; or b) the catalyst precursor also contains a carrier material in addition to the active mass and is produced by impregnation of the carrier material or precipitation onto the carrier material and the carrier material contains one or more alkaline elements selected from the group consisting of the alkali metals, Be, Ca, Ba and Sr or contains one or more minerals selected from the group consisting of hydrotalcite, chrysotile and sepiolite; or c) the catalyst precursor also contains a carrier material in addition to the active mass and is produced by impregnation of the carrier material or precipitation onto the carrier material and the active mass of the catalyst carrier contains one or more alkaline elements selected from the group consisting of the alkali metals and alkaline-earth metals; or d) the catalyst precursor is calcined at temperatures of 600°C and greater; or e) the catalyst precursor is produced by a ...

Gas clean-up for alkane oxidative dehydrogenation effluent

The invention relates to a process for the production of an alkene by alkane oxidative dehydrogenation, comprising: (a) subjecting a stream comprising an alkane to oxidative dehydrogenation conditions, comprising contacting the alkane with oxygen in the presence of a catalyst comprising a mixed metal oxide, resulting in a stream comprising alkene, unconverted alkane, water, carbon dioxide, unconverted oxygen, carbon monoxide and optionally an alkyne; (b) removing water from at least part of the stream comprising alkene, unconverted alkane, water, carbon dioxide, unconverted oxygen, carbon monoxide and optionally an alkyne resulting from step (a), resulting in a stream comprising alkene, unconverted alkane, carbon dioxide, unconverted oxygen, carbon monoxide and optionally alkyne; (c) removing unconverted oxygen, carbon monoxide and optionally alkyne from at least part of the stream comprising alkene, unconverted alkane, carbon dioxide, unconverted oxygen, carbon monoxide and optionally alkyne resulting from step (b), wherein carbon monoxide and optionally alkyne are oxidized into carbon dioxide, resulting in a stream comprising alkene, unconverted alkane and carbon dioxide; (d) optionally removing carbon dioxide from at least part of the stream comprising alkene, unconverted alkane and carbon dioxide resulting from step (c), resulting in a stream comprising alkene and unconverted alkane; (e) optionally separating at least part of the stream comprising alkene and unconverted alkane resulting from step (d), into a stream comprising alkene and a stream comprising unconverted alkane; (f) optionally recycling unconverted alkane from at least part of the stream comprising unconverted alkane resulting from step (e), to step (a).

Tablet-form copper manganese-based catalyst with increased stability against the action of acid

The invention relates to a copper manganese-based catalyst on the basis of a tablet-form shaped catalyst body, comprising calcium aluminate as a binder, for hydrating carbonyl groups in organic compounds, characterised in that said shaped catalyst body comprises calcium aluminate in an amount of 0.5 to 20 wt.%. The invention also relates to the production of the catalyst and to the use of same in the hydration of carbonyl groups in organic compounds.

Preparation method of propylene epoxidation catalyst and use thereof

본 발명에서는 프로필렌 에폭시화 촉매의 제조 방법 및 용도를 개시하였으며, 제조시, 조제된 활성 조성분의 알코올염 용액을 실리카겔 담체와 혼합한 후, 회전 증발 처리를 진행하여 저탄소 알코올을 제거하여 촉매 전구체를 얻은 후, 얻은 촉매 전구체에 대해 배소 및 실릴화 처리를 진행하여 프로필렌 에폭시화 촉매를 얻는다. 해당 촉매의 제조 과정은 간단하고, 프로필렌 에폭시화로 프로필렌 옥사이드를 제조하는 화학공업 과정에 사용될 수 있으며, 프로필렌 옥사이드에 대한 평균 선택성이 높음으로써 산업화 응용 전망을 구비한다. In the present invention, a method for preparing and using a propylene epoxidation catalyst is disclosed, and during preparation, an alcohol salt solution of an active component prepared is mixed with a silica gel carrier, and then rotary evaporation is performed to remove low-carbon alcohol to obtain a catalyst precursor After that, the obtained catalyst precursor is roasted and silylated to obtain a propylene epoxidation catalyst. The preparation process of this catalyst is simple, it can be used in the chemical process of producing propylene oxide by propylene epoxidation, and has a high average selectivity to propylene oxide, so it has industrial application prospects.

Upgrading fusel oil mixtures over heterogeneous catalysts to higher value renewable chemicals

This present disclosure relates to catalytic processes for upgrading crude and/or refined fusel oil mixtures to higher value renewable chemicals, via mixed metal oxide or zeolite catalysts. Disclosed herein are processes passing a vaporized stream of crude and/or refined fusel oils over various mixed metal oxide catalysts, metal doped zeolites, or non-metal doped zeolites and/or metal oxides providing options to valorize fusel oil mixtures to higher value products. Renewable chemicals formed, via these upgrading catalyst platforms, are comprised of, but not limited to, methyl isobutyl ketone (MIBK), di-isobutyl ketone (DIBK), isoamylene, and isoprene.

Tablet-form copper manganese-based catalyst with increased stability against the action of acid

The invention relates to a copper manganese-based catalyst on the basis of a tablet-form shaped catalyst body, comprising calcium aluminate as a binder, for hydrating carbonyl groups in organic compounds, characterised in that said shaped catalyst body comprises calcium aluminate in an amount of 0.5 to 20 wt. %. The invention also relates to the production of the catalyst and to the use of same in the hydration of carbonyl groups in organic compound.

Gas cleanup for alkane oxidative dehydrogenation effluents

本发明涉及通过烷烃氧化脱氢制备烯烃的方法，包括：(a)使包含烷烃的流经受氧化脱氢条件，包括在包含混合金属氧化物的催化剂存在下使烷烃与氧气接触，产生包含烯烃、未转化的烷烃、水、二氧化碳、未转化的氧气、一氧化碳和任选的炔烃的流；(b)从步骤(a)得到的包含烯烃、未转化的烷烃、水、二氧化碳、未转化的氧气、一氧化碳和任选的炔烃的流的至少部分除去水，得到包含烯烃、未转化的烷烃、二氧化碳、未转化的氧气、一氧化碳和任选的炔烃的流；(c)从步骤(b)得到的包含烯烃、未转化的烷烃、二氧化碳、未转化的氧气、一氧化碳和任选的炔烃的流的至少一部分中除去未转化的氧气、一氧化碳和任选的炔烃，其中一氧化碳和任选的炔烃被氧化成二氧化碳，产生包含烯烃、未转化的烷烃和二氧化碳的流；(d)任选地从步骤(c)得到的包含烯烃、未转化的烷烃和二氧化碳的流的至少部分中除去二氧化碳，得到包含烯烃和未转化的烷烃的流；(e)任选地将由步骤(d)得到的包含烯烃和未转化的烷烃的流的至少部分分离成包含烯烃的流和包含未转化的烷烃的流；(f)任选地将未转化的烷烃从步骤(e)得到的包含未转化的烷烃的流的至少部分中循环至步骤(a)。

Process for producing chlorotrifluoroethylene.

La presente invención se refiere, al menos en parte, a un proceso para preparar clorotrifluoroetileno (CFO-1113) a partir de 1,2-dicloro-1,1,2-trifluoroetano (HCFC-123a). En ciertos aspectos, el proceso incluye la deshidrocloración de 1,2-dicloro-1,1,2-trifluoroetano (HCFC-123a) en presencia de un catalizador seleccionado del grupo que consiste en (i) uno o más haluros metálicos; (ii) uno o más óxidos metálicos halogenados; (iii) uno o más metales de valencia cero o aleaciones metálicas; (Iv) combinaciones de los anteriores.

Iron-potassium-cerium complex oxide catalyst, and its preparation and use

철-칼륨-세륨계 복합 산화물 촉매, 그 제조 및 용도가 개시되고, 상기 촉매는 금속 원소 Fe, K 및 Ce 외에, IIA족 금속 원소, Cr 이외의 VIB족 금속 원소, 및 IVA족 금속 원소로 이루어지는 군으로부터 선택되는 적어도 하나인 금속 원소 M을 포함하고, 상기 촉매는 0.32-0.46 mmol/g, 바람직하게 0.32-0.42 mmol/g의 총 알칼리 함량, 및 0.061-0.082 mmol/g의 강알칼리 함량을 가진다. 알킬 방향족 화합물의 탈수소화에 사용될 때, 상기 촉매는 낮은 탈수소화 온도 및 초저 증기-대-오일 비에서도, 높은 선택도, 높은 촉매 활성 및 높은 안정성을 나타내고, 적은 부산물을 제공하고, 낮은 물질 소비 및 낮은 전력 소비의 특징을 가진다.

The method for producing ethanol amine and/or ethylene amines

本发明涉及一种通过在胺化催化剂存在下使乙二醇与氨反应而在气相中制备乙醇胺和/或亚乙基胺的方法。该方法的一个特征在于所述胺化催化剂通过还原包含活性组合物的煅烧催化剂前体制备，其中所述活性组合物包含选自元素周期表第8、9、10和11族的元素的一种或多种活性金属和任选一种或多种选自第3至7和12至17族的金属和半金属、元素P和稀土元素的附加催化剂元素。该方法的另一特征在于使用具有低碱度的催化剂前体，所述低碱度如下实现：a)所述催化剂前体通过共沉淀制备且所述活性组合物另外包含选自碱金属和碱土金属的一种或多种碱性元素；或b)所述催化剂前体除活性组合物外还另外包含载体材料并通过浸渍载体材料或沉淀施加至载体材料上而制备且所述载体材料包含选自碱金属、Be、Ca、Ba和Sr的一种或多种碱性元素或选自水滑石、温石棉和海泡石的一种或多种矿物；或c)所述催化剂前体除活性组合物外还另外包含载体材料并通过浸渍载体材料或沉淀施加至载体材料上而制备且所述催化剂载体的活性组合物包含选自碱金属和碱土金属的一种或多种碱性元素；或d)在600℃或更高的温度下煅烧所述催化剂前体；或e)通过方案a)和d)的组合或通过方案b)和d)的组合或通过方案c)和d)的组合制备所述催化剂前体。

Catalyst for oxidative esterification of aldehydes to carboxylic acid esters

Die vorliegende Erfindung betrifft neuartige Katalysatoren für die oxidative Veresterung, mittels derer beispielsweise (Meth)acrolein zu Methyl(meth)acrylat umgesetzt werden kann. Die erfindungsgemäßen Katalysatoren zeichnen sich dabei insbesondere durch eine hohe mechanische und chemische Stabilität auch über sehr lange Zeiträume aus. Dies betrifft insbesondere eine Verbesserung der Katalysatorstandzeit, der Aktivität und der Selektivität gegenüber Katalysatoren des Standes der Technik, die in Medien mit auch geringem Wassergehalt im kontinuierlichen Betrieb relativ schnell Aktivität und/oder Selektivität verlieren. The present invention relates to novel catalysts for the oxidative esterification, by means of which, for example, (meth) acrolein can be converted to methyl (meth) acrylate. The catalysts of the invention are characterized in particular by a high mechanical and chemical stability even over very long periods. This relates in particular to an improvement in the catalyst lifetime, the activity and the selectivity over prior art catalysts which relatively rapidly lose activity and / or selectivity in media with even low water content in continuous operation.

Nitrous oxide decomposition catalyst

The present invention provides a catalyst for the decomposition of nitrous oxide, said catalyst comprising oxides of cobalt, zinc and aluminum and an alkali metal promoter.

Methods for the valorization of carbohydrates

There are provided methods for the valorization of carbohydrates. The methods comprise reacting a fluid comprising at least one carbohydrate with at least one metal catalyst or at least one metal catalytic system in a fluidized bed reactor so as to obtain at least one organic acid or a derivative thereof.

Hydrogenolysis catalysts with high acid tolerance

METHOD FOR PREPARING SILICON AND/OR GERMANIUM NANOWIRE

L'invention concerne un procédé de préparation d'un matériau à base de nanofils de silicium et/ou de germanium, comprenant les étapes de : i) mise en contact d'une source de silicium et/ou d'une source de germanium avec un catalyseur comprenant un sulfure de métal binaire ou un sulfure de métaux multinaire, le ou lesdits métaux étant choisis parmi Sn, In, Bi, Sb, Ga, Ti, Cu, et Zn, ce par quoi on obtient des nanofils de silicium et/ou de germanium, ii) éventuellement récupération des nanofils de silicium et/ou de germanium obtenus à l'étape (i) ; le catalyseur, et éventuellement la source de silicium et/ou la source de germanium, étant chauffé avant, pendant, et/ou après la mise en contact dans des conditions de température et de pression permettant la croissance des nanofils de silicium et/ou de germanium. The invention relates to a method for preparing a material based on silicon and/or germanium nanowires, comprising the steps of: i) bringing a source of silicon and/or a source of germanium into contact with a catalyst comprising a binary metal sulphide or a multinary metal sulphide, the said metal(s) being chosen from among Sn, In, Bi, Sb, Ga, Ti, Cu, and Zn, whereby silicon nanowires and/or or germanium, ii) optionally recovering the silicon and/or germanium nanowires obtained in step (i); the catalyst, and optionally the source of silicon and/or the source of germanium, being heated before, during, and/or after the bringing into contact under temperature and pressure conditions allowing the growth of the silicon nanowires and/or germanium.

Environmental-friendly liquid fuel and production process thereof

The present invention discloses a liquid fuel and production process thereof, the liquid fuel comprises dialkyl carbonates with the structural formula of wherein R and R′ are same or different, and R and R′ are selected from the group consisting of C1-C8 linear chain alkyl, C3-C8 branched chain alkyl, C3-C8 naphthene base and alkyl containing furan ring. The process of the production of the liquid fuel comprises the steps of: performing a cycloaddition reaction between 2-methyl tetrahydrofuran produced by hydrogenation from furfural which is a biomass derivative and carbon dioxide to produce a cyclic carbonate (i.e. 1,4-pentanediol carbonate), then performing an ester exchange reaction between the cyclic carbonate and monohydric alcohol to produce the dialkyl carbonate. The liquid fuel produced is clean, safe and biodegradable, and the process provides a new way for industrial production of the dialkyl carbonate with remarkable economic and social benefit.

Gas phase heterogeneous catalytic oxidation of alkanes to aliphatic ketones and/or other oxygenates

A catalyst, its method of preparation and its use for producing aliphatic ketones by subjecting alkanes C 3 to C 9 to a gas phase catalytic oxidation in the presence of air or oxygen, and, optionally, steam and/or one or more diluting gases. The catalyst comprises a catalytically active mixed metal oxide phase and a suitable support material onto and/or into which the active catalytic phase id dispersed.

Catalyst molded product coated with metal oxide, method for producing same, and 1,3-butadiene production method using same

An embodiment of the present invention provides: a catalyst molded product including an inert support, an intermediate layer positioned on the surface of the inert support, and an active layer positioned on the surface of the intermediate layer, wherein the active layer includes a catalyst powder and a binder; a method for producing same; and a 1,3-butadiene production method using same.

Preparation method of two-dimensional IRPY type MOF material and functionalized M @ IRPA-MOF supported catalyst

一种二维IRPY型MOF材料及功能化M@IRPA‑MOF负载型催化剂的制备方法，通过对合成条件的调控，使其具有不同的配位模式，从而形成具有不同结构特点的MOFs框架，提供不同的催化活性，我们设计合成了系列可后修饰的稳定MOF材料(含氨基取代基)，进一步负载金属离子，得到系列具有二维层状结构的功能化M@IRPA‑MOF负载型催化剂，并能够展现出良好的催化效率和可循环性。弥补有机Rh催化剂费用高，均相联吡啶催化剂不可循环使用的缺点，为新型、绿色催化体系的研发提供理论基础。

A kind of oxalate hydrogenation catalyst and preparation method thereof

本发明公开了一种草酸酯加氢催化剂及其制备方法，该催化剂活性组分为铜，占催化剂组成的3‑60wt％，助剂为镁、银、镉所组成群组中的至少一种或其氧化物，占催化剂组成的0.1‑20wt％，载体为氧化锌、二氧化钛、氧化钙中的一种或几种，占催化剂组成的5‑78.9wt％。催化剂采用超声环境下的共沉淀法制备，一方面确保沉淀剂添加后能迅速扩散，沉淀颗粒大小均匀，另一方面，沉淀后形成的颗粒小，活性组分分散性更高。本发明提供的草酸酯加氢催化剂，可以解决现有草酸酯加氢催化剂乙二醇选择性低、稳定性差的问题，通过该方法制备的催化剂活性组分抗烧结温度高、活性组分分散性好，且制备工艺简单，生产成本低。