ULTRA-LOW WATER INPUT OIL SANDS RECOVERY PROCESS
This application is a continuation of U.S. patent application Ser. No. 14/694,375, filed on Apr. 23, 2015, and hereby incorporates such application in its entirety by reference. The present invention is a system and a method for processing oil sands in which oil sands material is subjected to a predistillation process. As is well known in the art, the typical systems and methods for processing oil sands are relatively complex, and require significant water and energy inputs. In particular, the typical processes involve the use and contamination of large volumes of water and the creation of large waste (tailings) ponds. Large volumes of CO2emissions (and emissions of other gases, e.g., NOx, SOx, and H2S) are generated by heating the large volumes of water by combustion of fossil fuels, to the extent that oil sands processing has become a major contributor of CO2emissions. Because the conventional systems and methods typically involve transporting oil sands, and waste sand resulting from the processing thereof, over relatively large distances, significant maintenance costs are also incurred due to the abrasion to which equipment is subjected. A typical process of the prior art is schematically illustrated in In connection with conventional processing, hot water (typically heated by natural gas) is also added, at step 26. As is well known in the art, a large amount of water is used in this step. In step 28, a portion of the sand is separated from crude bitumen (i.e., liquid or semi-solid raw petroleum) in the oil sand. More hot water is added at the initial separation of sand and bitumen, at step 30. Following sedimentation (step 32), the waste is sent to a waste pond (step 34). The bitumen, and the portion of the sand remaining with the bitumen at this point, is then cleaned (step 36). In this step, the sand typically is cleaned with naphtha, to remove any bitumen remaining with the sand at this point. The sand removed in this step is also sent to sedimentation (step 38), and subsequently to the waste pond (step 40). The bitumen remaining is then upgraded (step 42), and the bitumen is subsequently mixed with diluents to form “dilbit” (step 44). The diluents are less viscous than the bitumen, so that the viscosity of the dilbit is such that the dilbit can be pumped. The dilbit mixture of diluents and bitumen is then transported to a refinery (step 46), at which the bitumen and the diluents are separated, and the bitumen is refined to produce high-value products. Such high-value products include, for example, gasoline, diesel fuel, naphtha, and petrochemical feedstock. The many disadvantages of the conventional processing described above are well known in the art. For instance, the conventional processes consume up to five barrels of water for every barrel of extracted bitumen. The waste ponds (also referred to as tailings ponds) required in connection with conventional processing cover large areas and emit toxic compounds such as volatile organic compounds and toxic effluents to the surrounding environment (e.g., into the Athabasca River). The widespread modified landscapes resulting from mining are also sources of harmful substances, and substantial costs are incurred in connection with reclamation efforts. In addition, the diluents used in the dilbit (i.e., to reduce viscosity) are high-value products that could be profitably used elsewhere. As is well known in the art, the dilbit typically is transported thousands of kilometers via pipeline or railroads. This necessity creates significant risks, the most important of which is the risk of environmental damage due to a break or leak. Because of the nature of the components of dilbit, a spill of dilbit into the environment typically has serious consequences. When dilbit is released in an uncontrolled manner, the dilbit is initially relatively less viscous (i.e., due to its diluents content), and readily drains into the ground or water near the pipeline. However, shortly after the dilbit's release and drainage into the ground, the diluents tend to escape into the atmosphere, ultimately resulting in a more viscous residue (consisting primarily of the bitumen in the dilbit) distributed in the soil or water. As a practical matter, remediation of the viscous residue is difficult. The activities in a group identified as “A” in There is a need for a system that overcomes or mitigates one or more of the disadvantages or defects of the prior art. Such disadvantages or defects are not necessarily included in those described above. In its broad aspect, the invention provides a method of processing raw oil sands material that includes bitumen. The method includes subjecting an oil sands material including the raw oil sands material to a predistillation process that begins with heating the oil sands material to between approximately 350° C. and approximately 400° C., to produce atmospheric gas oil from the bitumen, and intermediate dried oil sands material. The intermediate dried oil sands material is heated to between approximately 535° C. and at least approximately 600° C., to produce vacuum gas oil and coked oil sands material that includes carbon-heavy hydrocarbons and sand. The coked oil sands material is heated to approximately 900° C., to produce a dry barren hot oil sands material and syngas including hydrogen and carbon monoxide gases. Heat energy is transferred from at least a portion of the barren hot oil sands material to at least one of the oil sands material and the intermediate dried oil sands material. In another of its aspects, the invention provides a method of processing raw oil sands material that includes free water and bitumen, produced from a mine. The method includes preheating a preheat oil sands material including the raw oil sands material to between approximately 100° C. and approximately 150° C. to convert the free water to steam, to release the free water from the raw oil sands material and to form a dried oil sands material from the preheat oil sands material. In a first predistillation step, the dried oil sands material is heated to between approximately 350° C. and approximately 400° C. to partially vaporize the bitumen, to provide atmospheric gas oil from the bitumen, and intermediate dried oil sands material. In a second predistillation step, the intermediate dried oil sands material is heated to between approximately 535° C. and at least approximately 600° C. to further at least partially vaporize the bitumen, to provide vacuum gas oil, and coked oil sands material that includes carbon-heavy hydrocarbons and sand. In a gasifier, the coked oil sands material is heated to approximately 900° C. for gasification thereof, to provide syngas including hydrogen and carbon monoxide gases retaining syngas heat energy therein, and a dry barren hot oil sands material retaining sand heat energy therein. Heat energy is transferred from at least a portion of the barren hot oil sands material to at least one of the preheat oil sands material and the dried oil sands material and the intermediate dried oil sands material. In another aspect, the invention provides a method of processing raw oil sands material that includes free water and bitumen, produced from a mine. The method includes preheating a preheat oil sands material including the raw oil sands material to between approximately 100° C. and approximately 150° C. to convert the free water to steam, to release the free water from the raw oil sands material and to form a dried oil sands material from the preheat oil sands material. In a predistillation process, the dried oil sands material is heated to between approximately 535° C. and at least approximately 600° C. to at least partially vaporize the bitumen, to provide atmospheric gas oil and vacuum gas oil from the bitumen, and to provide coked oil sands material that includes carbon-heavy hydrocarbons and sand. In a gasifier, the coked oil sands material is heated to approximately 900° C. for gasification thereof, to provide syngas including hydrogen and carbon monoxide gases retaining syngas heat energy therein, and a dry barren hot oil sands material retaining sand heat energy therein. Heat energy is transferred from at least a portion of the barren hot oil sands material to at least one of the preheat oil sands material and the dried oil sands material. In yet another of its aspects, the invention provides a method of processing raw oil sands material including bitumen. The method includes, in a predistillation process, heating the raw oil sands material to between approximately 535° C. and at least approximately 600° C. to at least partially vaporize the bitumen, to provide atmospheric gas oil and vacuum gas oil from the bitumen, and to provide coked oil sands material that includes carbon-heavy hydrocarbons and sand. The coked oil sands material is heated to approximately 900° C., to produce a dry barren hot oil sands material, and syngas including hydrogen and carbon monoxide gases. Heat energy is transferred from at least a portion of the barren hot oil sands material to the raw oil sands material. The invention will be better understood with reference to the attached drawings, in which: In the attached drawings, like reference numerals designate corresponding elements throughout. Reference is first made to In one embodiment, the atmospheric gas oil 156 preferably is refined ( Because of the temperature gradient of the predistillation process 152, the atmospheric gas oil 156 and the vacuum gas oil 162 are produced sequentially in the process. The atmospheric gas oil 156 and the vacuum gas oil 162 therefore may be captured substantially separately, and subsequently processed (i.e., refined) separately, in steps 172 and 174 respectively. Alternatively, it is possible to subject the oil sands material 151 to a predistillation process in which the atmospheric gas oil and the vacuum gas oil are not captured separately. For example, the oil sands material 151 may be heated to between approximately 535° C. and at least approximately 600° C., producing a mixture of the volatiles (i.e., a mixture of the atmospheric gas oil and the vacuum gas oil). In these circumstances, the atmospheric gas oil would be produced when the oil sands material is heated to between approximately 350° C. and approximately 400° C., and the vacuum gas oil would be produced when the oil sands material is further heated to between approximately 535° C. and at least approximately 600° C. In this alternative arrangement, the atmospheric gas oil and the vacuum gas oil would then be subjected to further processing together, to produce various petroleum products. Although this alternative may impose some limitations or additional requirements in the further processing of the atmospheric gas oil and the vacuum gas oil, it may be acceptable in some circumstances. In one embodiment, the syngas 170 preferably is further subjected to one or more gas-to-liquid processes (step 115) to provide one or more of gasoline, diesel fuel, naphtha, and petrochemical feedstock. In summary, in the method of the invention, volatiles (in the form of the atmospheric gas oil and the vacuum gas oil) are removed from oil sands material including bitumen by heating the oil sands material, in a predistillation process. The volatiles may be further processed to produce petroleum products. Coked oil sands material is also produced from the predistillation process. The coked oil sands material is subjected to a gasification process, in which molecule-changing chemical reactions provide a syngas that also may be further processed to produce petroleum products. Advantageously, the invention does not require the large inputs of water that are required in the prior art. Once the methods of the invention are functioning in a steady state, the energy requirements may be satisfied to a large extent by recovering energy from different products and by-products of the methods. It will be understood that the oil sands material 151 preferably includes raw oil sands material 178, produced from a mine 180 ( Preferably, and as illustrated in Those skilled in the art would also appreciate that the “sand” component of the oil sands may include various rock and soil materials, e.g., both sand (i.e., relatively small rock and/or mineral particles) and clay. As is also well known in the art, in addition to the bitumen thereof, the oil sands material typically also includes free water. The free water content varies, depending on a number of factors. For example, the free water content may be approximately 4 percent by weight. An embodiment of a system 194 of the invention is schematically illustrated in As will be described, in embodiments of the invention, heat energy is at least partially recoverable from certain products of the methods of the invention, and utilized elsewhere in the invention. Also, in certain circumstances (described below), the introduction of additional materials or substances retaining heat energy (e.g., hot air, or steam) may be advantageous. The recovery of part of the heat energy from certain products of the invention, and the utilization of heat energy from steam or hot air introduced into the system, preferably is effected via an energy recovery system (“ERS”). In an alternative embodiment of the system 294 ( For instance, in one embodiment, the appropriately sized raw oil sands material 178 preferably is mixed in the mixer/preheater 286 ( In an alternative embodiment schematically illustrated in It is also preferred that the method 250 additionally includes the step of, in the gasifier 184 ( In one embodiment, the steam 290 preferably is added to the coked oil sands 164 during the gasification thereof, to provide at least a portion of the hydrogen gas in the syngas 170 ( In another embodiment, and as noted above, the oil sands material 151 preferably also includes at least a portion of the barren hot oil sands material 168, and the preheating is at least partially effected by transfer of a portion of the sand heat energy to the raw oil sands material 178 ( In another alternative embodiment, at least a portion of the heat energy in the barren hot oil sands material 168 preferably is transferred to the dried oil sands material 288 ( It will be understood that, in connection with the method 150 of the invention, the barren hot oil sands material 168 may be recycled to the first predistillation step 154, to recover at least a portion of the heat energy retained in the barren hot oil sands material 168. In It is also preferred that at least a portion of the heat energy in the barren hot oil sands material 168 is transferred to the intermediate dried oil sands material 158 ( It will be understood that a portion of the heat energy in the barren hot oil sands material 168 may also be utilized in the second predistillation step 160 of the method 150. In It is also preferred that, prior to the gasification of the coked oil sands material 164, at least a portion of the syngas heat energy from previously produced syngas 170 is transferred to the coked oil sands material 164, to heat the coked oil sands material 164 to between approximately 650° C. and approximately 750° C. ( It will be understood that a portion of the heat energy in the barren hot oil sands material 168 may also be utilized to heat the coked oil sands material 164 in the method 150, illustrated in Other means for adding heat energy at selected points in the method of the invention may be advantageous, depending on the circumstances. For instance, in one embodiment, the method of the invention preferably also includes heating fresh water ( In another embodiment of the method of the invention, air preferably is heated to between approximately 650° C. and approximately 750° C. ( Those skilled in the art would appreciate that the composition of the syngas 170 as generated by gasification may not be consistent with a desired composition (i.e., desired for purposes of further processing). The composition of the syngas 170 may be altered in a syngas balancer 109 ( However, it has been determined that, in one embodiment, the additional gas(es) 111 preferably includes a natural gas-derived syngas resulting from combustion of natural gas. As an example, it may be intended to direct the syngas 170 to a gas-to-liquids facility 113 ( Those skilled in the art would appreciate that the syngas 170 and/or the balanced syngas 170′ may be processed in any suitable way, in any suitable facility. The gas-to-liquids facility is one example of a facility in which the syngas and/or balanced syngas may be further processed. It may be necessary or advisable to utilize one or more secondary crushers 117, to provide the coked oil sands material 164 in a form suitable for gasification. As illustrated in It will also be understood that, in one embodiment, the barren hot oil sands material 168 preferably is transported to the mine 180 for backfilling therein. Those skilled in the art would appreciate that the barren hot oil sands material 168 would have the advantage (i.e., over backfilling using the prior art materials) that it is accompanied by virtually no water. The method 250 of the invention was modeled, and the results are provided in Tables 1 and 2 below. The results are also schematically illustrated in The method 150 of the invention is also schematically illustrated in Among the benefits and advantages of the processes of the invention are the following.
It will be appreciated by those skilled in the art that the invention can take many forms, and that such forms are within the scope of the invention as claimed. The scope of the claims should not be limited by the preferred embodiments set forth in the examples, but should be given the broadest interpretation consistent with the description as a whole. A method of processing raw oil sands material that includes bitumen. The method includes, in a predistillation process, heating the raw oil sands material to between approximately 535° C. and at least approximately 600° C. to at least partially vaporize the bitumen, to provide atmospheric gas oil and vacuum gas oil from the bitumen, and to provide coked oil sands material that includes carbon-heavy hydrocarbons and sand. The coked oil sands material is heated to approximately 900° C., to produce a dry barren hot oil sands material and syngas including hydrogen and carbon monoxide gases. Heat energy is transferred from at least a portion of the barren hot oil sands material to the raw oil sands material. 1. A method of processing raw oil sands material comprising bitumen, the method comprising:
(a) subjecting an oil sands material comprising the raw oil sands material to a predistillation process comprising:
(i) heating the oil sands material to between approximately 350° C. and approximately 400° C., to produce atmospheric gas oil from the bitumen, and intermediate dried oil sands material; (ii) heating the intermediate dried oil sands material to between approximately 535° C. and at least approximately 600° C., to produce vacuum gas oil and coked oil sands material comprising carbon-heavy hydrocarbons and sand; (b) heating the coked oil sands material to approximately 900° C., to produce a dry barren hot oil sands material and syngas comprising hydrogen and carbon monoxide gases; and (c) transferring heat energy from at least a portion of the barren hot oil sands material to at least one of the oil sands material and the intermediate dried oil sands material. 2. A method according to (d) refining the atmospheric gas oil to provide at least one of liquefied petroleum gas and gasoline; and (e) refining the vacuum gas oil to provide at least one of jet fuel, diesel fuel, and gas oil. 3. A method according to 4. A method of processing raw oil sands material comprising free water and bitumen produced from a mine, comprising:
(a) preheating a preheat oil sands material comprising the raw oil sands material to between approximately 100° C. and approximately 150° C. to convert the free water to steam, to release the free water from the raw oil sands material and to form a dried oil sands material from the preheat oil sands material; (b) in a first predistillation step, heating the dried oil sands material to between approximately 350° C. and approximately 400° C. to partially vaporize the bitumen, to provide atmospheric gas oil from the bitumen, and intermediate dried oil sands material; (c) in a second predistillation step, heating the intermediate dried oil sands material to between approximately 535° C. and at least approximately 600° C. to further at least partially vaporize the bitumen, to provide vacuum gas oil, and coked oil sands material comprising carbon-heavy hydrocarbons and sand; (d) in a gasifier, heating the coked oil sands material to approximately 900° C. for gasification thereof, to provide syngas comprising hydrogen and carbon monoxide gases retaining syngas heat energy therein, and a dry barren hot oil sands material retaining sand heat energy therein; and (e) transferring heat energy from at least a portion of the barren hot oil sands material to at least one of the preheat oil sands material and the dried oil sands material and the intermediate dried oil sands material. 5. A method according to 6. A method according to 7. A method according to 8. A method according to 9. A method according to 10. A method according to 11. A method according to mixing the syngas with at least one additional gas to produce a balanced syngas comprising preselected gases in predetermined proportions. 12. A method according to 13. A method according to 14. A method according to 15. A method according to 16. A method according to 17. A method of processing raw oil sands material comprising free water and bitumen produced from a mine, comprising:
(a) preheating a preheat oil sands material comprising the raw oil sands material to between approximately 100° C. and approximately 150° C. to convert the free water to steam, to release the free water from the raw oil sands material and to form a dried oil sands material from the preheat oil sands material; (b) in a predistillation process, heating the dried oil sands material to between approximately 535° C. and at least approximately 600° C. to at least partially vaporize the bitumen, to provide atmospheric gas oil and vacuum gas oil from the bitumen, and to provide coked oil sands material comprising carbon-heavy hydrocarbons and sand; (c) in a gasifier, heating the coked oil sands material to approximately 900° C. for gasification thereof, to provide syngas comprising hydrogen and carbon monoxide gases retaining syngas heat energy therein, and a dry barren hot oil sands material retaining sand heat energy therein; and (d) transferring heat energy from at least a portion of the barren hot oil sands material to at least one of the preheat oil sands material and the dried oil sands material. 18. A method according to 19. A method according to 20. A method according to 21. A method according to 22. A method according to 23. A method of processing raw oil sands material comprising bitumen, the method comprising:
(a) in a predistillation process, heating the raw oil sands material to between approximately 535° C. and at least approximately 600° C. to at least partially vaporize the bitumen, to provide atmospheric gas oil and vacuum gas oil from the bitumen, and to provide coked oil sands material comprising carbon-heavy hydrocarbons and sand; (b) heating the coked oil sands material to approximately 900° C., to produce a dry barren hot oil sands material and syngas comprising hydrogen and carbon monoxide gases; and (c) transferring heat energy from at least a portion of the barren hot oil sands material to the raw oil sands material.CROSS-REFERENCE TO RELATED APPLICATION
FIELD OF THE INVENTION
BACKGROUND OF THE INVENTION
SUMMARY OF THE INVENTION
BRIEF DESCRIPTION OF THE DRAWINGS
DETAILED DESCRIPTION
Material and Energy Balance for an embodiment of the Method of the Invention Including Temperature Ranges. Temperature Pressure Range, No. Streams T, C Range, C. M (kg/h) kPa 1 Bitumen 25 25 5,000 100 2 Sand 25 25 45,000 100 3 Hot Sand 900 800-900 5,032 100 4 Air 25 25 — 100 5 Water Vapor 100 100-150 2,000 80-100 6 Bitumen-H2O 100 100-150 5,000 100 7 Sand 100 100-150 48,032 100 8 Hot Sand 900 800-900 37,022 100 9 Hot Sand 100 100-150 37,022 100 10 AGO 350 350-400 850 80-100 11 VGO 535 535-600 1,550 80-100 12 Resid 700 700-750 2,600 100 13 Sand 700 700-750 48,032 100 14 H2O (Steam) 500 450-500 2,000 100-150 15 H2O (Steam) 500 450-500 820 100-150 16 Air 700 700-750 6,507 100-150 17 Syngas 900 800-900 11,927 100 18 Hot Sand 900 800-900 48,032 100 19 Hot Sand 900 800-900 5,978 100 20 Water Pond 100 70-100 — 80-100 Energy Stream and Exit Temperature Ranges of Inlet and Outlet Streams of Heat Recovery. Heat Energy Stream, No. Exchanger MJ/h Exit Temperature Range, C. 1 E-101 970-1,846 57-87.3 2 E-102 485-521 71.2-104.8 3 E-103 3,032-3,318 173-214.4 4 E-104 85-87 Air: 150-186 Water: 90-100 5 E-105 260-275 Air: 153-188.9 Water: 25-100 6 E-106 327-515 Air: 162-197.4 Steam: 160-204 7 E-107 6,375 Water Phase Change@ 100 C. Syngas: 232-231.9 8 E-108 3,885-3,765 Air: 700-747.7 Syngas: 900-176 9 E-109 9,510 — 10 E-110 1,940 Steam: 500-540 Syngas: 160-197.4










