21-07-2016 дата публикации
Номер: US20160211137A1
Compositions, systems, and methods are described for implanting silicon and/or silicon ions in a substrate, involving generation of silicon and/or silicon ions from corresponding silicon precursor compositions, and implantation of the silicon and/or silicon ions in the substrate. 1. A method of implanting silicon and/or silicon ions in a substrate , comprising:generating silicon or silicon-containing ions from a composition comprising silicon precursor selected from the group consisting of:{'sup': 1', '2', '3', '4', '1', '2', '3', '4', '1', '2', '1', '2, 'sub': n', '2n-1', 'n', '2n-1', 'n', '2n', '2', '1', '10', '1', '10, '(a) monosilanes of the formula SiRRRRwherein each of R, R, R, and Rcan independently be: H; halogen (F, Cl, Br, I); hydroxy; alkoxy; acetoxy; amino; alkyl of the formula CHwherein n=1-10, optionally substituted with hydroxy, alkoxy, acetoxy, and/or amino; cycloalkyl, bi- and polycycloalkyl, of the formula CHwherein n=1-10, optionally substituted with hydroxy, alkoxy, acetoxy, and/or amino; alkenyl of the formula CHincluding a C═C bond, wherein n=1-10, optionally substituted with hydroxy, alkoxy, acetoxy, and/or amino; aryl, including phenyl and aromatic moieties; alkylene including functionality of the formula ═CHand C RRwherein each of Rand Ris as specified above, optionally substituted with hydroxy, alkoxy, acetoxy, and/or amino; alkylyne, including functionalities of the formulae ≡CH and ≡CR wherein R is C-Calkyl, hydroxyl, halogen, or amino derivative of alkyl; or acyloxyl of the formula —OOCR wherein R is C-Calkyl, hydroxyl, halogen, or amino derivative of alkyl;'}{'sub': n', 'y', 'n, 'sup': 1', '2', 'y', '1', '2', 'y', '1', '2', '3', '4, '(b) di- and polysilanes of the formula SiHcomprising at least one Si—Si bond, wherein n=1-8, and y=2n+2 for unbranched and branched chains, and y=2n for cyclic compounds and corresponding substituted di- and polysilanes of the formula SiRR. . . Rwherein n=1-8 and each of R, R. . . Ris as specified for each ...
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